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Related papers: CO ice photodesorption: A wavelength-dependent stu…

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Freeze-out of the gas phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes…

Astrophysics of Galaxies · Physics 2015-09-23 Adwin Boogert , Perry Gerakines , Douglas Whittet

We present 5.2-37.2 micron spectroscopy of the edge-on circumstellar disk CRBR 2422.8-3423 obtained using the InfraRed Spectrograph (IRS) of the Spitzer Space Telescope. The IRS spectrum is combined with ground-based 3-5 micron spectroscopy…

The aim of this study is to understand the chemical conditions of ices around embedded young stellar objects (YSOs) in the metal-poor Large Magellanic Cloud (LMC). We performed near-infrared (2.5-5 micron) spectroscopic observations toward…

Solar and Stellar Astrophysics · Physics 2015-05-18 Takashi Shimonishi , Takashi Onaka , Daisuke Kato , Itsuki Sakon , Yoshifusa Ita , Akiko Kawamura , Hidehiro Kaneda

The astronomical gas-phase detection of simple species and small organic molecules in cold pre-stellar cores, with abundances as high as $\sim$$10^{-8}-10^{-9}$ n$_\text{H}$, contradicts the generally accepted idea that at $10$ K, such…

Astrophysics of Galaxies · Physics 2018-06-19 K-J Chuang , G Fedoseev , D Qasim , S Ioppolo , EF van Dishoeck , H Linnartz

The adsorption of CO on unreconstructed and reconstructed Ir{100} has been studied, using a combination of density functional theory and thermodynamics, to determine the relative stability of the two phases as a function of CO coverage,…

Materials Science · Physics 2009-11-13 Prasenjit Ghosh , Shobhana Narasimhan , Stephen J. Jenkins , David A. King

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Earth and Planetary Astrophysics · Physics 2021-02-22 R. Basalgète , R. Dupuy , G. Féraud , C. Romanzin , L. Philippe , X. Michaut , J. Michoud , L. Amiaud , A. Lafosse , J. -H. Fillion , M. Bertin

CO$_2$ ice is an important reservoir of carbon and oxygen in star and planet forming regions. Together with water and CO, CO$_2$ sets the physical and chemical characteristics of interstellar icy grain mantles, including desorption and…

Astrophysics of Galaxies · Physics 2016-11-15 Ilsa R. Cooke , Edith C. Fayolle , Karin I. Öberg

[Abridged] Observations of protoplanetary disks suggest that they are depleted in gas-phase CO. It has been posed that gas-phase CO is chemically consumed and converted into less volatile species through gas-grain processes. Observations of…

Instrumentation and Methods for Astrophysics · Physics 2022-10-05 J. Terwisscha van Scheltinga , N. F. W. Ligterink , A. D. Bosman , M. R. Hogerheijde , H. Linnartz

H2CO is a ubiquitous molecule in the ISM and in the gas phase of prestellar cores, and is likely present in ice mantles, but its main desorption mechanism is unknown. In this paper our aim is to quantify the desorption efficiency of H2CO…

Astrophysics of Galaxies · Physics 2024-12-25 M. Faure , A. Bacmann , A. Faure , E. Quirico , P. Boduch , A. Domaracka , H. Rothard

The interstellar medium is known to be chemically complex. Organic molecules with up to 11 atoms have been detected in the interstellar medium, and are believed to be formed on the ices around dust grains. The ices can be released into the…

The long-timescale behavior of adsorbed carbon monoxide on the surface of amorphous water ice is studied under dense cloud conditions by means of off-lattice, on-the-fly, kinetic Monte Carlo simula- tions. It is found that the CO mobility…

Astrophysics of Galaxies · Physics 2014-01-08 L. J. Karssemeijer , S. Ioppolo , M. C. van Hemert , A. van der Avoird , M. A. Allodi , G. A. Blake , H. M. Cuppen

Warm absorber spectra contain bound-bound and bound-free absorption features seen in the X-ray and UV spectra from many active galactic nuclei (AGN). The widths and centroid energies of these features indicate they occur in outflowing gas,…

High Energy Astrophysical Phenomena · Physics 2023-04-12 Dev R Sadaula , Manuel A Bautista , Javier A Garcia , Timothy R Kallman

In this work we investigate the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride ions in water droplets. In our approach, we combine a…

Chemical Physics · Physics 2023-09-18 Richard A. Opoku , Céline Toubin , André Severo Pereira Gomes

Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV…

Chemical Physics · Physics 2020-11-05 Rémi Dupuy , Michal Haubner , Bernard Henrist , Jean-Hugues Fillion , Vincent Baglin

The 4.62 micron absorption band, observed along the line-of-sight towards various young stellar objects, is generally used as a qualitative indicator for energetic processing of interstellar ice mantles. This interpretation is based on the…

Astrophysics · Physics 2009-11-10 F. A. van Broekhuizen , J. V. Keane , W. A. Schutte

We present results of classical dynamics calculations, performed to study the photodissociation of water in crystalline and amorphous ice surfaces at a surface temperature of 10 K. Dissociation in the top six monolayers is considered.…

Astrophysics · Physics 2009-11-11 Stefan Andersson , Ayman Al-Halabi , Geert-Jan Kroes , Ewine F. van Dishoeck

This work aims to study the unexplained sulfur depletion observed toward dense clouds and protostars. We made simulation experiments of the UV-photoprocessing and sublimation of H2S and H2S:H2O ice in dense clouds and circumstellar regions,…

Earth and Planetary Astrophysics · Physics 2015-06-03 A. Jiménez-Escobar , G. M. Muñoz Caro

UV irradiation of simple ices is proposed to efficiently produce complex organic species during star- and planet-formation. Through a series of laboratory experiments, we investigate the effects of the H2O concentration, the dominant ice…

Astrophysics of Galaxies · Physics 2015-05-19 Karin I. Oberg , Ewine F. van Dishoeck , Harold Linnartz , Stefan Andersson

CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…

Chemical Physics · Physics 2015-06-17 Carina Arasa , Marc C. van Hemert , Ewine F. van Dishoeck , Geert-Jan Kroes