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Controlling electronic population through chemical doping is one way to tip the balance between competing phases in materials with strong electronic correlations. Vanadium dioxide exhibits a first-order phase transition at around 338 K…

HoFe1-xMnxO3 (0 < x < 1) single crystals have been grown by the optical floating zone technique. A structural transition from the orthorhombic to hexagonal modification has been established in the crystals in the concentration range of…

The crystal structures of the Sr1-xCaxRuO3 perovskites are investigated using both long range and local structural probes. High resolution synchrotron powder X-ray diffraction characterization at ambient temperature shows that the materials…

Materials Science · Physics 2020-03-25 Loi T. Nguyen , Milinda Abeykoon , Jing Tao , Saul Lapidus , R. J. Cava

We investigate the magnetic structure of Mn3-xFexSn2 using neutron powder diffraction experiments and electronic structure calculations. These alloys crystallize in the orthorhombic Ni3Sn2 type of structure (Pnma) and comprise two…

Materials Science · Physics 2013-09-03 Q. Recour , V. Ban , Z. Gercsi , T. Mazet , M. Francois , B. Malaman

The effect of Mg-substitution on the crystal structure of wurtzite ZnO is presented based on synchrotron X-ray diffraction studies of polycrystalline Zn1-xMgxO (0 <= x <= 0.15). Increase in Mg concentration results in pronounced c-axis…

Materials Science · Physics 2007-05-23 Young-Il Kim , Katharine Page , Ram Seshadri

The ferrimagnetic spinel $\mathrm{CoV_2O_4}$ has been a topic of intense recent interest, both as a frustrated insulator with unquenched orbital degeneracy and as a near-itinerant magnet which can be driven metallic with moderate applied…

Strongly Correlated Electrons · Physics 2016-02-03 D. Reig-i-Plessis , D. Casavant , V. O. Garlea , A. A. Aczel , M. Feygenson , J. Neuefeind , H. D. Zhou , S. E. Nagler , G. J. MacDougall

We used temperature-dependent neutron diffraction measurements on FeVO4 to understand the temperature driven anisotropy and observed that the maximum change for a and b lattice parameters in conjunction with a large contraction in angle…

Materials Science · Physics 2019-09-04 Ajay Tiwari , Sagarmal Kumawat , Sudhindra Rayaprol , Ambesh Dixit

Temperature dependent crystal structures of the quasi-one-dimensional ladder material BaFe2Se3 are examined. Combining the optical second harmonic generation (SHG) experiments and neutron diffraction measurements, we elucidate the crystal…

A neutron powder diffraction study has been carried out on Pb(Zr0.52Ti0.48)O3 in order to resolve an ongoing controversy about the nature of the low-temperature structure of this strongly-piezoelectric and technologically-important…

Materials Science · Physics 2009-11-10 D. E. Cox , B. Noheda , G. Shirane

The effects of the cooperative Jahn-Teller effect on the crystal structure and the stability of the charge ordered (CO) state were studied by measurements of powder X-ray diffraction, resistivity, and ultrasound for Pr1-xCaxMnO3…

Strongly Correlated Electrons · Physics 2009-11-10 R. K. Zheng , G. Li , Y. Yang , A. N. Tang , W. Wang , T. Qian , X. G. Li

Neutron powder diffraction studies of the crystal and magnetic structures of the magnetocaloric compound Mn1.1Fe0.9(P0.8Ge0.2) have been carried out as a function of temperature, applied magnetic field, and pressure. The data reveal that…

Materials Science · Physics 2009-11-30 D. M. Liu , Q. Huang , M. Yue , J. W. Lynn , L. J. Liu , Y. Chen , Z. H. Wu , J. X. Zhang

The crystal and magnetic structure of (La0.70Ca0.30)(CryMn1-y)O3 for y = 0.70, 0.50 and 0.15 has been investigated using neutron powder diffraction. The three samples crystallize in the Pnma space group at both 290 K and 5 K and exhibit…

We report investigation of structural phase transitions in technologically important material sodium niobate as a function of temperature on heating over 300-1075 K. Our high resolution powder neutron diffraction data show variety of…

Materials Science · Physics 2015-05-20 S. K. Mishra , R. Mittal , V. Yu. Pomjakushin , S. L. Chaplot

Temperature-dependent synchrotron powder diffraction on Cs0.83(Fe0.86Se)2 revealed first order I4/m to I4/mmm structural transformation around 216{\deg}C associated with the disorder of the Fe vacancies. Irreversibility observed during the…

Materials Science · Physics 2011-11-01 V. Svitlyk , D. Chernyshov , E. Pomjakushina , A. Krzton-Maziopa , K. Conder , V. Pomjakushin , V. Dmitriev

Vanadium Sesquioxide (V$_2$O$_3$) is an antiferromagnetic insulator below $T_{\mathrm N}\approx$ 155 K. The magnetic order is not of C- or G-type as one would infer from the bipartite character of the hexagonal basal plane in the…

Materials Science · Physics 2015-08-19 Daniel Grieger , Michele Fabrizio

The structural, magnetic and resistive properties of (La1-yYy)FeAsO compounds (y = 0.10, 0.20, 0.30) have been investigated by means of X-ray and neutron powder diffraction as well as by resistivity measurements. The temperatures at which…

Materials Science · Physics 2015-05-14 A. Martinelli , A. Palenzona , M. Tropeano , C. Ferdeghini , M. R. Cimberle , C. Ritter

We study the structural evolution of Sr$_3$Ir$_2$O$_7$ as a function of pressure using x-ray diffraction. At a pressure of 54 GPa at room temperature, we observe a first-order structural phase transition, associated with a change from…

The effect of electron doping on the structural, transport, and magnetic properties of Mn (IV) - rich Ca1-xYxMnO3 (x < 0.2) samples have been investigated using neutron diffraction, neutron depolarization, magnetization and resistivity…

Materials Science · Physics 2016-02-09 Neetika Sharma , A. Das , C. L. Prajapat , Amit Kumar , M. R. Singh

The crystal structure of KAgF3 was studied by powder neutron diffraction. KAgF3 exhibits at all temperatures an orthorhombic symmetry in space group Pnma that allows for several distortions with respect to the ideal cubic perovskite…

Structural and physical properties determined by measurements on large single crystals of the anisotropic ferromagnet MnBi are reported. The findings support the importance of magneto-elastic effects in this material. X-ray diffraction…

Materials Science · Physics 2014-11-19 Michael A. McGuire , Huibo Cao , Bryan C. Chakoumakos , Brian C. Sales