Does the Sastry transition control cavitation in simple liquids?
Abstract
We examine the Sastry (athermal cavitation) transitions for model monatomic liquids interacting via Lennard-Jones as well as shorter- and longer-ranged pair potentials. Low-temperature thermodynamically stable liquids have except when the attractive forces are long-ranged. For moderate- and short-ranged attractions, stable liquids with exist at higher temperatures; the pressures in these liquids are high, but the Sastry transition may strongly influence their cavitation under dynamic hydrostatic expansion. The temperature at which stable liquids emerge is for Lennard-Jones liquids; decreases (increases) rapidly with increasing (decreasing) pair-interaction range. In particular, for short-ranged potentials, is above the critical temperature. All liquids' inherent structures are isostructural (isomorphic) for densities below (above) the Sastry density . Overall, our results suggest that the barriers to cavitation in most simple liquids under ambient conditions where significant cavitation is likely to occur are primarily vibrational-energetic and entropic rather than configurational-energetic. The most likely exceptions to this rule are liquids with long-ranged pair interactions, such as alkali metals. The most likely exceptions to this rule are liquids with long-ranged pair interactions, such as alkali metals.
Cite
@article{arxiv.2007.13942,
title = {Does the Sastry transition control cavitation in simple liquids?},
author = {Caitlin M. Gish and Kai Nan and Robert S. Hoy},
journal= {arXiv preprint arXiv:2007.13942},
year = {2020}
}
Comments
9 pages, 6 figures