Related papers: Gibbs, Boltzmann, and negative temperatures
The positivity conditions of the relative entropy between two thermal equilibrium states $\hat{\rho}_1$ and $\hat{\rho}_2$ are used to obtain upper and lower bounds for the subtraction of their entropies, the Helmholtz potential and the…
Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…
It is shown that the Gibbs paradox is actually paralogism, viz. an erroneous statement sounding credible due to the statistic-mechanical interpretation of entropy as a measure of "any and all" irreversibility. As an alternative, the…
We show that there exists a natural way to define a condition of generalized thermal equilibrium between systems governed by Tsallis thermostatistics, under the hypotheses that i) the coupling between the systems is weak, ii) the structure…
The concept of negative absolute temperature, introduced by Ramsey based on the study of a nuclear spin system by Purcell and Pound in 1951, has been subject to continued debate. According to a recent analysis by Struchtrup, the apparent…
Recently, we have presented some simple arguments supporting the existence of certain complementarity between thermodynamic quantities of temperature and energy, an idea suggested by Bohr and Heinsenberg in the early days of Quantum…
After negative temperature is restated, we find that it will derive necessarily decrease of entropy. Negative temperature is based on the Kelvin scale and the condition dU>0 and dS<0. Conversely, there is also negative temperature for dU<0…
Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…
We extend the recently developed non-gaussian thermodynamic formalism \cite{tre98} of a (presumably strongly turbulent) non-Markovian medium to its most general form that allows for the formulation of a consistent thermodynamic theory. All…
We employ classical thermodynamics to gain information about absolute entropy, without recourse to statistical methods, quantum mechanics or the Third Law of thermodynamics. The Gibbs-Duhem equation yields various simple methods to…
Absolute temperature, the fundamental temperature scale in thermodynamics, is usually bound to be positive. Under special conditions, however, negative temperatures - where high-energy states are more occupied than low-energy states - are…
It has been suggested recently that `$q$-exponential' distributions which form the basis of Tsallis' non-extensive thermostatistical formalism may be viewed as mixtures of exponential (Gibbs) distributions characterized by a fluctuating…
In statistical mechanics Gibbs' paradox is avoided if the particles of a gas are assumed to be indistinguishable. The resulting entropy then agrees with the empirically tested thermodynamic entropy up to a term proportional to the logarithm…
To the student of thermodynamics the most difficult subject is entropy. In this paper we examine the actual, practical application of entropy to two simple systems, the homogeneous slab with fixed boundary values of the temperature, and an…
We show through a nonlinear Fokker-Planck formalism, and confirm by molecular dynamics simulations, that the overdamped motion of interacting particles at T=0, where T is the temperature of a thermal bath connected to the system, can be…
In a recent companion paper, we observed that the rules of ordinary thermodynamics generally fail to respect thermal duality, a symmetry of string theory under which the physics at temperature T is related to the physics at the inverse…
We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…
Many-body quantum systems with local interactions undergo ``sudden death of entanglement" at high temperatures, whereby thermal states become classical mixtures of product states. We investigate whether symmetry constraints can prevent this…
Gibbs and Boltzmann definitions of temperature agree only in the macroscopic limit. The ambiguity in identifying the equilibrium temperature of a finite sized `small' system exchanging energy with a bath is usually understood as a…
We show that for any perfect fluid in a static spacetime, if the Einstein constraint equation is satisfied and the temperature of the fluid obeys Tolman's law, then the other components of Einstein's equation are implied by the assumption…