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Temperature-dependent FAR-infrared reflectivity spectra of partially ordered magnetodielectric La2CoMnO6 is presented, from room temperature up to 675 K. A clear first-ordered structural phase transition (SPT) from a monoclinic structure…

Materials Science · Physics 2018-02-22 R. X. Silva , A. Nonato , R. L. Moreira , R. M. Almeida , C. W. A. Paschoal

Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…

The limited operational range of phase transition-based luminescence thermometers necessitates the exploration of new host materials exhibiting first-order structural phase transitions to broaden the applicability of this approach.…

Materials Science · Physics 2025-04-03 M. Tahir Abbas , M. Szymczak , V. Kinzhybalo , D. Szymanski , M. Drozd , L. Marciniak

We utilize single-crystal neutron diffraction to study the $C2/m$ structure of potassium hydrogen carbonate (KHCO$_3$) and macroscopic quantum entanglement above the phase transition at $T_c = 318$ K. Whereas split atom sites could be due…

Other Condensed Matter · Physics 2008-07-10 François Fillaux , Alain Cousson , Matthias J. Gutmann

Phase transitions are key in determining and controlling the quantum properties of correlated materials. Here, by using the powerful combination of precise material synthesis and angle resolved photoelectron spectroscopy, we show evidence…

The structure of dielectric perovskite BaZrO$_3$, long known to be cubic at room temperature without any structural phase transition with variation of temperature, has been recently disputed to have different ground state structures with…

Materials Science · Physics 2022-06-29 Dong-Hyeon Gim , Yeahan Sur , Yoon Han Lee , Jeong Hyuk Lee , Soonjae Moon , Yoon Seok Oh , Kee Hoon Kim

The insulator-metal transition in single crystal La(5/8-y)Pr(y)Ca(3/8)MnO3 with y=0.35 was studied using synchrotron x-ray diffraction, electric resistivity, magnetic susceptibility, and specific heat measurements. Despite the dramatic drop…

Condensed Matter · Physics 2009-10-31 V. Kiryukhin , B. G. Kim , V. Podzorov , S-W. Cheong , T. Y. Koo , J. P. Hill , I. Moon , Y. H. Jeong

We report direct experimental evidence of antiferroelectric to paraelectric phase transition under pressure in NaNbO3 using neutron diffraction at room temperature. The paraelectric phase is found to stabilize above 8 GPa and its crystal…

Materials Science · Physics 2015-06-11 S. K. Mishra , M. K. Gupta , R. Mittal , S. L. Chaplot , Thomas Hansen

We report on the temperature dependent Raman spectroscopic studies of orthorombic distorted perovskite YCrO3 in the temperature range of 20-300K. Temperature dependence of DC-magnetization measurement under field cooled and zero field…

Materials Science · Physics 2013-09-30 Yogesh Sharma , Satyaprakash Sahoo , W. Perez , Ram S. Katiyar

The structural phase transition in hexagonal BaMnO$_3$ occurring at $T_c$=130 K was studied in ceramic samples using electron and X-ray diffraction, second harmonic generation as well as by dielectric and lattice dynamic spectroscopies. The…

Understanding the mechanism of structural phase transitions in rare-earth elements is a fundamental challenge in condensed matter physics, with significant implications for materials science applications. In this study, we present a…

The prototypical phase change material GeTe shows an enigmatic phase transition at Tc ca. 650 K from rhombohedral (R3m) to cubic (Fm-3m) symmetry. While local probes see little change in bonding, in contrast, average structure probes imply…

Materials Science · Physics 2015-07-01 Jessica M. Hudspeth , Tapan Chatterji , Simon J. L. Billinge , Simon A. J. Kimber

Pulsed neutron diffraction investigations have been performed in the ferroelectric PZT system, Pb(Zr1-xTix)O3, doped with 1%wt. of Nb2O5, as a function of both temperature and composition. The study has been made in a wide range of…

Materials Science · Physics 2009-10-31 B. Noheda , J. A. Gonzalo , M. Hagen

In recent yerars, Bismuth sodium titanate (BNT) and BNT-based piezoelectric materials have proved potential for lead-free piezoelectric technologies. Such materials' complicated phase structure is crucial to their thermo-electromechanical…

Materials Science · Physics 2024-10-08 Akshayveer , Federico C Buroni , Roderick Melnik , Luis Roderiguez-Tembleque , Andres Saez

Several experiments conducted over decades have revealed that the perovskite-structured BaCeO3 goes through a series of temperature-induced structural phase transitions. However, it has been frequently observed that the number of phases and…

We used low-temperature synchrotron x-ray diffraction to investigate the structural phase transitions of Fe1+yTe in the vicinity of a tricitical point in the phase diagram. Detailed analysis of the powder diffraction patterns and…

Superconductivity · Physics 2013-10-03 Cevriye Koz , Sahana Rößler , Alexander A. Tsirlin , Steffen Wirth , Ulrich Schwarz

In this work, we report the effects of calcination temperature on structural, dielectric, semiconducting and optical properties of YFeO3 nanoparticles prepared by a high energy ball milling process. The structural analysis of the X-ray…

Materials Science · Physics 2019-10-08 Chandra Bhal Singh , Dinesh Kumar , Narendra Kumar Verma , Akhilesh Kumar Singh

The structural changes in Sr(0.66)Ba(0.34)Nb2O6 single crystal fibers when the temperature decreases from 295 to 10 K is investigated by dielectric constant measurements and Raman spectroscopy. The anomaly observed in the plot of e is…

The crystal structures and phonon spectra of orthorhombic cadmium titanate with the $Pbnm$ structure and of its two possible ferroelectrically distorted phases with $Pbn2_1$ and $Pb2_1m$ space groups were calculated from first principles…

Materials Science · Physics 2015-07-27 Alexander I. Lebedev

Single crystals of a ternary relaxor ferroelectric system, 0.29Pb(In1/2Nb1/2)O3-0.45Pb(Mg1/3Nb2/3)O3-0.26PbTiO3, have been studied using triple-axis based elastic and inelastic neutron scattering. Elastic diffuse scattering confirms the…

Materials Science · Physics 2022-08-10 Qian Li , Sergey Danilkin , Guochu Deng , Jian Wang , Zhengrong Li. Ray L. Withers , Zhuo Xu , Yun Liu