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We study the minimizers of a degenerate case of the Ohta-Kawasaki energy, defined as the sum of the perimeter and a Coulombic nonlocal term. We start by investigating radially symmetric candidates which give us insights into the asymptotic…

Optimization and Control · Mathematics 2024-09-16 Qiang Du , James M. Scott , Zirui Xu

We consider, in a $D-$dimensional cylinder, a non--local evolution equation that describes the evolution of the local magnetization in a continuum limit of an Ising spin system with Kawasaki dynamics and Kac potentials. We consider…

Analysis of PDEs · Mathematics 2015-05-28 Eric A. Carlen , Enza Orlandi

We examine a non-local diffuse interface energy with Coulomb repulsion in three dimensions inspired by the Thomas-Fermi-Dirac-von Weizs\"{a}cker, and the Ohta-Kawasaki models. We consider the corresponding mass-constrained variational…

Analysis of PDEs · Mathematics 2024-01-09 Lorena Aguirre Salazar , Xin Yang Lu , Jun-cheng Wei

The paper is devoted to deriving novel second-order necessary and sufficient optimality conditions for local minimizers in rather general classes of nonsmooth unconstrained and constrained optimization problems in finite-dimensional spaces.…

Optimization and Control · Mathematics 2025-01-07 Pham Duy Khanh , Vu Vinh Huy Khoa , Boris S. Mordukhovich , Vo Thanh Phat

We consider a variational model for periodic partitions of the upper half-space into three regions, where two of them have prescribed volume and are subject to the geometrical constraint that their union is the subgraph of a function, whose…

Analysis of PDEs · Mathematics 2022-10-19 Marco Bonacini , Riccardo Cristoferi

The derivation of density functional energies from the random phase approximation of self-consistent mean field theory is generalized and applied to a binary blend of diblock copolymers and homopolymers. A nonlocal transformation is…

Soft Condensed Matter · Physics 2023-07-04 Sulin Wang , Yuan Chen , Zengqiang Tan , Keith Promislow

We study a two-dimensional quaternary inhibitory system. This free energy functional combines an interface energy favoring micro-domain growth with a Coulomb-type long range interaction energy which prevents micro-domains from unlimited…

Analysis of PDEs · Mathematics 2023-07-25 Stanley Alama , Lia Bronsard , Xinyang Lu , Chong Wang

When two types of side chains (A,B) are densely grafted to a (stiff) backbone and the resulting bottle-brush polymer is in a solution under poor solvent conditions, an incompatibility between A and B leads to microphase separation in the…

Soft Condensed Matter · Physics 2015-05-28 Igor Erukhimovich , Panagiotis E. Theodorakis , Wolfgang Paul , Kurt Binder

In this paper, we propose second-order sufficient optimality conditions for a very general nonconvex constrained optimization problem, which covers many prominent mathematical programs.Unlike the existing results in the literature, our…

Optimization and Control · Mathematics 2022-11-24 Matus Benko , Helmut Gfrerer , Jane Ye , Jin Zhang , Jinchuan Zhou

We consider a version of Gamow's liquid drop model with a short range attractive perimeter-penalizing potential and a long-range Coulomb interaction of a uniformly charged mass in $\R^3$. Here we constrain ourselves to minimizing among the…

Analysis of PDEs · Mathematics 2021-08-11 Patrick Dondl , Matteo Novaga , Stephan Wojtowytsch , Steve Wolff-Vorbeck

A key question in the analysis of discrete models for material defects, such as vortices in spin systems and superconductors or isolated dislocations in metals, is whether information on boundary energy for a domain can be sufficient for…

Analysis of PDEs · Mathematics 2024-08-06 Adriana Garroni , Mircea Petrache , Emanuele Spadaro

This paper is concerned with a study of the classical isoperimetric problem modified by an addition of a non-local repulsive term. We characterize existence, non-existence and radial symmetry of the minimizers as a function of mass in the…

Analysis of PDEs · Mathematics 2013-10-11 Hans Knuepfer , Cyrill B. Muratov

In this paper we consider a two-dimensional copolymer consisting of a random concatenation of hydrophobic and hydrophilic monomers near a linear interface separating oil and water acting as solvents. The configurations of the copolymer are…

Probability · Mathematics 2012-02-21 E. Bolthausen , F. den Hollander , A. A. Opoku

We investigate the ordered morphologies occurring in thin-films diblock copolymer. For temperatures above the order-disorder transition and for an arbitrary two-dimensional surface pattern, we use a Ginzburg-Landau expansion of the free…

Soft Condensed Matter · Physics 2007-05-23 Yoav Tsori , David Andelman

The capacity to devise order metrics for microstructures of multiphase heterogeneous media is a highly challenging task, given the richness of the possible geometries and topologies of the phases that can arise. This investigation initiates…

Soft Condensed Matter · Physics 2022-07-20 Salvatore Torquato , Murray Skolnick , Jaeuk Kim

We consider a sharp-interface model of $ABC$ triblock copolymers, for which the surface tension $\sigma_{ij}$ across the interface separating phase $i$ from phase $j$ may depend on the components. We study global minimizers of the…

Analysis of PDEs · Mathematics 2023-05-01 Stanley Alama , Lia Bronsard , Xinyang Lu , Chong Wang

We study morphologies of thin-film diblock copolymers between two flat and parallel walls. The study is restricted to the weak segregation regime below the order-disorder transition temperature. The deviation from perfect lamellar shape is…

Soft Condensed Matter · Physics 2009-11-07 Yoav Tsori , David Andelman

We propose a nonlocal Ohta-Kawasaki model to study the nonlocal effect on the pattern formation of some binary systems with general long-range interactions. While the nonlocal Ohta-Kawasaki model displays similar bubble patterns as the…

Numerical Analysis · Mathematics 2022-04-13 Wangbo Luo , Yanxiang Zhao

We prove existence of partitions of an open set $\Omega$ with a given number of phases, which minimize the sum of the fractional perimeters of all the phases, with Dirichlet boundary conditions. In two dimensions we show that, if the…

Analysis of PDEs · Mathematics 2020-04-24 Annalisa Cesaroni , Matteo Novaga

The Ohta-Kawasaki model for diblock-copolymers is well known to the scientific community of diffuse-interface methods. To accurately capture the long-time evolution of the moving interfaces, we present a derivation of the corresponding…

Numerical Analysis · Mathematics 2024-03-11 Amlan K. Barua , Ray Chew , Shuwang Li , John Lowengrub , Andreas Münch , Barbara Wagner