English

Critical Temperature and Nonextensivity in Long-range Interacting Lennard-Jones-like Fluids

Condensed Matter 2009-10-31 v1

Abstract

Molecular dynamic simulations for systems with D=2,3D=2,3 Lennard-Jones-like interactions are studied. In the model, we assume that, at long distances, the two-body attractive potential decays as rαr^{-\alpha}. Thermodynamic extensivity (nonextensivity) is observed for α>D\alpha > D (0αD0\leq \alpha \leq D). Particular attention is payed to the liquid-gas critical point located, in the temperature-pressure plane, at (Tc,PcT_c,P_c). (Tc,PcT_c,P_c) are, in the NN\to \infty limit (NN\equiv number of molecules), {\em finite} for α>D\alpha > D and {\em diverge} for αD\alpha \leq D (as (αD)1(\alpha - D)^{-1} for α/D1+0\alpha/D \to 1 + 0). However, the variables TcTc/NT_c^* \equiv T_c/N^* and PcPc/NP_c^* \equiv P_c/N^* with N[N1α/D1]/[1α/D]N^* \equiv [N^{1-\alpha/D} -1]/[1-\alpha/D] remain {\em finite for all} α\alpha. Thus, the extensive and nonextensive regions become unified, as recently conjectured. These results should be useful for discussing gravitation and some special fluids

Keywords

Cite

@article{arxiv.cond-mat/9911152,
  title  = {Critical Temperature and Nonextensivity in Long-range Interacting Lennard-Jones-like Fluids},
  author = {Sergio Curilef and Constantino Tsallis},
  journal= {arXiv preprint arXiv:cond-mat/9911152},
  year   = {2009}
}

Comments

7 pages and 6 PS-figures, RevTeX, to appear in Physics Letters A