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We examine the discontinuous first-order superfluid $^3$He A to B transition in the vicinity of the polycritical point (2.232 mK and 21.22 bar). We find path-dependent transitions: cooling at fixed pressure yields a well defined transition…

We use the results derived in the framework of the replica approach to study the liquid-glass thermodynamic transition. The main results are rederived without using replicas and applied to the study of the Lennard-Jones binary mixture…

Soft Condensed Matter · Physics 2009-10-31 Barbara Coluzzi , Giorgio Parisi , Paolo Verrocchio

The location of the Frenkel line (FL) of a Lennard-Jones fluid which demarcates two distinct physical states, liquidlike and gaslike within the supercritical regime, has been established through molecular dynamics (MD) simulations of the…

Statistical Mechanics · Physics 2018-01-29 Kanka Ghosh , C. V. Krishnamurthy

Polymorphism is ubiquitous in crystalline solids. Amorphous solids, such as glassy water and silicon, may undergo amorphous-to-amorphous transitions (AATs). The nature of AATs remains ambiguous, due to diverse system-dependent behaviors and…

Here we present an explicit counterexample to the widely spread beliefs about an exclusive role of bimodality as the first order phase transition signal. On the basis of an exactly solvable statistical model generalizing the statistical…

Nuclear Theory · Physics 2013-04-23 V. V. Sagun , A. I. Ivanytskyi , D. R. Oliinychenko , K. A. Bugaev

The existence of a phase transition between two distinct liquid phases in single-component network-forming liquids (e.g., water, silica, silicon) has elicited considerable scientific interest. The challenge, both for experiments and…

Soft Condensed Matter · Physics 2022-05-30 Yagyik Goswami , Srikanth Sastry

Within the coexistence region between liquid and vapor the equilibrium pressure of a simulated fluid exhibits characteristic jumps and plateaus when plotted as a function of density at constant temperature. These features exclusively…

Statistical Mechanics · Physics 2015-09-09 S. Prestipino , C. Caccamo , D. Costa , G. Malescio , G. Munaò

Molecular models of real fluids are validated by comparing the vapor-liquid surface tension from molecular dynamics (MD) simulation to correlations of experimental data. The considered molecular models consist of up to 28 interaction sites,…

Computational Physics · Physics 2016-08-16 Stephan Werth , Martin Horsch , Hans Hasse

We report the first observation of homogeneous crystallization in simulated high-dimensional ($d > 3$) liquids that follow physically realistic dynamics and have system sizes that are large enough to eliminate the possibility that…

Soft Condensed Matter · Physics 2023-11-08 Robert S. Hoy

Employing simplified models in computer simulation is on the one hand often enforced by computer time limitations but on the other hand it offers insights into the molecular properties determining a given physical phenomenon. We employ this…

Statistical Mechanics · Physics 2008-04-18 Bortolo Matteo Mognetti , Martin Oettel , Leonid Yelash , Peter Virnau , Wolfgang Paul , Kurt Binder

Here we present two explicit counterexamples to the widely spread beliefs about an exclusive role of bimodality as the first order phase transition signal. On the basis of an exactly solvable statistical model generalizing the statistical…

Nuclear Theory · Physics 2015-06-16 K. A. Bugaev , A. I. Ivanytskyi , V. V. Sagun , D. R. Oliinychenko

An electronically coarse-grained model for water reveals a persistent vestige of the liquid-gas transition deep into the supercritical region. A crossover in the density dependence of the molecular dipole arises from the onset of…

Statistical Mechanics · Physics 2015-09-15 V. P. Sokhan , A. Jones , F. S. Cipcigan , J. Crain , G. J. Martyna

Molecular dynamic simulations for systems with $D=2,3$ Lennard-Jones-like interactions are studied. In the model, we assume that, at long distances, the two-body attractive potential decays as $r^{-\alpha}$. Thermodynamic extensivity…

Condensed Matter · Physics 2009-10-31 Sergio Curilef , Constantino Tsallis

It is shown that if impurities in superfluid 3He have form of infinitely long non-magnetic strands, which are straight, parallel to each other and reflect quasi-particles specularly, the temperature of transition of liquid 3He from the…

Disordered Systems and Neural Networks · Physics 2019-04-22 I. A. Fomin

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · Physics 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

Bootstrap, or $k$-core, percolation displays on the Bethe lattice a mixed first/second order phase transition with both a discontinuous order parameter and diverging critical fluctuations. I apply the recently introduced $M$-layer technique…

Statistical Mechanics · Physics 2019-03-18 Tommaso Rizzo

The phase transitions of liquid Helium 3 are described by truncations of an exact nonperturbative renormalization group equation. The location of the first order transition lines and the jump in the order parameter are computed…

Statistical Mechanics · Physics 2009-10-31 Markus Kindermann , Christof Wetterich

Achieving a coherent understanding of the many thermodynamic and dynamic anomalies of water is among the most important unsolved puzzles in physics, chemistry, and biology. One hypothesized explanation imagines the existence of a line of…

Statistical Mechanics · Physics 2012-06-01 Tobias Kesselring , Giancarlo Franzese , Sergey Buldyrev , Hans Herrmann , H. Eugene Stanley

It is discussed how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be defined and classified for finite systems from the topology of the energy surface…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross , E. Votyakov

The recent paper nucl-th/0208024 by Moretto et al. is commented: Their picture of nuclear phase transition in terms of macroscopic control parameters, temperature and pressure, is irrelevant. Their criticism of order-disorder…

Nuclear Theory · Physics 2007-05-23 D. H. E. Gross
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