English

Electron-stimulated desorption from molecular ices in the sub-keV regime

Chemical Physics 2020-11-05 v1 Accelerator Physics Applied Physics

Abstract

Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV electrons and fast ions has been extensively studied, the sub-keV electron regime is comparatively little known. We measured and quantified electron-stimulated desorption from molecular ice systems (layers of N2_2, CO, CO2_2, Ar and H2_2O/D2_2O condensed at cryogenic temperatures) in the 150-2000 eV electron energy range. In this regime stopping power is no longer sufficient to explain the electron energy dependence of ESD yields. We introduce the notion of desorption-relevant depth, which characterizes the transition between two energy deposition regimes near the surface. We then apply this notion to the different systems, showing how ESD in the sub-keV regime can for example reveal the differences in species diffusion in crystalline and porous amorphous CO2_2 ices.

Keywords

Cite

@article{arxiv.2010.09538,
  title  = {Electron-stimulated desorption from molecular ices in the sub-keV regime},
  author = {Rémi Dupuy and Michal Haubner and Bernard Henrist and Jean-Hugues Fillion and Vincent Baglin},
  journal= {arXiv preprint arXiv:2010.09538},
  year   = {2020}
}

Comments

The following article has been accepted by the Journal of Applied Physics. After it is published, it will be found at https://publishing.aip.org/resources/librarians/products/journals/