Related papers: Gas-grain models for interstellar anion chemistry
We revisit the question of the ionization of the diffuse medium in late type galaxies, by studying NGC 891. The most important challenge for the models considered so far was the observed increase of [OIII]/Hb, [OII]/Hb, and [NII]/Ha with…
Characterizing the relationship between stars, gas, and metals in galaxies is a critical component of understanding the cosmic baryon cycle. We compile contemporary censuses of the baryons in collapsed structures, their chemical make-up and…
We determined C, N and alpha-element relative abundances in the gas surrounding six QSOs at an average redshift of < z > ~ 2.4, by studying six narrow associated absorption systems in UVES high-resolution spectra. We found five systems with…
The study of the chemical evolution of glycine in the interstellar medium is one of challenging topics in astrochemistry. Here, we present the chemical modeling of glycine in hot cores using the state-of-the-art three-phase chemical model…
Many chemical models of dense interstellar clouds predict that the majority of gas-phase elemental nitrogen should be present as N2, with an abundance approximately five orders of magnitude less than that of hydrogen. As a homonuclear…
The chemical inventory of protoplanetary midplanes is the basis for forming planetesimals. Among them, solid-state reactions based on CO/CO$_2$ toward molecular complexity on interstellar dust grains have been studied in theoretical and…
Observations conducted using the Atacama Large Millimeter/submillimeter Array on the protoplanetary disk around TW Hya show the nitrogen fractionation of HCN molecules in HC$^{14}$N/HC$^{15}$N $\sim$120 at a radius of $\sim$20 AU. In this…
Aminoacetonitrile (AAN), also known as glycinenitrile, has been suggested as a possible precursor of glycine and adenine in the interstellar medium. Here we present the chemical modeling of AAN and its isomers in hot cores using the…
We have carried out observations of CCH ($N=1-0$), CH$_{3}$CN ($J=5-4$), and three $^{13}$C isotopologues of HC$_{3}$N ($J=10-9$) toward three massive young stellar objects (MYSOs), G12.89+0.49, G16.86--2.16, and G28.28--0.36, with the…
We construct the gas-grain chemical network model which includes carbon isotopes (12C and 13C) with an emphasis on isotopomer-exchange reactions. Temporal variations of molecular abundances, the carbon isotope ratios (12CX/13CX) and the…
Evolution of grain mantles in various interstellar environment is studied. We concentrate mainly on water, methanol, carbon di-oxide, which constitute nearly 90% of the grain mantle. We investigate how the production rates of these…
The interstellar medium is crucial to understanding the physics of active galaxies and the coevolution between supermassive black holes and their host galaxies. However, direct gas measurements are limited by sensitivity and other…
The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…
We report the discovery of large amounts of cold (T ~ 10^4 K), chemically young gas in an overdensity of galaxies at redshift z ~ 1.6 in the Great Observatories Origins Deep Survey southern field (GOODS-S). The gas is identified thanks to…
Large interstellar organic molecules are potential precursors of prebiotic molecules. Their formation pathways and chemical relationships with one another and simpler molecules are therefore of great interest. In this paper, we address the…
Context. Time dependent gas-grain chemistry can help us understand the layered structure of species deposited onto the surface of grains during the lifetime of a protoplanetary disk. The history of trapping important quantities of carbon-…
The $L_{\rm IR}-L_{\rm HCN}$ relation suggests that there is a tight connection between dense gas and star formation. We use data from the Close AGN Reference Survey (CARS) to investigate the dense gas - star formation relation in AGN…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
We consider the depletion of elements from the interstellar gas onto a population of very small dust grains. Adopting a grain model in which of order 4% of the cosmic C abundance is in grains with radii <= 10 Angstroms, we find that the…
We have explored the capabilities of dust extinction and $\gamma$ rays to probe the properties of the interstellar medium in the nearby anti-centre region. We have jointly modelled the $\gamma$-ray intensity and the stellar reddening,…