Related papers: Gas-grain models for interstellar anion chemistry

Reactions occurring on the ice-covered surfaces of interstellar dust grains are considered to be among the most important sources of complex species in the interstellar medium. Despite this, molecules such as cyanamide, NH2CN, are largely…

We investigate the molecular gas content of z~6 quasar host galaxies using the IRAM / Northern Extended Millimeter Array. We target the 3mm dust continuum, and the line emission from CO(6-5), CO(7-6), [CI]2-1 in 10 infra-red-luminous…

Ubiquitously found in the Universe, atomic hydrogen represents up to 70% of the neutral gas composition of the Milky Way. As an adatom, hydrogen can physisorb or chemisorb onto interstellar dust grains and icy mantles, thereby contributing…

We present an analysis of "bistability" in gas-phase chemical models of dark interstellar clouds. We identify the chemical mechanisms that allow high- and low-ionization solutions to the chemical rate-equations to coexist. We derive simple…

Recent laboratory experiments have demonstrated that, even though contribution from other reaction channels cannot be neglected, unsaturated hydrocarbons easily break their multiple C-C bonds to form CO after their interactions with atomic…

We introduce a model for the explicit evolution of interstellar dust in a cosmological galaxy formation simulation. We post-process a simulation from the Cosmic Reionization on Computers project (CROC, Gnedin 2014), integrating an ordinary…

We present new interstellar dust models which have been derived by simultaneously fitting the far-ultraviolet to near-infrared extinction, the diffuse infrared (IR) emission and, unlike previous models, the elemental abundance constraints…

[ABRIDGED]We study the carbon abundances with a twofold objective. On the one hand, we want to evaluate the behaviour of carbon in the context of Galactic chemical evolution. On the other hand, we focus on the possible dependence of carbon…

For the first time, we report a unified microscopic-macroscopic Monte Carlo simulation of gas-grain chemistry in cold interstellar clouds in which both the gas-phase and the grain surface chemistry are simulated by a stochastic technique.…

The high interstellar abundances of polycyclic aromatic hydrocarbons (PAHs) and their size distribution are the result of complex chemical processes implying dust, UV radiation, and the main gaseous components (H, C+, and O). These…

Chemical abundance radial gradients provide key information on how the processes that affect chemical enrichment of the gas-phase interstellar medium (ISM) act at different galaxy scales. Whereas in the last decades there has been an…

Present AGN models aiming to account for the observed infrared SEDs consider a physical description of the dust and a solution of the radiative transfer problem. Mid infrared spectra obtained at different spatial scales are presented. They…

Recent JWST observations have revealed a population of high-redshift galaxies ($z\gtrsim5$) exhibiting unexpectedly bright ultraviolet (UV) nitrogen emission lines. The strong N III] and N IV] features imply nitrogen-to-oxygen abundance…

We built a grid of photoionization models and compiled already available observational emission line intensities ($\rm 1000 \: < \: \lambda(\AA) \: < \: 2000$) of confirmed star formation regions and Active Galactic Nucleus (AGNs) in order…

Observations of ionised carbon at 158 micron ([CII]) from luminous star-forming galaxies at z~0 show that their ratios of [CII] to far infrared (FIR) luminosity are systematically lower than those of more modestly star-forming galaxies. In…

Context. The chemistry of the diffuse interstellar medium rests upon three pillars: exothermic ion-neutral reactions (" cold chemistry "), endothermic neutral-neutral reactions with significant activation barriers (" warm chemistry "), and…

Earth is deficient in carbon and nitrogen by up to ${\sim}4$ orders of magnitude compared with the Sun. Destruction of (carbon- and nitrogen-rich) refractory organics in the high-temperature planet forming regions could explain this…

Gas phase Elemental abundances in Molecular CloudS (GEMS) is an IRAM 30m Large Program designed to estimate the S, C, N, and O depletions and gas ionization degree, X(e-), in a set of star-forming filaments of Taurus, Perseus and Orion. Our…

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation…