We report a temperature-dependent Raman scattering investigation of DyScO3 and GdScO3 single crystals from room temperature up to 1200 {\deg}C. With increasing temperature, all modes decrease monotonously in wavenumber without anomaly, which attests the absence of a structural phase transition. The high temperature spectral signature and extrapolation of band positions to higher temperatures suggest a decreasing orthorhombic distortion towards the ideal cubic structure. Our study indicates that this orthorhombic-to-cubic phase transition is close to or higher than the melting point of both rare-earth scandates (\approx 2100 {\deg}C), which might exclude the possibility of the experimental observation of such a phase transition before melting. The temperature-dependent shift of Raman phonons is also discussed in the context of thermal expansion.
@article{arxiv.1004.1892,
title = {Temperature-dependent Raman scattering of DyScO3 and GdScO3 single crystals},
author = {O. Chaix-Pluchery and D. Sauer and J. Kreisel},
journal= {arXiv preprint arXiv:1004.1892},
year = {2010}
}