Related papers: Minimality via second variation for microphase sep…
We discuss the local minimality of certain configurations for a nonlocal isoperimetric problem used to model microphase separation in diblock copolymer melts. We show that critical configurations with positive second variation are local…
In this paper we collect some new observations about periodic critical points and local minimizers of a nonlocal isoperimetric problem, arising in the modeling of diblock copolymers. In the main result, by means of a purely variational…
We give a detailed description of the geometry of single droplet patterns in a nonlocal isoperimetric problem. In particular we focus on the sharp interface limit of the Ohta-Kawasaki free energy for diblock copolymers, regarded as a…
Using the delta correction to the standard free energy \cite{bc} in the elastic setting with a quadratic foundation term and some parameters, we introduce a one dimension only model for strong segregation in diblock copolymers, whose sharp…
We propose a new preconditioner for the Ohta--Kawasaki equation, a nonlocal Cahn--Hilliard equation that describes the evolution of diblock copolymer melts. We devise a computable approximation to the inverse of the Schur complement of the…
Using area-preserving curve shortening flow, and a new inequality relating the potential generated by a set to its curvature, we study a non-local isoperimetric problem which arises in the study of di-block copolymer melts, also referred to…
We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove…
We consider a nonlocal isoperimetric problem defined in the whole space $\R^N$, whose nonlocal part is given by a Riesz potential with exponent $\alpha\in(0, N-1)$. We show that critical configurations with positive second variation are…
We study a two-dimensional ternary inhibitory system derived as a sharp-interface limit of the Nakazawa-Ohta density functional theory of triblock copolymers. This free energy functional combines an interface energy favoring micro-domain…
For a diblock copolymer with total chain length $\gamma>0$ and mass ratio $m\in(-1,1)$, we consider the problem of minimizing the doubly nonlocal free energy $$ \mathcal{E}_{\varepsilon}(u) =\mathcal{H}(u) +\frac{1}{\varepsilon^{2s}}…
This is the second in a series of papers in which we derive a $\Gamma$-expansion for the two-dimensional non-local Ginzburg-Landau energy with Coulomb repulsion known as the Ohta-Kawasaki model in connection with diblock copolymer systems.…
In this paper we consider the volume-constrained minimization of a variant of the Ohta-Kawasaki functional with an anisotropic surface energy replacing the standard perimeter. Following and suitably adapting the second variation approach…
The goal of this paper is to derive in the two-dimensional case necessary and sufficient minimality conditions in terms of the second variation for the functional \[ v\mapsto\int_{\Omega}\big(|\nabla v|^{2}+\chi_{\{v>0\}}Q^{2} \big)\,dx, \]…
The Ohta-Kawasaki equation models the mesoscopic phase separation of immiscible polymer chains that form diblock copolymers, with applications in directed self-assembly for lithography. We perform a mathematical analysis of this model under…
We consider a functional which models an elastic body with a cavity. We show that if a critical point has positive second variation then it is a strict local minimizer. We also provide a quantitative estimate.
Block copolymer, a synthesized polymer material, has found many applications in industry. It is consisting of multiple sequences of monomer alternating in series with different monomer blocks. The combination of different polymers endows…
A variational model for describing the morphology of two-phase continua by allowing for the interplay between coherent and incoherent interfaces is introduced. Coherent interfaces are characterized by the microscopical arrangement of atoms…
The microphase separated morphology of a melt of a specific class of comb-coil diblock copolymers, consisting of an AB comb block and a linear homopolymer A block, is analyzed in the weak segregation limit. On increasing the length of the…
In this paper we study a new model for patterns in two dimensions, inspired by diblock copolymer melts with a dominant phase. The model is simple enough to be amenable not only to numerics but also to analysis, yet sophisticated enough to…
We study a geometric variational problem for sets in the plane in which the perimeter and a regularized dipolar interaction compete under a mass constraint. In contrast to previously studied nonlocal isoperimetric problems, here the…