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The ferrimagnetic spinel $\mathrm{CoV_2O_4}$ has been a topic of intense recent interest, both as a frustrated insulator with unquenched orbital degeneracy and as a near-itinerant magnet which can be driven metallic with moderate applied…

Strongly Correlated Electrons · Physics 2016-02-03 D. Reig-i-Plessis , D. Casavant , V. O. Garlea , A. A. Aczel , M. Feygenson , J. Neuefeind , H. D. Zhou , S. E. Nagler , G. J. MacDougall

We report a sequence of continuous phase transformations in iron telluride, Fe1+yTe (y~0.1), which is observed by combining neutron diffraction, magnetic susceptibility, and specific heat measurements on single crystal samples. While a…

Strongly Correlated Electrons · Physics 2012-02-14 I. A. Zaliznyak , Z. J. Xu , J. S. Wen , J. M. Tranquada , G. D. Gu , V. Solovyov , V. N. Glazkov , A. I. Zheludev , V. O. Garlea , M. B. Stone

The rich phase diagram of bulk Pr$_{1-x}$Ca$_{x}$MnO$_3$ resulting in a high tunability of physical properties gave rise to various studies related to fundamental research as well as prospective applications of the material. Importantly, as…

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

In this article we present a neutron diffraction in-situ study of the thermal evolution and high-temperature structure of layered cobaltites Y(Ba, Sr)Co2 O5+{\delta}. Neutron thermodiffractograms and magnetic susceptibility measurements are…

Materials Science · Physics 2015-05-19 G Aurelio , R D Sánchez , J Curiale , G J Cuello

Ba2CaMoO6 was synthesized by solid state method. The crystal structure adopts cubic Fm-3m space group at room temperature with lattice parameters of 8.378231(5) {angstroms}. Upon cooling, Ba2CaMoO6 was determined to have a structural phase…

Materials Science · Physics 2020-11-03 Loi T. Nguyen , Robert J. Cava , Allyson M. Fry-Petit

Barium zirconate BaZrO3 is one of few perovskites that is claimed to retain an average cubic structure down to 0K at ambient pressure, while being energetically very close to a tetragonal phase obtained by condensation of a soft phonon mode…

Materials Science · Physics 2024-03-22 Erik Fransson , Petter Rosander , Paul Erhart , Göran Wahnström

A theoretically supported experimental study of the (1-x)LaFeO3.xLaMnO3 (LFO-LMO) solid solution is being reported for the first time which reveals a phase transformation from the Pbnm and R3-c phase at a chemical composition of x=0.625.…

Materials Science · Physics 2020-12-29 E. G. Rini , Mayanak. K. Gupta , R. Mittal , A. Mekki , Mohammed H. Al Saeed , Somaditya Sen

We measured phonon dispersion in single crystal EuTiO$_3$ using inelastic x-ray scattering. A structural transition to an antiferrodistortive phase was found at a critical temperature $T_0$=287$\pm$1 K using powder and single-crystal x-ray…

Strongly Correlated Electrons · Physics 2015-06-11 David S. Ellis , Hiroshi Uchiyama , Satoshi Tsutsui , Kunihisa Sugimoto , Kenichi Kato , Daisuke Ishikawa , Alfred Q. R. Baron

Measurements of the resistive properties and the lattice parameters of a (LaVO3)[6 unit cells]/(SrVO3)[1 unit cell] superlattice between 10K and room temperature are presented. A low temperature metallic phase compatible with a Fermi liquid…

Strongly Correlated Electrons · Physics 2015-05-28 A. David , R. Frésard , Ph. Boullay , W. Prellier , U. Lüders , P. -E. Janolin

The ratiometric approach is the most commonly employed readout technique in luminescence thermometry. To address the trade-off between the risk of measurement disturbance in thermometers with high spectral separation of emission bands (due…

The results of polarization-dependent Raman spectroscopy of single-crystalline LiVO$_2$ exhibiting transition to a diamagnetic state below $T_c \sim $500K are reported. Our measurements clearly detect additional peaks in the low-temperature…

Strongly Correlated Electrons · Physics 2024-07-12 Yuri S. Ponosov , Evgenia V. Komleva , Elizaveta A. Pankrushina , Haohang Xu , Yu Sui , Sergey V. Streltsov

Neutron spectroscopy has revealed a highly unusual magnetic structure and dynamics in YVO$_3$, an insulating pseudocubic perovskite that undergoes a series of temperature induced phase transitions between states with different spin and…

Strongly Correlated Electrons · Physics 2009-11-07 C. Ulrich , G. Khaliullin , J. Sirker , M. Reehuis , M. Ohl , S. Miyasaka , Y. Tokura , B. Keimer

X-ray diffraction, dynamical mechanical analysis and infrared reflectivity studies revealed an antiferrodistortive phase transition in EuTiO3 ceramics. Near 300K the perovskite structure changes from cubic Pm-3m to tetragonal I4/mcm due to…

In order to explore the origin of the Metal-Insulator (M-I) transition, the precise crystal structures of the hole-doped Mott insulator system, Y1-XCaXTiO3 (x=0.37, 0.39 and 0.41), are studied for the temperature range between 20K and 300K…

Strongly Correlated Electrons · Physics 2009-11-07 K. Kato , E. Nishibori , M. Takata , M. Sakata , T. Nakano , K. Uchihira , M. Tsubota , F. Iga , T. Takabatake

The recent surge of interest in phase change materials GeTe, Ge$_2$Sb$_2$Te$_5$, and related compounds motivated us to revisit the structural phase transition in GeTe in more details than was done before. Rhombohedral-to-cubic ferroelectric…

Materials Science · Physics 2015-03-19 Tapan Chatterji , C. M. N. Kumar , Urszula D. Wdowik

Structural phase transformations in (001)-oriented (1-x)Pb(Mg1/3Nb2/3O3)-32%PbTiO3 (PMN-x%PT) crystals have been investigated by x-ray diffraction. A C->T->MC sequence was observed in both the field-cooled (FC) and zero-field-cooled (ZFC)…

Materials Science · Physics 2009-11-10 Hu Cao , Feiming Bai , Jiefang Li , D. Viehland , Guangyong Xu , H. Hiraka , G. Shirane

We investigate the importance of quantum orbital fluctuations in the orthorhombic and monoclinic phases of the Mott insulators LaVO3 and YVO3. First, we construct ab-initio material-specific t2g Hubbard models. Then, by using dynamical…

Strongly Correlated Electrons · Physics 2009-01-07 M. De-Raychaudhury , E. Pavarini , O. K. Andersen

The structural phase diagram of the La1-xSrxMnO3 system in the compositional range 0.08 <= x <= 0.125 has been investigated by high-resolution synchrotron x-ray powder diffraction techniques between 20-600 K. Recent studies have reported…

Strongly Correlated Electrons · Physics 2009-10-31 D. E. Cox , T. Iglesias , E. Moshopoulou , K. Hirota , K. Takahashi , Y. Endoh

We present a comprehensive magnetic and structural phase diagram for $\mathrm{Y_{1-x}Lu_xBaCo_4O_7}$, established through neutron diffraction and magnetization measurements. Our results outline the evolution of various nuclear structures,…

Strongly Correlated Electrons · Physics 2023-12-08 Sevda Sahinbay , Hong Zheng , John F. Mitchell , Stephan Rosenkranz , Omar Chmaissem