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Computational identification of unknown adsorption and desorption rates is discussed in conjunction with reactive flow considered at pore scale. The reactive transport is governed by incompressible Stokes equations, coupled with…

Numerical Analysis · Mathematics 2019-12-10 Vasiliy V. Grigoriev , Oleg Iliev , Petr N. Vabishchevich

The problem of diffusion in a porous medium with a spatially varying porosity is considered. The particular microstructure analyzed comprises a collection of impenetrable spheres, though the methods developed are general. Two different…

Fluid Dynamics · Physics 2017-10-12 Maria Bruna , S. Jonathan Chapman

We analyze the Fick's diffusion of a gas inside porous nanomaterials through the one-dimensional diffusion equation in nanopores for various cases of boundary conditions for homogeneous and non-homogeneous problems. We study the diffusion…

Soft Condensed Matter · Physics 2019-07-25 Leandro N. Acquaroli

The hindered diffusion model is introduced. It is a continuum model giving the dynamics of a conserved density. Similar to the spin-facilitated models, the kinetics are hindered by a fluctuating diffusion coefficient that decreases as the…

Statistical Mechanics · Physics 2007-05-23 Gene F Mazenko

In this work we study the transport properties of non-interacting overdamped particles, moving on tilted disordered potentials, subjected to Gaussian white noise. We give exact formulas for the drift and diffusion coefficients for the case…

Statistical Mechanics · Physics 2014-09-04 Raul Salgado-Garcia

The diffusion and low vibrational motions of adsorbates on surfaces can be well described by a purely stochastic model, the so-called interacting single adsorbate model, for low-moderate coverages (\theta \lesssim 0.12). Within this model,…

Statistical Mechanics · Physics 2010-02-16 R. Martinez-Casado , A. S. Sanz , G. Rojas-Lorenzo , S. Miret-Artes

Using an analytically tractable lattice model for reaction-diffusion processes of hard-core particles we demonstrate that under nonequilibrium conditions phase coexistence may arise even if the system is effectively one-dimensional as e.g.…

Statistical Mechanics · Physics 2007-05-23 Fatemeh Tabatabaei , Gunter M. Schütz

A thermodynamically consistent framework able to model either diffusive and displacive phase transitions is proposed. The first law of thermodynamics, the balance of linear momentum equation and the Cahn-Hilliard equation for solute mass…

Materials Science · Physics 2015-03-17 Mirko Maraldi , Luisa Molari , Diego Grandi

Theoretical and experimental investigations of water vapor interaction with porous materials are carried out both at the macro level and at the micro level. At the macro level, the influence of the arrangement structure of individual pores…

Fluid Dynamics · Physics 2018-05-08 E. G. Nikonov , M. Pavluš , M. Popovičová

We present the detailed analysis of the diffusive transport of spatially inhomogeneous fluid mixtures and the interplay between structural and dynamical properties varying on the atomic scale. The present treatment is based on different…

Mesoscale and Nanoscale Physics · Physics 2011-05-19 Umberto Marini Bettolo Marconi , Simone Melchionna

The paper addresses the single-file diffusion in the presence of an absorbing boundary. The emphasis is on an interplay between the hard-core interparticle interaction and the absorption process. The resulting dynamics exhibits several…

Statistical Mechanics · Physics 2014-02-26 Artem Ryabov , Petr Chvosta

Studies of the transport of wet water vapour are relevant for various areas of human activity, including the construction and production of building materials, mining, agriculture, environmental safety of technological processes, scientific…

Soft Condensed Matter · Physics 2019-01-23 E. G. Nikonov , M. Popovičová

We show how the nonlinear interaction effects `volume filling' and `adhesion' can be incorporated into the fractional subdiffusive transport of cells and individual organisms. To this end, we use microscopic random walk models with…

Statistical Mechanics · Physics 2015-01-20 Peter Straka , Sergei Fedotov

The permeability of certain polymer membranes with impenetrable nanoinclusions increases with the particle volume fraction (Merkel et al., Science, 296, 2002). This intriguing observation contradicts even qualitative expectations based on…

Materials Science · Physics 2007-05-23 Reghan J. Hill

An asymmetric exclusion process comprising positive particles, negative particles and vacancies is introduced. The model is defined on a ring and the dynamics does not conserve the number of particles. We solve the steady state exactly and…

Statistical Mechanics · Physics 2009-11-07 M. R. Evans , Y. Kafri , E. Levine , D. Mukamel

The dispersion of solute in porous media shows a non-linear increase in the transition from diffusion to advection dominated dispersion as the flow velocity is raised. In the past, the behavior in this intermediate regime has been explained…

Fluid Dynamics · Physics 2014-09-23 B. Ph. van Milligen , P. D. Bons

For a gas-solid interfacial system where chemical species undergo reversible adsorption, we develop a mesoscopic stochastic modeling method that simulates both gas-phase hydrodynamics and surface coverage dynamics by coupling the Langmuir…

The dynamics of desorption from a submonolayer of adsorbed atoms or ions are significantly influenced by the absence or presence of lateral diffusion of the adsorbed particles. When diffusion is present, the adsorbate configuration is…

Chemical Physics · Physics 2013-10-18 Tjipto Juwono , Per Arne Rikvold

Renewal theory is finding increasing applications in non-equilibrium statistical physics. One example relates the probability density and survival probability of a Brownian particle or an active run-and-tumble particle with stochastic…

Statistical Mechanics · Physics 2025-03-04 Paul C Bressloff

Over the past decades, nonlocal models have been widely used to describe aggregation phenomena in biology, physics, engineering, and the social sciences. These are often derived as mean-field limits of attraction-repulsion agent-based…

Cell Behavior · Quantitative Biology 2025-05-14 Carles Falcó , Ruth E. Baker , José A. Carrillo
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