Related papers: Why is the ground state electron configuration for…
Bohr's model agreed with the hydrogen spectrum results, but did not agree with the spectrum of Helium. Here we show that Bohr's model-based methods can calculate the experimental value (-79.005 eV) of Helium ground state energy correctly.…
$R$-matrix calculations of the electron collisions with lithium atom at energies below the $3s$ excitation threshold are presented. The $^1S^e$, $^3S^e$ and $^1P^o$ phase shifts calculated in the near-threshold energy range are in excellent…
We show the existence of bound two-electron states in an almost depleted two-dimensional island. These two-electron states are carried by special compact configurations of four single-electron levels. The existence of these states does not…
Lithium titanium oxide Li$_4$Ti$_5$O$_{12}$ (LTO) is an intriguing anode material promising particularly long lived batteries, due to its remarkable phase stability during (dis)charging of the cell. However, its usage is limited by its low…
Materials in which electrons occupy interstitial sites as anions are called electrides and exhibit unusual dimensionality-dependent electronic behavior. These properties make electrides attractive for catalysis, transparent conductors, and…
At a very low temperature of 9mK, electrons in the 2nd Landau level of an extremely high mobility two-dimensional electron system exhibit a very complex electronic behavior. With varying filling factor, quantum liquids of different origins…
For superheavy elements with atomic numbers $120\leq Z \leq 170$, the concept of the ground-state configuration is being reexamined. To this end, relativistic calculations of the electronic structure of the low-lying levels are carried out…
The electric dipole polarizabilities and hyperpolarizabilities for the lithium isotopes $^6$Li and $^7$Li in the ground state $2^2S$ and the excited states $2^2P$ and $3^2D$, as well as the leading resonance and dispersion long-range…
The non-relativistic interacting electron gas in an external field of positively charged massive cores is dealt with in the scheme of second quantization. Ladder operators that change between stationary states of contiguous energy…
We show that, in the high-density limit, restricted M{\o}ller-Plesset (RMP) perturbation theory yields $E_{\text{RMP}}^{(2)} = \pi^{-2}(1-\ln 2) \ln r_s + O(r_s^0)$ for the correlation energy per electron in the uniform electron gas, where…
Two- and three-dimensional electron gases with a uniform neutralizing background are studied at negative compressibility. Parametrized expressions for the dielectric function are used to access this strong-coupling regime, where the…
The electronic structure of singly ionized tin (SnII) is partly a one-electron and partly a three-electron system with ground configuration 5s25p. The excited configurations are of the type 5s2nl in the one-electron part, and 5s5p2, 5p3 and…
Outer crusts of neutron stars and interiors of cool white dwarfs consist of bare atomic nuclei, arranged in a crystal lattice and immersed in a Fermi gas of degenerate electrons. We study electrostatic properties of such Coulomb crystals,…
We study the ground state of a clean two-dimensional electron liquid in a weak magnetic field where $N \gg 1$ lower Landau levels are completely filled and the upper level is partially filled. It is shown that the electrons at the upper…
A nonperturbative numerical evaluation of the one-photon electron self energy for the K- and L-shell states of hydrogenlike ions with nuclear charge numbers Z=1 to 5 is described. Our calculation for the 1S state has a numerical uncertainty…
Electronic correlations associated with incipient magnetism have long been recognized as an important factor in stabilizing the largest atomic volume $\delta$ phase of plutonium, yet their strength compared to those in the rare earths and…
We have performed a comprehensive study of the singlet ground state of two electrons on the surface of a sphere of radius $R$. We have used electronic structure models ranging from restricted and unrestricted Hartree-Fock theory to…
Starting from the recently derived expression for the chemical potential of the electron gas on a 1D lattice,and a well known thermodynamical relation,we have derived the equation of state and the specific heat of the electron gas on a 1D…
The helium ground state nonrelativistic energy with 24 significant digits is presented. The calculations are based on variational expansion with randomly chosen exponents. This data can be used as a benchmark for other approaches for many…
We investigate the properties of the ground state of a system of interacting bosons on regular lattices with coordination number $k\geq 2$. The interaction is a pure, infinite, on-site repulsion. Our concern is to give an improved upper…