English

Lamellar phase solutions for diblock copolymers with nonlocal diffusions

Analysis of PDEs 2020-11-16 v1

Abstract

For a diblock copolymer with total chain length γ>0\gamma>0 and mass ratio m(1,1)m\in(-1,1), we consider the problem of minimizing the doubly nonlocal free energy Eε(u)=H(u)+1ε2sΩW(u)dx+12Ω(γ2Δ)12(um)2dx \mathcal{E}_{\varepsilon}(u) =\mathcal{H}(u) +\frac{1}{\varepsilon^{2s}} \int_{\Omega}W(u)\,dx +\frac{1}{2}\int_{\Omega} \left|(-\gamma^{2}\Delta)^{-\frac{1}{2}}(u-m)\right|^2\,dx in a domain Ω\Omega, where H(u)\mathcal{H}(u) is a fractional HsH^s-norm with s(0,12)s\in(0,\frac12), and WW is a double-well potential. This arises in the study of micro-phase separation phenomena for diblock copolymers with nonlocal diffusions. On the unit interval, we identify the Γ\Gamma-limit as ε0+\varepsilon\to0^+, and also find explicit isolated local minimizers associated the lamellar morphology phase in the case m=0m=0, provided that the chain is sufficiently short or the nonlocal interaction is sufficiently strong (i.e. as s0+s\to0^+). We stress that such extra condition is new for the nonlocal case and is not present in the classical model. The proof, while elementary, requires a careful analysis of the nonlocal integrals.

Keywords

Cite

@article{arxiv.2011.06907,
  title  = {Lamellar phase solutions for diblock copolymers with nonlocal diffusions},
  author = {Hardy Chan and Masomeh Jamshid Nejad and Juncheng Wei},
  journal= {arXiv preprint arXiv:2011.06907},
  year   = {2020}
}

Comments

27 pages

R2 v1 2026-06-23T20:10:39.721Z