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Atomic motion dynamics during structural changes or chemical reactions have been visualized by picosecond and femtosecond pulsed electron beams via ultrafast electron diffraction and microscopy. Imaging the even faster dynamics of electrons…

Optics · Physics 2019-05-15 Martin Kozák , Norbert Schönenberger , Peter Hommelhoff

Recolliding electrons are responsible for many of the interesting phenomena observed in the interaction of strong laser fields with atoms and molecules. We show that in multielectron targets such as C60 a new important recollision pathway…

Atomic Physics · Physics 2009-11-13 M. Ruggenthaler , S. V. Popruzhenko , D. Bauer

We investigate dynamics of atomic and molecular systems exposed to intense, shaped chaotic fields and a weak femtosecond laser pulse theoretically. As a prototype example, the photoionization of a hydrogen atom is considered in detail. The…

Quantum Physics · Physics 2015-05-18 Kamal P Singh , Jan M Rost

Measuring the delay for an electron to emerge from different states is one of the major achievements of attosecond science. This delay can have two origins - the electron wave packet is reshaped during departure by the electrostatic field…

Atomic Physics · Physics 2020-10-14 Graham G. Brown , Dong Hyuk Ko , Chunmei Zhang , P. B. Corkum

We discuss the influence of periodic orbits on the dissociation of a model diatomic molecule driven by a strong bichromatic laser fields. Through the stability of periodic orbits we analyze the dissociation probability when parameters like…

Chaotic Dynamics · Physics 2009-11-13 S. Huang , C. Chandre , T. Uzer

Realistic attosecond wave packets have complex profiles that, in dispersive conditions, rapidly broaden or split into multiple components. Such behaviors are encoded in sharp features of the wave packet spectral phase. Here, we exploit the…

Strong ultrashort laser pulses give rise to prompt molecular alignment followed by full, half and quarter quantum revivals of the rotational wave packets. In Four Wave Mixing (FWM) experiments, we make use of the long succession of…

Quantum Physics · Physics 2007-05-23 Sharly Fleischer , I. Sh. Averbukh , Yehiam Prior

We examine x-ray scattering from an isolated organic molecule from the linear to nonlinear absorptiveregime. In the nonlinear regime, we explore the importance of both the elastic and inelastic channelsand observe the onset of nonlinear…

Chemical Physics · Physics 2021-06-09 Phay J. Ho , Adam E. A. Fouda , Kai Li , Gilles Doumy , Linda Young

This paper concerns the theory of non-recollisional ionization or detachment of atoms or ions by intense few-cycle pulses. It is shown that in certain conditions of pulse duration, peak intensity and carrier-envelope phase, the ionization…

Atomic Physics · Physics 2014-09-04 C. C. Chirila , R. M. Potvliege

Asymmetric molecules look different when viewed from one side or the other. This difference influences the electronic structure of the valence electrons, thereby giving stereo sensitivity to chemistry and biology. We show that attosecond…

Electron motion on the (sub-)femtosecond time scale constitutes the fastest response in many natural phenomena such as light-induced phase transitions and chemical reactions. Whereas static electron densities in single molecules can be…

Observing the motion of the nuclear wavepackets during a molecular reaction, in both space and time, is crucial for understanding and controlling the outcome of photoinduced chemical reactions. We have imaged the motion of a vibrational…

Attosecond photoemission or photoionization delays are a unique probe of the structure and the electronic dynamics of matter. However, spectral congestion and spatial delocalization of valence electron wave functions set fundamental limits…

Strong field photoemission and electron recollision provide a viable route to extract electronic and nuclear dynamics from molecular targets with attosecond temporal resolution. However, since an {\em ab-initio} treatment of even the…

Atomic Physics · Physics 2016-11-02 N. Suárez , A. Chacón , M. F. Ciappina , B. Wolter , J. Biegert , M. Lewenstein

A novel polarization-modulation transient method has been developed for studying fast anisotropic relaxation in electronic excited states of polyatomic and biologically relevant molecules under excitation with femtosecond laser pulses. The…

Chemical Physics · Physics 2020-05-12 Ioanna Gorbunova , Nikolay Bezverkhnii , Maxim Sasin , Idris Gagzhiev , Oleg Vasyutinskii

We explore the novel capabilities offered by attosecond extreme ultraviolet and x-ray pulses that can be now generated by free-electron lasers and high-harmonics generation sources for probing photon-induced electron dynamics in molecules.…

Quantum Physics · Physics 2023-02-15 Marvin Reuner , Daria Popova-Gorelova

We report the first observation of free-electron angular momentum wave packets generated by atomic multiphoton ionization with bichromatic three-dimensional (3D) polarization-tailored ultrashort laser fields. These fields, created by the…

Atomic Physics · Physics 2025-11-25 Darius Köhnke , Hans-Christian Ahlswede , Tim Bayer , Matthias Wollenhaupt

We studied the recollision dynamics between the electrons and D$_2^+$ ions following the tunneling ionization of D$_2$ molecules in an intense short pulse laser field. The returning electron collisionally excites the D$_2^+$ ion to excited…

Atomic Physics · Physics 2009-11-10 X. M. Tong , Z. X. Zhao , C. D. Lin

We present experimental results for the ionization of aniline and benzene molecules subjected to intense ultrashort laser pulses. Measured parent molecular ions yields were obtained using a recently developed technique capable of…

We propose a protocol to probe the ultrafast evolution and dephasing of coherent electronic excitation in molecules in the time domain by the intrinsic streaking field generated by the molecule itself. Coherent electronic motion in the…

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