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Atomic-scale fabrication is an outstanding challenge and overarching goal for the nanoscience community. The practical implementation of moving and fixing atoms to a structure is non-trivial considering that one must spatially address the…

We report {\it ab initio} calculations of the structural, electronic and magnetic properties of a graphene monolayer substitutionally doped with Co (Co$_{sub}$) atoms. We focus in Co because among traditional ferromagnetic elements (Fe, Co…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 E. J. G. Santos , D. Sanchez-Portal , A. Ayuela

Doping of the graphene lattice with transition metal atoms resulting in high magnetic anisotropy energy (MAE) is an important goal of materials research owing to its potential application in spintronics. In this article, by using…

We theoretically investigate the electronic structures of moir\'{e} superlattices arising in monolayer / bilayer graphene stacked on hexagonal boron nitride (hBN) in presence and absence of magnetic field. We develop an effective continuum…

Mesoscale and Nanoscale Physics · Physics 2014-10-10 Pilkyung Moon , Mikito Koshino

A novel crystalline structure of hybrid monolayer hexagonal boron nitride (BN) and graphene is predicted by means of the first-principles calculations. This material can be derived via boron or nitrogen atoms substituted by carbon atoms…

Mesoscale and Nanoscale Physics · Physics 2013-10-25 Jinyun Li , Daqiang Gao , Xiaoning Niu , Mingsu Si , Desheng Xue

First principles based DFT calculations performed to insight structural and electronic properties of Boron doped Magnesium atom decorated graphene sheet for application of hydrogen storage. The four H2 molecules stably binds magnesium atom…

Materials Science · Physics 2020-03-31 Baliram Lone

The ability to perform first-principles calculations of electronic and vibrational properties of two-dimensional heterostructures in a field-effect setup is crucial for the understanding and design of next-generation devices. We present…

Materials Science · Physics 2017-09-06 Thibault Sohier , Matteo Calandra , Francesco Mauri

Understanding the magnetic properties of graphenic nanostructures is instrumental in future spintronics applications. These magnetic properties are known to depend crucially on the presence of defects. Here we review our recent theoretical…

Mesoscale and Nanoscale Physics · Physics 2013-04-02 Elton J. G. Santos , Andres Ayuela , Daniel Sanchez-Portal

The electronic properties of hydrogenated graphenes are investigated with the first-principles calculations. Geometric structures, energy bands, charge distributions, and density of states (DOS) strongly depend on the different…

Materials Science · Physics 2015-10-09 Hao-Chun Huang , Shih-Yang Lin , Chung-Lin Wu , Ming-Fa Lin

The structures, cohesive energies and HOMO-LUMO gaps of graphene nanoflakes and corresponding polycyclic aromatic hydrocarbons for a large variety of size and topology are investigated at the density functional based tight-binding level.…

Materials Science · Physics 2013-02-27 Agnieszka Kuc , Thomas Heine , Gotthard Seifert

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

Graphene and boron nitride (GPBN) heterostructures provide a viable way to realize tunable bandgap, promising new opportunities in graphene-based nanoelectronic and optoelectronic devices. In the present study, we investigated the interplay…

Materials Science · Physics 2015-03-10 Bin Ouyang , Fanchao Meng , Jun Song

While graphene is a semi-metal, a recently synthesized hydrogenated graphene called graphane, is an insulator. We have probed the transformation of graphene upon hydrogenation to graphane within the framework of density functional theory.…

Mesoscale and Nanoscale Physics · Physics 2012-10-05 Prachi Chandrachud , Bhalchandra S Pujari , Soumyajyoti Haldar , Biplab Sanyal , D G Kanhere

The electron-phonon interaction in monolayer graphene is investigated by using density functional perturbation theory. The results indicate that the electron-phonon interaction strength is of comparable magnitude for all four in-plane…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 K. M. Borysenko , J. T. Mullen , E. A. Barry , S. Paul , Y. G. Semenov , J. M. Zavada , M. Buongiorno Nardelli , K. W. Kim

The significant halogenation effects on the essential properties of graphene are investigated by the first-principles method. The geometric structures, electronic properties, and magnetic configurations are greatly diversified under the…

Mesoscale and Nanoscale Physics · Physics 2017-06-08 Ngoc Thanh Thuy Tran , Duy Khanh Nguyen , Glukhova O. E. , Ming-Fa Lin

Defects change essentially not only electronic but also chemical properties of graphene being centers of its chemical activity. Their functionalization is a way to modify electronic and crystal structure of graphene which may be important…

Materials Science · Physics 2009-01-05 D. W. Boukhvalov , M. I. Katsnelson

We investigated theoretically the effect of covalent edge functionalization, with organic functional groups, on the electronic properties of graphene nanostructures and nano-junctions. Our analysis shows that functionalization can be…

Materials Science · Physics 2012-03-30 Caterina Cocchi , Alice Ruini , Deborah Prezzi , Marilia J. Caldas , Elisa Molinari

It is shown, by DFT calculations, that the uniform functionalization of upper layer of graphite by hydrogen or fluorine does not change essentially its bonding energy with the underlying layers, whereas the functionalization by phenyl…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 D. W. Boukhvalov , M. I. Katsnelson

We present a detailed numerical study of the electronic properties of single-layer graphene with resonant ("hydrogen") impurities and vacancies within a framework of noninteracting tight-binding model on a honeycomb lattice. The algorithms…

Mesoscale and Nanoscale Physics · Physics 2010-09-29 Shengjun Yuan , Hans De Raedt , Mikhail I. Katsnelson

Bilayer graphene nanoribbon with zigzag edge is investigated with the tight binding model. Two stacking structures, alpha and beta, are considered. The band splitting is seen in the alpha structure, while the splitting in the wave number…

Mesoscale and Nanoscale Physics · Physics 2012-03-13 Kikuo Harigaya , Hiroshi Imamura