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A vibrational model of transport properties of dense fluids assumes that solid-like oscillations of atoms around their temporary equilibrium positions dominate the dynamical picture. The temporary equilibrium positions of atoms do not form…

Soft Condensed Matter · Physics 2024-01-09 Sergey Khrapak

First steps towards developing a new perturbation theory for molecular liquids are taken. By choosing a new form of splitting the site-site potential functions between molecules, we will get a set of atomic fluids as the reference system…

Chemical Physics · Physics 2017-11-21 Mehrdad Khanpour

The paper intends to offer a general overview on what the concept of integrability means for a nonlinear dynamical system and how the symmetry method can be applied for approaching it. After a general part where key problems as direct and…

Mathematical Physics · Physics 2011-11-08 Rodica Cimpoiasu , Radu Constantinescu

Ten "themes" of viscous liquid physics are discussed with a focus on how they point to a general description of equilibrium viscous liquid dynamics (i.e., fluctuations) at a given temperature. This description is based on standard…

Soft Condensed Matter · Physics 2009-11-11 Jeppe C. Dyre

Colloidal particles are not simple rigid particles, in general an isolated particle is a system with many degrees of freedom in its own right, e.g., the counterions around a charged colloidal particle.The behaviour of model colloidal…

Statistical Mechanics · Physics 2009-10-31 Richard P. Sear

The friction kernel (or memory function) $\gamma(t)$ characterizing single-molecule dynamics in strongly bound liquids exhibits two distinct relaxations with the longer time-scale relaxation associated with attractive intermolecular forces.…

Chemical Physics · Physics 2014-11-10 X. You , L. R. Pratt , S. W. Rick

In this third paper of the series, which started with [N. P. Bailey et al., J. Chem. Phys. 129, 184507 and 184508 (2008)], we continue the development of the theoretical understanding of strongly correlating liquids - those whose…

Soft Condensed Matter · Physics 2013-01-29 Thomas B. Schrøder , Nicholas P. Bailey , Ulf R. Pedersen , Nicoletta Gnan , Jeppe C. Dyre

We present a theory of the dynamics of monatomic liquids built on two basic ideas: (1) The potential surface of the liquid contains three classes of intersecting nearly-harmonic valleys, one of which (the ``random'' class) vastly outnumbers…

Statistical Mechanics · Physics 2009-11-10 Eric D. Chisolm , Duane C. Wallace

The particle diffusion in a fluid is a classical topic that dates back to more than one century ago. However, a full solution to this issue still lacks. In this work the velocity autocorrelation function and the diffusion constant are…

Fluid Dynamics · Physics 2016-08-03 Hanqing Zhao , Hong Zhao

The possibility of self-consistent determination of instanton liquid parameters is discussed together with the definition of optimal pseudo-particle configurations and comparing the various pseudo-particle ensembles. The weakening of…

High Energy Physics - Phenomenology · Physics 2009-01-09 S. V. Molodtsov , G. M. Zinovjev

Fluids can behave in a highly irregular, turbulent way. It has long been realised that, therefore, some weak notion of solution is required when studying the fundamental partial differential equations of fluid dynamics, such as the…

Analysis of PDEs · Mathematics 2023-06-14 Dennis Gallenmüller , Raphael Wagner , Emil Wiedemann

We consider the general model for dynamical systems defined on a simplicial complex. We describe the conjugacy classes of these systems and show how symmetries in a given simplicial complex manifest in the dynamics defined thereon,…

Dynamical Systems · Mathematics 2022-10-05 Eddie Nijholt , Lee DeVille

Friction in liquids arises from conservative forces between molecules and atoms. Although the hydrodynamics at the nanoscale is subject of intense research and despite the enormous interest in the non-Markovian dynamics of single molecules…

Statistical Mechanics · Physics 2020-07-13 Arthur V. Straube , Bartosz G. Kowalik , Roland R. Netz , Felix Höfling

We study the equilibrium configurations of a possibly asymmetric fluid-structure-interaction problem. The fluid is confined in a bounded planar channel and is governed by the stationary Navier-Stokes equations with laminar inflow and…

Analysis of PDEs · Mathematics 2023-08-11 Edoardo Bocchi , Filippo Gazzola

I put forward a continuum theory for active nematic gels, defined as fluids or suspensions of orientable rodlike objects endowed with active dynamics, that is based on symmetry arguments and compatibility with thermodynamics. The starting…

Soft Condensed Matter · Physics 2017-11-15 Stefano S Turzi

Liquids in contact with solids are submitted to intermolecular forces making liquids heterogeneous and stress tensors are not any more spherical as in homogeneous bulks. The aim of this article is to show that a square-gradient functional…

Classical Physics · Physics 2017-08-23 Henri Gouin

We examine the Sastry (athermal cavitation) transitions for model monatomic liquids interacting via Lennard-Jones as well as shorter- and longer-ranged pair potentials. Low-temperature thermodynamically stable liquids have $\rho < \rho_S$…

Soft Condensed Matter · Physics 2020-07-29 Caitlin M. Gish , Kai Nan , Robert S. Hoy

When liquids are cooled sufficiently rapidly below their melting temperature, they may bypass crystalization and, instead, enter a long-lived metastable supercooled state that has long been the focus of intense research. Although they…

Statistical Mechanics · Physics 2023-12-05 Zohar Nussinov

Phase separation is a fairly common physical phenomenon with examples including the formation of water droplets from humid air (fog, rain), the separation of a crystalline structure from an isotropic material such as a liquid or even the…

Probability · Mathematics 2007-05-23 Ágoston Pisztora

Soft particles such as microgels and core-shell particles can undergo significant and anisotropic deformations when adsorbed to a liquid interface. This, in turn, leads to a complex phase behavior upon compression. Here we develop a…

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