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We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…

Soft Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

We investigate the influence of multiscale aggregation and deposition on the colloidal dynamics in a saturated porous medium. At the pore scale, the aggregation of colloids is modeled by the Smoluchowski equation. Essentially, the colloidal…

Analysis of PDEs · Mathematics 2014-04-17 Oleh Krehel , Adrian Muntean , Peter Knabner

Asymptotic multiple scale homogenisation allows to determine the effective behaviour of a porous medium by starting from the pore-scale description, when there is a large separation between the pore-scale and the macroscopic scale. When the…

Classical Physics · Physics 2019-03-06 Pascale Royer

Nonequilibrium interfacial thermodynamics is formulated in the presence of surface reactions for the study of diffusiophoresis in isothermal systems. As a consequence of microreversibility and Onsager-Casimir reciprocal relations,…

Chemical Physics · Physics 2018-12-24 Pierre Gaspard , Raymond Kapral

We derive diffusive macroscopic equations for the particle and energy density of a system whose time evolution is described by a kinetic equation for the one particle position and velocity function f(r,v,t) that consists of a part that…

Statistical Mechanics · Physics 2018-11-14 Pedro L. Garrido , Joel L. Lebowitz

A thermodynamically consistent visco-elastodynamical model at finite strains is derived that also allows for inelasticity (like plasticity or creep), thermal coupling, and poroelasticity with diffusion. The theory is developed in the…

Mathematical Physics · Physics 2024-04-17 Alexander Mielke , Tomáš Roubíček

Self-similar solutions of the coherent diffusion equation are derived and measured. The set of real similarity solutions is generalized by the introduction of a nonuniform phase surface, based on the elegant Gaussian modes of optical…

Quantum Physics · Physics 2015-05-19 O. Firstenberg , P. London , D. Yankelev , R. Pugatch , M. Shuker , N. Davidson

It is shown that the critical properties of a recently studied model for non-equilibrium wetting are robust if one extends the dynamic rules by single-particle diffusion on terraces of the wetting layer. Examining the behavior at the…

Statistical Mechanics · Physics 2016-08-16 S. Rössner , H. Hinrichsen

The kinetics of the deposition of colloidal particles onto a solid surface is analytically studied. We take into account both the diffusion of particles from the bulk as well as the geometrical aspects of the layer of adsorbed particles. We…

Statistical Mechanics · Physics 2009-10-30 P. Wojtaszczyk , J. B. Avalos , J. M. Rubi

We consider a nonlinear drift-diffusion system for multiple charged species in a porous medium in 2D and 3D with periodic microstructure. The system consists of a transport equation for the concentration of the species and Poisson's…

Analysis of PDEs · Mathematics 2022-06-16 Apratim Bhattacharya , Markus Gahn , Maria Neuss-Radu

Generative diffusion models apply the concept of Langevin dynamics in physics to machine leaning, attracting a lot of interests from engineering, statistics and physics, but a complete picture about inherent mechanisms is still lacking. In…

Statistical Mechanics · Physics 2025-01-07 Zhendong Yu , Haiping Huang

We consider a model for driven particulate matter in which absorbing states can be reached both by particle isolation and by particle caging. The model predicts a non-equilibrium phase diagram in which analogues of hydrodynamic and elastic…

Soft Condensed Matter · Physics 2020-03-04 Christopher Ness , Michael E. Cates

In this article we address the problem of the nonlinear interaction of subdiffusive particles. We introduce the random walk model in which statistical characteristics of a random walker such as escape rate and jump distribution depend on…

Statistical Mechanics · Physics 2015-06-15 Sergei Fedotov

Heterogeneous media diffusion is often described using position-dependent diffusion coefficients and estimated indirectly through mean squared displacement in experiments. This approach may overlook other mechanisms and their interaction…

Statistical Mechanics · Physics 2023-09-11 Haroldo V. Ribeiro , Angel A. Tateishi , Ervin K. Lenzi , Richard L. Magin , Matjaz Perc

We present a theoretical and computational model for the behavior of a porous solid undergoing two interdependent processes, the finite deformation of a solid and species migration through the solid, which are distinct in bulk and on…

Soft Condensed Matter · Physics 2023-05-16 Jaemin Kim , Ida Ang , Francesco Ballarin , Chung-Yuen Hui , Nikolaos Bouklas

We present a thermodynamically consistent mesoscopic model of protein adsorption at liquid-solid interfaces. First describing the equilibrium state under varying protein concentration of the solution and binding conditions, we predict a…

Soft Condensed Matter · Physics 2016-08-31 Gergely J. Szollosi , Imre Derenyi , Janos Voros

Energy transfer in small nanosized systems can be very different from that in their macroscopic counterparts due to reduced dimensionality, interaction with surfaces, disorder, and large fluctuations. Those ingredients may induce…

Statistical Mechanics · Physics 2023-04-05 Giuliano Benenti , Davide Donadio , Stefano Lepri , Roberto Livi

When a fluid carrying a passive solute flows quickly through porous media, three key macroscale transport mechanisms occur. These mechanisms are diffusion, advection and dispersion, all of which depend on the microstructure of the porous…

Fluid Dynamics · Physics 2024-10-16 Lucy C Auton , Mohit P. Dalwadi , Ian M. Griffiths

In the context of transpiration cooling, a 1D porous medium model consisting of a temperature system and a mass-momentum system is derived from the 2D/3D Darcy-Forchheimer equations. The temperatures of the coolant and the solid are assumed…

Fluid Dynamics · Physics 2022-08-30 Siegfried Müller , Michael Rom

We consider the theoretical description of a fluid adsorbed in a nanopore. Hysteresis and discontinuities in the isotherms in general hampers the determination of equilibrium thermodynamic properties, even in computer simulations. A…

Soft Condensed Matter · Physics 2015-06-18 Joël Puibasset , Edouard Kierlik , Gilles Tarjus