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The structural and magnetic properties of YVO3, NdVO3 and TbVO3 were investigated by single-crystal and powder neutron diffraction. YVO3 shows a structural phase transition at 200 K from an orthorhombic structure with the space group Pbnm…

Strongly Correlated Electrons · Physics 2009-11-11 M. Reehuis , C. Ulrich , P. Pattison , B. Ouladdiaf , M. C. Rheinstadter , M. Ohl , L. P. Regnault , M. Miyasaka , Y. Tokura , B. Keimer

The temperature (T) dependent x-ray diffraction (XRD) and resistivity measurements of La0.175Pr0.45Ca0.375MnO3 (LPCMO) have been performed down to 2K to understand the structural and transport properties. From room temperature down to 220K,…

Materials Science · Physics 2016-06-22 Shivani Sharma , Aga Shahee , Kiran Singh , N. P. Lalla

We report a temperature-dependent neutron diffraction (ND) study on polycrystalline monoclinic BaIrO$_3$ which is famous for charge density wave (CDW) and weak ferromagnetic phase transitions at T$_C$$\sim$180 K simultaneously. A Rietveld…

Strongly Correlated Electrons · Physics 2023-08-17 Bin Chang , Jinwon Jeong , Han-Jin Noh , Seongsu Lee

A structural transition at $T\approx 322$ K from the $Pmmm$ to $Pmma$ phase is found to coincide with an anomaly of resistivity. Another structural phase transition doubling the lattice parameter $c$, which has been postulated earlier to…

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

Materials Science · Physics 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

We report a temperature-dependent Raman scattering investigation of DyScO3 and GdScO3 single crystals from room temperature up to 1200 {\deg}C. With increasing temperature, all modes decrease monotonously in wavenumber without anomaly,…

Materials Science · Physics 2010-04-13 O. Chaix-Pluchery , D. Sauer , J. Kreisel

We report investigation of structural phase transitions in technologically important material sodium niobate as a function of temperature on heating over 300-1075 K. Our high resolution powder neutron diffraction data show variety of…

Materials Science · Physics 2015-05-20 S. K. Mishra , R. Mittal , V. Yu. Pomjakushin , S. L. Chaplot

We have grown a YCrO$_3$ single crystal by the floating-zone method and studied its temperature-dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well…

Strongly Correlated Electrons · Physics 2024-03-08 Qian Zhao , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Kaitong Sun , Hai-Feng Li

The controversies about the structure of the true ground state of pseudorhombohedral compositions of Pb(ZrxTi1-x)O3 (PZT) are addressed using a 6% Sr2+ substituted sample with x=0.550. Sound velocity measurements reveal a phase transition…

The structural phase transformation in the La2/3Ba1/3MnO3 perovskite manganite was studied by ultrasound, neutron diffraction and electron microscopy techniques. Minima of the velocity and maxima of the decrement of the ultrasound point out…

Materials Science · Physics 2007-05-23 A. B. Beznosov , E. L. Fertman , P. P. Pal-Val , L. N. Pal-Val , C. Ritter , M. Rossell , D. D. Khalyavin

We have recently predicted and subsequently verified experimentally by specific heat measurements that EuTiO3 undergoes a structural phase transition at elevated temperature TS = 282 K. The origin of the phase transition has been attributed…

Materials Science · Physics 2012-05-25 J. Köhler , R. Dinnebier , A. Bussmann-Holder

Up to now the crystallographic structure of the magnetoelectric perovskite EuTiO3 was considered to remain cubic down to low temperature. Here we present high resolution synchrotron X-ray powder diffraction data showing the existence of a…

Electronic structure of pulsed laser deposited epitaxial LaVO3 (LVO) thin film grown on LaAlO3 (001) (LAO) substrate, has been studied at room temperature and at 130 K, which is below the structural (141 K) and magnetic transition…

Strongly Correlated Electrons · Physics 2020-12-30 Anupam Jana , Rajamani Raghunathan , Ritu Rawat , R. J. Choudhary , D. M. Phase

Optical and magneto-optical properties of YVO$_3$ single crystal were studied in FIR, visible, and UV regions. Two structural phase transitions at 75 K and 200 K were observed and established to be of the first and second order,…

Many materials exhibit various types of phase transitions at different temperatures, with many also demonstrating polymorphism. Doping materials can significantly alter their conductivity. In light of this, we have investigated the…

Materials Science · Physics 2024-08-29 Mohammad Abu Thaher Chowdhury , Shumsun Naher Begum

With the development of electronic structure theory, a new class of materials - quantum ones has been recognized by the community. Traditionally, it has been believed that the properties of such compounds cannot be described within the…

Materials Science · Physics 2023-11-10 Himanshu Joshi , Mateusz Wlazło , Harshan Reddy Gopidi , Oleksandr I. Malyi

In the R1/2D1/2MnO3 manganites (R: rare earth, D: divalent cation), the structural phase transition at Tco is commonly interpreted as a concomitant charge and orbital ordering (CO/OO) process driven by a cooperative Jahn-Teller effect and…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , J. Rodriguez-Carvajal , L. Pinsard-Gaudart , M. T. Fernandez-Diaz , A. Revcolevschi

Soft phonon behavior associated with a structural phase transition from the low-temperature-orthorhombic (LTO) phase ($Bmab$ symmetry) to the low-temperature-tetragonal (LTT) phase ($P4_{2}/ncm$ symmetry) was investigated in…

Superconductivity · Physics 2009-11-10 H. Kimura , Y. Noda , H. Goka , M. Fujita , K. Yamada , G. Shirane

We report a detailed high-resolution powder neutron diffraction investigation of the structural behaviour of the multiferroic hexagonal polymorph of YMnO3 between room temperature and 1403 K. The study was aimed at resolving previous…

Materials Science · Physics 2015-05-19 Alexandra S. Gibbs , Kevin S. Knight , Philip Lightfoot

Group theoretical aspects of the three temperature-dependent and temperature-reversible experimentally observed phase transitions in the KNbO3 crystal (cubic-tetragonal, tetragonal-orthorhombic, orthorhombic-rhombohedral) in the framework…

Materials Science · Physics 2024-11-05 R. A. Evarestov , Yu. E. Kitaev , S. S. Novikov
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