Related papers: Gibbs, Boltzmann, and negative temperatures
Controversy exists regarding the possible existence of a transition between the liquid and glassy states of water. Here we use experimental measurements of the entropy, specific heat, and enthalpy of both liquid and glassy water to…
Gibbs states play a central role in quantum statistical mechanics as the standard description of thermal equilibrium. Traditionally, their use is justified either by a heuristic, a posteriori reasoning, or by derivations based on notions of…
The second law of thermodynamics constitutes a fundamental principle of physics, precluding the existence of perpetual motion machines and providing a natural definition of the arrow of time. Its scope extends across virtually all areas of…
The ``Gibbs Paradox'' refers to several related questions concerning entropy in thermodynamics and statistical mechanics: whether it is an extensive quantity or not, how it changes when identical particles are mixed, and the proper way to…
Bohr and Heisenberg suggested that the thermodynamical quantities of temperature and energy are complementary in the same way as position and momentum in quantum mechanics. Roughly speaking, their idea was that a definite temperature can be…
The entropy shows an unavoidable tendency of disorder in thermostatistics according to the second thermodynamics law. This provides a minimization entropy principle for quantum thermostatistics with the von Neumann entropy and nonextensive…
Microcanonical equations for several thermodynamic properties of a system, suitable for molecular dynamics simulations, are derived from the nonextensive Tsallis entropy functional. Two possible definitions of temperature, the usual one and…
To understand under which conditions thermodynamics emerges from the microscopic dynamics is the ultimate goal of statistical mechanics. Despite the fact that the theory is more than 100 years old, we are still discussing its foundations…
We give the first example of a smooth family of real and complex maps having sensitive dependence of geometric Gibbs states at positive temperature. This family consists of quadratic-like maps that are non-uniformly hyperbolic in a strong…
The notion of group entropy is proposed. It enables to unify and generalize many different definitions of entropy known in the literature, as those of Boltzmann-Gibbs, Tsallis, Abe and Kaniadakis. Other new entropic functionals are…
The Nernst heat theorem is probed from purely thermodynamic arguments connected with the second law of thermodynamics, and alien to the vanishing of the specific heats, or to the unattainability of the zeroth isotherm. If the proof is…
Some problems have been found as to the definition of entropy of black hole being applied to the extremal Kerr-Newman case, which has conflicts with the third law of thermodynamics. We have proposed a new modification for the near extremal…
The physical meaning of entropy is analyzed in the context of statistical, nuclear, atomic physics and cosmology. Only the microcanonical Boltzmann entropy leads to no contradictions in several simple, elementary and for thermodynamics…
We show that the generalized Boltzmann distribution is the only distribution for which the Gibbs-Shannon entropy equals the thermodynamic entropy. This result means that the thermodynamic entropy and the Gibbs-Shannon entropy are not…
A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new…
We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth $U_0$ around the origin. When the temperature is small compared to the trap depth ($\xi=k_B T/U_0 \ll 1$), there exists a range of…
Superstatistics (Physica A 322, 267-275, 2003) is a formalism that attempts to explain the presence of distributions other than the Boltzmann-Gibbs distributions in Nature, typically power-law behavior, for systems out of equilibrium such…
The possible distinction between inanimate and living matter has been of interest to humanity since thousands of years. Clearly, such a rich question can not be answered in a single manner, and a plethora of approaches naturally do exist.…
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…
Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…