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State-specific approximations can provide an accurate representation of challenging electronic excitations by enabling relaxation of the electron density. While state-specific wave functions are known to be local minima or saddle points of…

Chemical Physics · Physics 2022-01-06 Hugh G. A. Burton

Stochastic electrodynamics is a classical theory which assumes that the physical vacuum consists of classical stochastic fields with average energy $\frac{1}{2}\hbar \omega$ in each mode, i.e., the zero-point Planck spectrum. While this…

Quantum Physics · Physics 2017-08-16 Theo M. Nieuwenhuizen , Matthew T. P. Liska

We propose a scheme for investigating the quantum dynamics of interacting electron models by means of time-dependent variational principle and spin coherent states of space lattice operators. We apply such a scheme to the one-dimensional…

Superconductivity · Physics 2009-10-31 Arianna Montorsi , Vittorio Penna

Some of the most spectacular failures of density-functional and Hartree-Fock theories are related to an incorrect description of the so-called static electron correlation. Motivated by recent progress on the N-representability problem of…

We present a generalization of the variational principle that is compatible with any Hamiltonian eigenstate that can be specified uniquely by a list of properties. This variational principle appears to be compatible with a wide range of…

Chemical Physics · Physics 2020-02-07 Jacqueline A. R. Shea , Elise Gwin , Eric Neuscamman

We introduce a variational method for the approximation of ground states of strongly interacting spin systems in arbitrary geometries and spatial dimensions. The approach is based on weighted graph states and superpositions thereof. These…

Quantum Physics · Physics 2007-05-23 S. Anders , M. B. Plenio , W. Dür , F. Verstraete , H. -J. Briegel

Perhaps the simplest first-principles approach to electronic structure is to fit the charge distribution of each orbital pair and use those fits wherever they appear in the entire electron-electron (EE) interaction energy. The charge…

Chemical Physics · Physics 2015-11-10 Brett I Dunlap , Mark C Palenik

The exchange interaction is investigated theoretically for electrons confined to a 2-D sample placed in a linearly varying magnetic field perpendicular to the plane. Unusual and interesting behavior is predicted: starting from zero, as one…

Strongly Correlated Electrons · Physics 2020-12-30 Pervez Hoodbhoy

Model Hamiltonians with long-range interaction yield energies that are corrected taking into account the universal behavior of the electron-electron interaction at short range. Although the intention of the paper is to explore the…

Chemical Physics · Physics 2020-10-28 Andreas Savin

In this paper, we investigate whether Variational Principles can be associated with the Helmholtz equation subject to impedance (absorbing) boundary conditions. This model has been extensively studied in the literature from both…

Numerical Analysis · Mathematics 2025-11-18 G. Makrakis , C. Makridakis , D. Mitsoudis , M. Plexousakis , T. Pryer

A first-principles approach to describe electron dynamics in open quantum systems driven far from equilibrium via external time-dependent stimuli is introduced. Within this approach, the driven Liouville von Neumann methodology is used to…

Mesoscale and Nanoscale Physics · Physics 2023-05-10 Annabelle Oz , Abraham Nitzan , Oded Hod , Juan E. Peralta

Stochastic electrodynamics is the classical electrodynamic theory of interacting point charges which includes random classical radiation with a Lorentz-invariant spectrum whose scale is set by Planck's constant. Here we give a cursory…

Classical Physics · Physics 2019-03-05 Timothy H. Boyer

We present a generalized dynamical mean-field approach for the nonequilibrium physics of a strongly correlated system in the presence of a time-dependent external field. The Keldysh Green's function formalism is used to study the…

Strongly Correlated Electrons · Physics 2007-05-23 P. Schmidt , H. Monien

Computational difficulties aside, nonequilibrium Green's functions appear ideally suited for investigating the dynamics of central nuclear reactions. Many particles actively participate in those reactions. At the two energy extremes for the…

Nuclear Theory · Physics 2018-05-17 Hossein Mahzoon , Pawel Danielewicz , Arnau Rios

A stochastic dynamics has a natural decomposition into a drift capturing mean rate of change and a martingale increment capturing randomness. They are two statistically uncorrelated, but not necessarily independent mechanisms contributing…

Statistical Mechanics · Physics 2021-06-28 Ying-Jen Yang , Hong Qian

An analysis shows that the ground state of the inhomogeneous system of interacting electrons in the static external field, which satisfies the thermodynamic limit, can be consistently described only using the Green function theory based on…

Statistical Mechanics · Physics 2014-09-02 V. B. Bobrov

It is argued that the world is a dissipative dynamic system, a phase flow of which is formed by conformally-symplectic mapping. The key assumption is that the concept of energy in microcosm makes sense only for the steady motions…

Dynamical Systems · Mathematics 2009-04-08 A. P. Alexandrov

We give a variational formulation of classical statistical mechanics where the one-body density and the local entropy distribution constitute the trial fields. Using Levy's constrained search method it is shown that the grand potential is a…

Soft Condensed Matter · Physics 2015-05-30 Matthias Schmidt

We introduce a new form of density functional theory for the {\em ab initio} description of electronic systems in contact with a molecular liquid environment. This theory rigorously joins an electron density-functional for the electrons of…

Soft Condensed Matter · Physics 2009-11-11 Sahak Petrosyan , Jean-Francois Briere , David Roundy , T. A. Arias

A dynamical method for inelastic transport simulations in nanostructures is compared with a steady-state method based on non-equilibrium Green's functions. A simplified form of the dynamical method produces, in the steady state in the…

Mesoscale and Nanoscale Physics · Physics 2008-08-19 Eunan J. McEniry , Thomas Frederiksen , Tchavdar N. Todorov , Daniel Dundas , Andrew P. Horsfield