Space-time Thermodynamics of the Glass Transition
Abstract
We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these distributions where the entropy of trajectory space is sub-extensive in time. These low action tails are a consequence of dynamic heterogeneity and an indication of phase coexistence in trajectory space. The glass transition, where the system falls out of equilibrium, is then an order-disorder phenomenon in space-time occurring at a temperature T_g which is a weak function of measurement time. We illustrate our perspective ideas with facilitated lattice models, and note how these ideas apply more generally.
Keywords
Cite
@article{arxiv.cond-mat/0501180,
title = {Space-time Thermodynamics of the Glass Transition},
author = {Mauro Merolle and Juan P. Garrahan and David Chandler},
journal= {arXiv preprint arXiv:cond-mat/0501180},
year = {2009}
}
Comments
5 pages, 4 figures