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The routine transformation of a liquid, as it is cooled rapidly, resulting in glass formation, is remarkably complex. A theoretical explanation of the dynamics associated with this process has remained one of the major unsolved problems in…

Disordered Systems and Neural Networks · Physics 2014-12-17 T. R. Kirkpatrick , D. Thirumalai

We propose that an onset of glass transition can be defined as the point at which a supercooled liquid acquires the stress relaxation mechanism of a solid glass. We translate this condition into the rate equation for local relaxation…

Materials Science · Physics 2009-11-11 Kostya Trachenko

We describe our perspective on the Structural Glass Transition (SGT) problem built on the premise that a viable theory must provide a consistent picture of the dynamics and statics, which are manifested by large increase in shear viscosity…

Soft Condensed Matter · Physics 2009-12-15 T. R. Kirkpatrick , D. Thirumalai

The random first order transition theory of the dynamics of supercooled liquids is extended to treat aging phenomena in nonequilibrium structural glasses. A reformulation of the idea of ``entropic droplets'' in terms of libraries of local…

Soft Condensed Matter · Physics 2009-11-10 Vassiliy Lubchenko , Peter G. Wolynes

We study the local dynamical fluctuations in glass-forming models of particles embedded in $d$-dimensional space, in the mean-field limit of $d\to\infty$. Our analytical calculation reveals that single-particle observables, such as squared…

Disordered Systems and Neural Networks · Physics 2022-04-27 Giulio Biroli , Patrick Charbonneau , Giampaolo Folena , Yi Hu , Francesco Zamponi

The nature of the transition to collective motion in assemblies of aligning self-propelled particles remains a long-standing matter of debate. In this article, we focus on dry active matter and show that weak fluctuations suffice to…

We study theoretically and numerically a family of multi-point dynamic susceptibilities that quantify the strength and characteristic lengthscales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments…

Nearly all glass forming liquids display secondary relaxations, dynamical modes seemingly distinct from the primary alpha relaxations. We show that accounting for driving force fluctuations and the diversity of reconfiguring shapes in the…

Soft Condensed Matter · Physics 2015-05-13 Jacob D. Stevenson , Peter G. Wolynes

Sticky hard spheres, i.e., hard particles decorated with a short-ranged attractive interaction potential, constitute a relatively simple model with highly non-trivial glassy dynamics. The mode-coupling theory of the glass transition (MCT)…

Soft Condensed Matter · Physics 2021-08-26 Chengjie Luo , Liesbeth M. C. Janssen

We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these…

Statistical Mechanics · Physics 2009-11-11 Mauro Merolle , Juan P. Garrahan , David Chandler

We analyse numerically thermal fluctuations of the static overlap between equilibrium configurations in a glass-forming liquid approaching the glass transition. We find that the emergence of slow dynamics near the onset temperature…

Statistical Mechanics · Physics 2013-08-23 Ludovic Berthier

Tracking experiments in dense biological tissues reveal a diversity of sources f or local energy injection at the cell scale. The effect of cell motility has been largely studied, but much less is known abo ut the effect of the observed…

Soft Condensed Matter · Physics 2017-11-29 Elsen Tjhung , Ludovic Berthier

We present a first-principles formalism for studying dynamical heterogeneities in glass forming liquids. Based on the Non-Equilibrium Self-Consistent Generalized Langevin Equation theory, we were able to describe the time-dependent local…

Soft Condensed Matter · Physics 2022-04-06 J. Lira-Escobedo , J. R. Velez-Cordero , Pedro E. Ramírez-González

Glassy behavior is a generic feature of electrons close to disorder-driven metal-insulator transitions. Deep in the insulating phase, electrons are tightly bound to impurities, and thus classical models for electron glasses have long been…

Strongly Correlated Electrons · Physics 2009-11-10 V. Dobrosavljevic

When supercooled, liquids viscosity increases dramatically as the glass transition temperature is approached. While the physical origin of this behavior is still not understood, it is now well established that the addition of a few…

Soft Condensed Matter · Physics 2024-11-25 Victor Teboul

We show that the dynamics of kinetically constrained models of glass formers takes place at a first-order coexistence line between active and inactive dynamical phases. We prove this by computing the large-deviation functions of suitable…

Statistical Mechanics · Physics 2009-11-13 J. P. Garrahan , R. L. Jack , V. Lecomte , E. Pitard , K. van Duijvendijk , F. van Wijland

We study the quantum version of a lattice model whose classical counterpart captures the physics of structural glasses. We discuss the role of quantum fluctuations in such systems and in particular their interplay with the amorphous order…

Disordered Systems and Neural Networks · Physics 2015-03-17 Laura Foini , Guilhem Semerjian , Francesco Zamponi

We develop a field-theoretical description of dynamical heterogeneities and fluctuations in supercooled liquids close to the (avoided) MCT singularity. Using quasi-equilibrium arguments we eliminate time from the description and we…

Statistical Mechanics · Physics 2011-09-23 Silvio Franz , Giorgio Parisi , Federico Ricci-Tersenghi , Tommaso Rizzo

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as…

Soft Condensed Matter · Physics 2009-09-29 J. M. Brader , Th. Voigtmann , M. Fuchs , R. G. Larson , M. E. Cates

Thermodynamics and kinetics are thought to be linked in glass transitions. The quantitative predictions of -relaxation activation barriers provided by the theory of glasses based on random first order transitions are compared with…

Soft Condensed Matter · Physics 2007-05-23 Jacob D. Stevenson , Peter G. Wolynes