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The internal quantum efficiency (IQE) of an organic photovoltaic device (OPV) is proportional to the number of free charge carriers generated and their conductivity, per absorbed photon. However, both the IQE and the quantities that…

Mesoscale and Nanoscale Physics · Physics 2016-06-15 Livia Noëmi Glanzmann , Duncan John Mowbray

The efficiency of an organic light-emitting diode (OLED) depends on the microscopic orientation of transition dipole moments of the molecular emitters. The most effective materials used for light generation have threefold symmetry, which…

Chemical Physics · Physics 2015-02-26 Florian Steiner , Sebastian Bange , Jan Vogelsang , John M. Lupton

Excited states are the key species in photocatalysis, while the critical parameters that govern their applications are: i) excitation energy, ii) accessibility, and iii) lifetime. However, in molecular transition metal-based…

We study two-electron states confined in two coupled quantum dots formed by a short-range potential in a two-dimensional topological insulator. It is shown that there is a fairly wide range of the system parameters, where the ground state…

Mesoscale and Nanoscale Physics · Physics 2018-09-17 Vladimir A. Sablikov , Aleksei A. Sukhanov

Thermally-activated delayed fluorescence (TADF) enables organic semiconductors with charge transfer (CT)-type excitons to convert dark triplet states into bright singlets via a reverse intersystem crossing (rISC) process. Here, we consider…

We present a generic theory of primary photoexcitations in low band gap donor-acceptor conjugated copolymers. Because of the combined effects of strong electron correlations and broken symmetry, there is considerable mixing between a…

Mesoscale and Nanoscale Physics · Physics 2016-01-01 Karan Aryanpour , Tirthankar Dutta , Uyen N. V. Huynh , Zeev Valy Vardeny , Sumit Mazumdar

Spin-triplet superconductivity is a key platform for topological quantum computing, yet its experimental realization and control in solid-state materials remain a significant challenge. For this purpose, we propose an ultrafast optical…

Strongly Correlated Electrons · Physics 2025-12-29 Zecheng Shen , Chendi Xie , Wei-Chih Chen , Yao Wang

While the search for topological triplet-pairing superconductivity has remained a challenge, recent developments in optically stabilizing metastable superconducting states suggest a new route to realizing this elusive phase. Here, we devise…

Superconductivity · Physics 2024-03-11 Steven Gassner , Clara S. Weber , Martin Claassen

We report accurate numerical studies of excited state orderings in long hypothetical pi-conjugated oligomers in which the hydrogen atoms of trans-polyacetylene are replaced with conjugated sidegroups, within modified Hubbard models. There…

Strongly Correlated Electrons · Physics 2009-11-11 Y. Yan , S. Mazumdar

A generalization of the Cooper pairing mechanism is proposed which allows for a triplet state of lower energy. This is achieved by incorporating spin into the canonical commutation relations and by modifying the $\delta$ potential contact…

Superconductivity · Physics 2010-12-14 Ashok Das , J. Gamboa , F. Mendez , F. Torres

We study the ground state of three-leg $S=1/2$ Heisenberg tube using the density-matrix renormalization group method. The dimerization order-parameter and spin-excitation gap are calculated in a wide range of leg exchange interactions. We…

Strongly Correlated Electrons · Physics 2010-02-02 S. Nishimoto , M. Arikawa

We explore the electroluminescence efficiency for a quantum mechanical model of a large number of molecular emitters embedded in an optical microcavity. We characterize the circumstances under which a microcavity enhances harvesting of…

Mesoscale and Nanoscale Physics · Physics 2019-09-04 Luis A. Martínez-Martínez , Elad Eizner , Stéphane Kéna-Cohen , Joel Yuen-Zhou

We propose a minimal model Hamiltonian for the electronic structure of a monomethine dye, in order to describe the photoisomerization of such dyes. The model describes interactions between three diabatic electronic states, each of which can…

Chemical Physics · Physics 2015-05-14 Seth Olsen , Ross H. McKenzie

This work demonstrates the unique approach of introducing divacancy imperfections in topological Stone-Wales type defected graphene quantum dots for harvesting both singlet and triplet excitons, essential for fabricating fluorescent organic…

Mesoscale and Nanoscale Physics · Physics 2022-08-09 Tushima Basak , Tista Basak , Alok Shukla

Twisted bilayer two-dimensional electronic systems give rise to many exotic phenomena and unveil a new frontier for the study of quantum materials. In photonics, twisted two-dimensional systems coupled via near-field interactions offer a…

Mesoscale and Nanoscale Physics · Physics 2022-05-17 Rongqian Wang , Jincheng Lu , Xiaohu Wu , Jiebin Peng , Jian-Hua Jiang

The electronic interaction between an optically active singlet state ($S_1S_0$) and a dark state of singlet multiplicity, known as correlated triplet pair ($^1[TT]$), plays a crucial role in the effective transformation from $S_1S_0$ to…

Conjugated polymers are experiencing a surge of renewed interest due to their promising applications in various organic electronic devices. These include organic light-emitting diodes (OLEDs), field-effect transistors (FETs), and organic…

Materials Science · Physics 2025-09-24 Miguel Lagos , Miguel Kiwi , Rodrigo Paredes

Triplet excitons have been the focus of considerable attention with regards to the functioning of polymer solar cells, because these species are long-lived and quench subsequently generated singlet excitons in their vicinity. The role of…

Chemical Physics · Physics 2018-02-14 Florian Steiner , John M. Lupton , Jan Vogelsang

The S1 (21Ag-) state is an optically dark state of natural and synthetic pi-conjugated materials that can play a critical role in optoelectronic processes such as, energy harvesting, photoprotection and singlet fission. Despite this…

The reported enhanced singlet-exciton yields in light-emitting polymers over the statistical limit of 25% has attracted wide experimental and theoretical attention. Most theoretical estimates of the singlet-exciton yield depend crucially on…

Chemical Physics · Physics 2007-05-23 William Barford , Eric E. Moore