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The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

The metal-insulator transition (MIT) in vanadium dioxide VO$_2$ due to V-V dimerization has been extensively discussed for decades. While it is widely acknowledged that electron correlations, Peierls instabilities, and molecular orbital…

Strongly Correlated Electrons · Physics 2024-03-12 Shunsuke Kitou , Akitoshi Nakano , Masato Imaizumi , Yuiga Nakamura , Ichiro Terasaki , Taka-hisa Arima

We report neutron powder diffraction measurements on a series of NaxCoO2 samples with x near 0.75 which were prepared under different synthesis conditions. Two different crystal structures for the samples are observed at room temperature.…

Strongly Correlated Electrons · Physics 2012-04-12 Q. Huang , B. Khaykovich , F. C. Chou , J. H. Cho , J. W. Lynn , Y. S. Lee

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

We report a thorough study of Y$_{0.7}$La$_{0.3}$VO$_3$ single crystals by measuring magnetic properties, specific heat, thermal conductivity, x-ray and neutron diffraction with the motivation of revealing the lattice response to the…

Strongly Correlated Electrons · Physics 2019-12-04 J. -Q. Yan , W. Tian , H. B. Cao , S. Chi , F. Ye , A. Llobet , Q. Chen , J. Ma , Y. Ren , J. -G. Cheng , J. -S. Zhou , M. A. McGuire , R. J. McQueeney

Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…

Coexistence of mutually influencing ferroelectric and magnetic ordering at low temperature in hexagonal phase of rare-earth manganites gives rise to interesting physical phenomena. Here, we report a detailed analysis of powder neutron…

Materials Science · Physics 2014-05-13 A. K. Singh , S. D. Kaushik , V. Siruguri , S. Patnaik

Synchrotron X-ray diffraction investigations of two single crystals of Na_xCoO_2 from different batches with composition x = 0.525-0.530 reveal homogeneous incommensurate sodium ordering with propagation vector (0.53 0.53 0) at…

Strongly Correlated Electrons · Physics 2010-07-16 R. Feyerherm , E. Dudzik , S. Valencia , A. U. B. Wolter , C. J. Milne , S. Landsgesell , D. Alber , D. N. Argyriou

CsCuCl$_3$, chiral and Jahn-Teller distorted at room temperature, takes a more symmetric structure above 423K. Describing this 'simpler' high temperature structure is far from simple and has been the subject of many, sometimes…

Materials Science · Physics 2026-05-28 Emma A. Pappas , Toby Woods , Jue Liu , Daniel P. Shoemaker

(BiFeO3)(1-x){\Lambda}/(LaFeO3)x{\Lambda} superlattices (SLs) with varying x have been grown by pulsed laser deposition on (111) oriented SrTiO3 substrates. In order to obtain good epitaxy and flat samples a conducting SrRuO3 buffer has…

Materials Science · Physics 2019-01-08 J. Belhadi , S. Yousfi , H. Bouyanfif , M. El Marssi

Polarization dependent vanadium L edge X-ray absorption spectra of BaVS$_3$ single crystals are measured in the four phases of the compound. The difference between signals with the polarization \textbf{E}$\perp$\textbf{c} and…

The sol-gel prepared (1-x) Na0.5Bi0.5TiO3- (x) CaMnO3 (x=0, 0.03, 0.06, 0.12) compositions show a Rhombohedral (R3c) phase for x=0.06 while a mixed Rhombohedral (R3c) and orthorhombic (Pnma) phases for the x=0.12. The lattice volume…

X-ray diffraction, dynamical mechanical analysis and infrared reflectivity studies revealed an antiferrodistortive phase transition in EuTiO3 ceramics. Near 300K the perovskite structure changes from cubic Pm-3m to tetragonal I4/mcm due to…

Results of X-ray diffraction experiments on solid oxygen at low temperature and at pressures up to 10 GPa are presented.A careful sample preparation and annealing around 240 K allowed to obtain very good diffraction patterns in the…

Materials Science · Physics 2009-11-07 Federico A. Gorelli , Mario Santoro , Lorenzo Ulivi , Michael Hanfland

The existing controversy about the room temperature structure of multiferroic Pb(Fe_1/2Nb_1/2)O_3 is settled using synchrotron powder x-ray diffraction data. Results of Rietveld refinements in the temperature range 300 to 12K reveal that…

Materials Science · Physics 2007-06-06 Satendra Pal Singh , Dhananjai Pandey , Songhak Yoon , Sunggi Baik , Namsoo Shin

High-pressure synchrotron based angle dispersive x-ray diffraction (ADXRD) studies were carried out on SmGdO3 (SGO) up to 25.7GPa at room temperature. ADXRD results indicated a reversible pressure-induced phase transition from ambient…

Materials Science · Physics 2015-06-22 Yogesh Sharma , Pankaj Misra , Satyaprakash Sahoo , A. K. Mishra , S. M. Sharma , Ram S. Katiyar

We have grown intermetallic ErPd$_2$Si$_2$ single crystals employing laser-diodes with the floating-zone method. The temperature-dependent crystallography was determined using synchrotron and in-house X-ray powder diffraction measurements…

Materials Science · Physics 2022-08-02 Kaitong Sun , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Qian Zhao , Chongde Cao , Hai-Feng Li

The vibrational properties of $\mathrm{CrI_3}$ single crystals were investigated using Raman spectroscopy and were analyzed with respect to the changes of the crystal structure. All but one mode are observed for both the low-temperature…

The crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_4 (0<x<0.7) has been studied by diffraction techniques and high resolution capacitance dilatometry. There is no evidence for a structural phase transition like those found in…

Materials Science · Physics 2009-11-10 D. Senff , P. Reutler , M. Braden , O. Friedt , D. Bruns , A. Cousson , F. Bouree , M. Merz , B. Buechner , A. Revcolevschi
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