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A one-dimensional many-body model is established to mimic the charge distribution and dynamics in nonfullerene organic solar cells. Two essential issues are taken into account in the model: The alternating donor and acceptor structure and…

Materials Science · Physics 2018-12-05 Yao Yao

Electron beam induced current (EBIC) is a powerful characterization technique which offers the high spatial resolution needed to study polycrystalline solar cells. Ideally, an EBIC measurement reflects the spatially resolved quantum…

Materials Science · Physics 2014-09-26 Paul M. Haney , Heayoung P. Yoon , Prakash Koirala , Robert W. Collins , Nikolai B. Zhitenev

Record efficiency in chalcopyrite-based solar cells Cu(In,Ga)(S,Se)2 is achieved using a gallium gradient to increase the band gap of the absorber towards the back side. Although this structure has successfully reduced recombination at the…

The power conversion efficiency of an ultrathin CIGS solar cell was maximized using a coupled optoelectronic model to determine the optimal bandgap grading of the nonhomogeneous CIGS layer in the thickness direction. The bandgap of the CIGS…

Applied Physics · Physics 2020-03-17 Faiz Ahmad , Tom H. Anderson , Peter B. Monk , Akhlesh Lakhtakia

The ability to reduce energy loss at semiconductor surfaces through passivation or surface field engineering has become an essential step in the manufacturing of efficient photovoltaic (PV) and optoelectronic devices. Similarly, surface…

Drift-diffusion model is an indispensable modeling tool to understand the carrier dynamics (transport, recombination, and collection) and simulate practical-efficiency of solar cells (SCs) through taking into account various carrier…

Mesoscale and Nanoscale Physics · Physics 2017-04-20 Xingang Ren , Zishuai Wang , Wei E. I. Sha , Wallace C. H. Choy

Suppressing charge recombination is key for organic solar cells to become commercial reality. However, there is still no conclusive picture of how recombination losses are influenced by the complex nanoscale morphology. Here, new insight is…

Interpreting the impedance response of perovskite solar cells (PSC) is significantly more challenging than for most other photovoltaics. This is for a variety of reasons, of which the most significant are the mixed ionic-electronic…

The importance of considering near-field effects on photon recycling and spontaneous emission in a thermophotovoltaic device is investigated. Fluctuational electrodynamics is used to calculate external luminescence from a photovoltaic cell…

Optics · Physics 2017-08-02 John DeSutter , Rodolphe Vaillon , Mathieu Francoeur

The analytical modelling of bulk and quantum well solar cells is reviewed. The analytical approach allows explicit estimates of dominant generation and recombination mechanisms at work in charge neutral and space charge layers of the cells.…

Mesoscale and Nanoscale Physics · Physics 2012-04-25 James P. Connolly

Strong interference in ultrathin film semiconductor absorbers on metallic back reflectors has been shown to enhance the light harvesting efficiency of solar cell materials. However, metallic back reflectors are not suitable for tandem cell…

The present work revisits the recombination velocities ($s_{\mathrm{GB}}$) of minority-charge carriers determined at grain boundaries in polycrystalline absorber materials for solar cells. The equations describing $s_{\mathrm{GB}}$ as well…

Materials Science · Physics 2025-03-13 Daniel Abou-Ras , Matthias Maiberg

The photoluminescence in amorphous semiconductors decays according to power law $t^{-delta}$ at long times. The photoluminescence is controlled by dispersive transport of electrons. The latter is usually characterized by the power $alpha$…

Statistical Mechanics · Physics 2009-11-11 Kazuhiko Seki , Mariusz Wojcik , M. Tachiya

A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

There is evidence that interface recombination in Cu2ZnSnS4 solar cells contributes to the open-circuit voltage deficit. Our hybrid density functional theory calculations suggest that electron-hole recombination at the Cu2ZnSnS4/CdS…

Materials Science · Physics 2019-01-23 Ji-Sang Park , Sunghyun Kim , Samantha N. Hood , Aron Walsh

Solar photons possessing energy less than the band-gap of a single-junction solar cell can be utilized via the up-conversion (UC) of two or more photons, resulting in the emission of a single above-bandgap photon. Due to the non-linear…

This work addresses nucleation rates in systems with strong initial recombination. Initial (or `geminate') recombination is a process where a dissociated structure (anion, vortex, kink etc.) recombines with its twin brother (cation,…

Statistical Mechanics · Physics 2009-10-30 T. Christen , M. Buttiker

We derive the photovoltaic conversion efficiency limit for two-terminal tandem solar cells with a perovskite top cell and silicon bottom cell with an embedded spectrum splitter. For large-bandgap top-cells a spectrum splitter strongly…

Optics · Physics 2020-12-24 Verena Neder , Stefan W. Tabernig , Albert Polman

Effects of coupling between an molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using nonequilibrium Green's function method.…

Materials Science · Physics 2013-11-12 Kuniyuki Miwa , Mamoru Sakaue , Hideaki Kasai

Colored solar cells suffer from lower efficiency due to reflection and absorption losses by coatings. By studying different types of coatings on solar cells, the spectrum parameters impacting the solar cell efficiency were identified. A…

Applied Physics · Physics 2021-09-22 Farid Elsehrawy , Konrad Klockars , Orlando J. Rojas , Janne Halme