Related papers: Gibbs, Boltzmann, and negative temperatures
Generalization through novel interpretations of the inner logic of the century-old Gibbs' statistical thermodynamics is presented: i) Identifying $k_B\to 0$ as classical energetics, one directly derives a pair of thermodynamic variational…
The Bekenstein-Hawking entropy suggests that thermodynamics is an intrinsic ingredient of gravity. Here, we explore the idea that requirements of thermodynamic consistency could determine the gravitational entropy in other set-ups. We…
Previous results on Renyi and Wang's formalism of the Tsallis thermostatics are founded by using an extensive variable z connected to the entropic parameter q. It is shown that in the thermodynamical limit both the Tsallis and Renyi…
This paper is motivated by the recent paper M. Baldovin, S. Iubini, R. Livi and A. Vulpiani, Statistical mechanics of systems with negative temperature, arXiv:2103.12572. The authors suggest that negative absolute temperatures are…
We fix the temperature $T$ and consider mean energy and Boltzmann-Gibbs-Shannon entropy as two players of a game. As a result, basic formulas for the ordinary quantum mean energy and the Boltzmann-Gibbs-Shannon entropy are derived. We…
In this work, we demonstrate the inappropriateness of the Boltzmann-Gibbs log-formulation of the physical Clausius entropy $S$ in connecting thermodynamics and phase space statistics. To achieve our goal, we study thermodynamically the…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
In an attempt to derive thermodynamics from classical mechanics, an approximate expression for the equilibrium temperature of a finite system has been derived [M. Bianucci, R. Mannella, B. J. West, and P. Grigolini, Phys. Rev. E 51, 3002…
Entropy and temperature of a system in a coherent state are naturally defined on a base of a density matrix of the system. As an example, entropy and temperature are evaluated for coherent states of a harmonic oscillator and quantum field…
This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both…
Temperature of a finite-sized system fluctuates due to the thermal fluctuations. However, a systematic mathematical framework for measuring or estimating the temperature is still underdeveloped. Here, we incorporate the estimation theory in…
Alternative definitions are given of basic concepts of generalized thermostatistics. In particular, generalizations of Shannon's entropy, of the Boltzmann-Gibbs distribution, and of relative entropy are considered. Particular choices made…
We prove the Gibbs variational formula in terms of quantum relative entropy density that characterizes translation invariant thermal equilibrium states in quantum lattice systems. It is a natural quantum extension of the similar statement…
The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy.…
We expand upon a natural analogy between Bayesian statistics and statistical physics in which sample size corresponds to inverse temperature. This analogy motivates the definition of two novel statistical quantities: a learning capacity and…
The Boltzmann-Gibbs celebrated entropy $S_{BG}=-k\sum_ip_i \ln p_i$ is {\it concave} (with regard to all probability distributions $\{p_i\}$) and {\it stable} (under arbitrarily small deformations of any given probability distribution). It…
The present paper studies a large class of temperature dependent probability distributions and shows that entropy and energy can be defined in such a way that these probability distributions are the equilibrium states of a generalized…
The features of the fundamental thermodynamical relation (expressing entropy as function of state variables) that arise from the self-gravitating character of a system are analyzed. The models studied include not only a spherically…
The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…
For open quantum systems coupled to a thermal bath at inverse temperature $\beta$, it is well known that under the Born-, Markov-, and secular approximations the system density matrix will approach the thermal Gibbs state with the bath…