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Using density functional theory, we present a comparative study of the electronic properties of BN-doped graphene monolayer, bilayer, trilayer, and multilayer systems. In addition, we address a superlattice of pristine and BN-doped…

Mesoscale and Nanoscale Physics · Physics 2014-02-25 T. P. Kaloni , R. P. Joshi , N. P. Adhikari , U. Schwingenschlögl

Prompted by recent reports on $\sqrt{3} \times \sqrt{3}$ graphene superlattices with intrinsic inter-valley interactions, we perform first-principles calculations to investigate the electronic properties of periodically nitrogen-doped…

Mesoscale and Nanoscale Physics · Physics 2021-02-05 Fuming Xu , Zhizhou Yu , Zhirui Gong , Hao Jin

This work investigates the electronic properties of the energy spectrum of a hybrid system composed of (i) a circular quantum dot of monolayer graphene surrounded by an infinite sheet of AA-stacked bilayer graphene and (ii) a circular…

Mesoscale and Nanoscale Physics · Physics 2021-08-02 Abdelhadi Belouad , Abdellatif Kamal , El Bouâzzaoui Choubabi , Rachid Houça , Mohammed El Bouziani

The possibility to control the commensurability and distance between graphene layers separated by a dielectric spacer is considered by the example of a heterostructure consisting of double-layer graphene separated by atomic layers of argon.…

Mesoscale and Nanoscale Physics · Physics 2013-09-24 Andrey M. Popov , Irina V. Lebedeva , Andrey A. Knizhnik , Yurii E. Lozovik , Boris V. Potapkin

It is shown that for monolayer graphene electrons are confined on a perfect two dimensional surface. The implications for the electronic properties of corrugated graphene are discussed in view of a derivation of the constrained relativistic…

Materials Science · Physics 2015-05-18 Victor Atanasov , Avadh Saxena

First-principles density functional theory (DFT) study of embedding V and Nb atom in monovacant and divacant graphene is reported. Complete/almost complete spin polarization is verified for V/Nb embedding in MV/DV graphene. The origin of…

Materials Science · Physics 2018-04-26 Jyoti Thakur , Manish K. Kashyap , Hardev S. Saini , Ali H. Reshak

The properties of graphene-like BC$_6$N semiconductor are studied using density functional theory taking into account the attractive interaction between B and N atoms. In the presence of a strong attractive interaction between B and N…

Mesoscale and Nanoscale Physics · Physics 2021-08-03 Nzar Rauf Abdullah , Botan Jawdat Abdullah , Chi-Shung Tang , Vidar Gudmundsson

Using density functional theory (DFT), Hartree-Fock, exact diagonalization, and numerical renormalization group methods we study the electronic structure of diluted hydrogen atoms chemisorbed on graphene. A comparison between DFT and…

Mesoscale and Nanoscale Physics · Physics 2012-03-07 J. O. Sofo , Gonzalo Usaj , P. S. Cornaglia , A. M. Suarez , A. D. Hernández-Nieves , C. A. Balseiro

Based on the calculation and analysis of local Green functions of impurity atoms of low concentration in a two-dimensional graphene lattice, the conditions for the formation and characteristics of local discrete levels with energies lying…

Mesoscale and Nanoscale Physics · Physics 2025-07-03 S. B. Feodosyev , V. A. Sirenko , E. S. Syrkin , E. V. Manzhelii , I. S. Bondar , K. A. Minakova

The enhanced photocatalytic performance of doped graphene(GR)/semiconductor nanocomposites have recently been widely observed, but an understanding of the underlying mechanisms behind it is still out of reach. As a model system to study the…

Computational Physics · Physics 2015-10-29 Chao-Ni He , Wei-Qing Huang , Liang Xu , Yin-Cai Yang , Bing-Xin Zhou , Gui-Fang Huang , P. Peng , Wu-Ming Liu

We derive electronic structure models for weakly interacting bilayers such as graphene-graphene and graphene-hexagonal boron nitride, based on density functional theory calculations followed by Wannier transformation of electronic states.…

Mesoscale and Nanoscale Physics · Physics 2016-06-28 Shiang Fang , Efthimios Kaxiras

Graphene clusters consisting of 24 to 150 carbon atoms and hydrogen termination at the zigzag boundary edges have been studied, as well as clusters disordered by vacancy(s). Density Function Theory and Gaussian03 software were used to…

Mesoscale and Nanoscale Physics · Physics 2012-11-21 N. Kheirabadi , A. Shafiekhani

Fabrication of ordered structures at the nanoscale limit poses a cornerstone challenge for modern technologies. In this work we show how naturally occurring moir\'e patterns in Ir(111)-supported graphene template the formation of 2D ordered…

Density-functional theory calculations with spin-polarized generalized gradient approximation and Hubbard $U$ correction is carried out to investigate the mechanical, structural, electronic and magnetic properties of graphitic heptazine…

Recent progress in preparing well controlled 2D van der Waals heterojunctions has opened up a new frontier in materials physics. In this paper we address the intriguing energy gaps that are sometimes observed when a graphene sheet is placed…

Mesoscale and Nanoscale Physics · Physics 2015-02-23 Jeil Jung , Ashley DaSilva , Allan H. MacDonald , Shaffique Adam

The interaction between substitutional nitrogen atoms in graphene is studied by performing first principles calculations. The nearest neighbor interaction between nitrogen dopants is highly repulsive because of the strong electrostatic…

Materials Science · Physics 2015-03-19 Hongjun Xiang , Bing Huang , Zhenyu Li , Su-Huai Wei , Jinlong Yang , Xingao Gong

By using first principles calculations we report a chemical doping induced gap in graphene. The structural and electronic properties of CrO$_3$ interacting with graphene layer are calculated using ab initio methods based on the density…

Materials Science · Physics 2007-11-08 I. Zanella S. Guerini , S. B. Fagan , J. Mendes Filho , A. G. Souza Filho

Although iron-based single atom catalysts are regarded as a promising alternative to precious metal catalysts, their precise electronic structures during catalysis still pose challenges for computational descriptions. A particularly urgent…

Materials Science · Physics 2024-11-07 Young-Joon Song , Charlotte Gallenkamp , Genís Lleopart , Vera Krewald , Roser Valentí

First-principles calculations of the effect of carbon coverage on the atomic, electronic and magnetic structure of nickel and iron substrates demonstrate insignificant changes in the interatomic distances and magnetic moments on the atoms…

Materials Science · Physics 2014-12-24 D. W. Boukhvalov , Yu. N. Gornostyrev , M. A. Uimin , A. V. Korolev , A. Ye Yermakov

Heterostructures made of stacked 2D materials with different electronic properties are studied for their potential in creating multifunctional devices. Graphene (G) and hexagonal boron nitride (h-BN) van der Waals (vdW) systems have been…

Materials Science · Physics 2023-03-16 D. P. de Andrade Deus , J. M. J. Lopes , Roberto H. Miwa
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