Related papers: Gas-grain models for interstellar anion chemistry
Context. Cosmic ray particles that hit interstellar grains in dark molecular cores may induce whole-grain heating. The high temperature of a CR-heated grain allows energy barriers for bulk diffusion and reactions to be overcome.…
Gas-phase abundance ratios between \ce{C2H4O2} isomers methyl formate (MF), glycolaldehyde (GA), and acetic acid (AA) are typically on the order of 100:10:1 in star-forming regions. However, an unexplained divergence from this neat…
Cold gaseous systems play important roles in galaxy evolution by possibly providing fuel to ignite active galactic nuclei (AGN) activity and star-formation. In this work, we analyze [CII]$158\rm \mu m$ and continuum observations from ALMA…
We present a theoretical investigation of CN and HCN molecule formation in dense interstellar clouds. We study the gas-phase CN and HCN production efficiencies from the outer photon-dominated regions (PDRs) into the opaque cosmic-ray…
Interstellar dust models are facing a "carbon crisis", so called because recent observations suggest that the abundance of carbon available for dust in the interstellar medium is less than half of the amount required to be tied up in…
Star formation activity in molecular clouds is often found to be correlated with the amount of material above a column density threshold of $\sim 10^{22} \, {\rm cm^{-2}}$. Attempts to connect this column density threshold to a ${\it…
We explore the relationship between gas, dust and star formation in a sample of 12 ultra-luminous infrared galaxies (ULIRGs) at high redshift compared to a similar sample of local galaxies. We present new CO observations and/or Spitzer…
We investigate chemistry in the compression layer behind the interstellar shock waves, where molecular cloud formation starts. We perform three-dimensional magnetohydrodynamics simulations of converging flows of atomic gas with shock…
Ionization-recombination balance in dense interstellar and circumstellar environments is a key factor for a variety of important physical processes, such as chemical reactions, dust charging and coagulation, coupling of the gas with…
Eleven models of Galactic chemical evolution, differing in the carbon, nitrogen,and oxygen yields adopted, have been computed to reproduce the Galactic O/H values obtained from H II regions. All the models fit the oxygen gradient, but only…
We perform a complete census of molecular ions with an abundance larger than 1e-10 in the protostellar shock L1157-B1 by means of an unbiased high-sensitivity survey obtained with the IRAM-30m and Herschel/HIFI. By means of an LVG radiative…
Within the framework of The Heterogeneous dust Evolution Model at the IaS (THEMIS) this work investigates in detail the surface processes and chemistry relating to core/mantle interstellar and cometary grain structures and its influence on…
Context: Diffusion of species on the dust surface is a key process for determining the chemical composition of interstellar ices. On the dust surface, adsorbed species diffuse from one potential well to another and react with other adsorbed…
We aim to understand the rich chemical composition of AFGL 2591, a prototypical isolated high-mass star-forming region. Based on HIFI and JCMT data, the molecular abundances of species found in the protostellar envelope of AFGL 2591 were…
We review the reactions involving HCN and HNC in dark molecular clouds to elucidate new chemical sources and sinks of these isomers. We find that the most important reactions for the HCN-HNC system are Dissociative Recombination (DR)…
The quantity of NH3 produced on grain surfaces in the prestellar core is thought to be one of the determining factors regarding the chemical complexity achievable at later stages of stellar birth. In order to investigate how this quantity…
Condensation of circumstellar dust begins with formation of molecular clusters close to the stellar photosphere. These clusters are predicted to act as condensation cores at lower temperatures and allow efficient dust formation farther away…
We present new measurements of the interstellar gas-phase oxygen abundance along the sight lines towards 19 early-type galactic stars at an average distance of 2.6 kpc. We derive O {\small I} column densities from {\it HST}/STIS…
We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady state photodissociation region code that treats the freeze-out of gas species, grain surface chemistry, and desorption of ices from grains. The code…
Chemical evolution models predict a gradual build-up of $^{13}$C in the universe, based on empirical nuclear reaction rates and assumptions on the properties of stellar populations. However, old metal-poor stars within the Galaxy contain…