Related papers: CO ice photodesorption: A wavelength-dependent stu…
(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…
We discuss the interstellar absorption from many atomic and molecular species seen in high-resolution $HST$/STIS UV and high-S/N optical spectra of the moderately reddened B3-5~V star HD~62542. This remarkable sight line exhibits both very…
Abundances and partitioning of ices and gases produced by gas-grain chemistry are governed by adsorption and desorption on grains. Understanding astrophysical observations rely on laboratory measurements of adsorption and desorption rates…
We present a computational study into the adsorption properties of CO$_2$ on amorphous and crystalline water surfaces under astrophysically relevant conditions. Water and carbon dioxide are two of the most dominant species in the icy…
A sample of 59 sight lines to reddened Galactic OB stars was examined for correlations of the strength of the CO Fourth Positive (A - X) absorption band system with the ultraviolet interstellar extinction curve parameters. We used archival…
The absorption spectrum of CO$_2$ in the wavelength range 120\,nm --- 160\,nm is analyzed by means of quantum mechanical calculations performed using vibronically coupled PESs of five singlet valence electronic states and the coordinate…
It has been implicitly assumed that ices on grains in molecular clouds and proto planetary disks are formed by homogeneous layers regardless of their composition or crystallinity. To verify this assumption, we observed the H2O deposition…
In cold and shielded environments, molecules freeze out on dust grain surfaces to form ices such as H2O, CO, CO2, CH4, CH3OH, and NH3. In protoplanetary disks, the exact radial and vertical ice extension depend on disk mass, geometry, and…
Medium resolution (lambda/Delta lambda = 5000-10000) VLT-ISAAC M-band spectra are presented of 39 young stellar objects in nearby low-mass star forming clouds showing the 4.67 micron stretching vibration mode of solid CO. By taking…
Data from the Five College Radio Astronomy Observatory CO Mapping Survey of the Taurus molecular cloud are combined with extinction data for a sample of 292 background field stars to investigate the uptake of CO from the gas to icy grain…
We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…
The James Webb Space Telescope now enables the spectral study of ices with unprecedented sensitivity and angular resolution. Water ice plays a crucial role in the growth of grains and in planetary formation but its spatial distribution in…
The direct study of molecular gas in inner protoplanetary disks is complicated by uncertainties in the spatial distribution of the gas, the time-variability of the source, and the comparison of observations across a wide range of…
Molecular clouds are the cold regions of the Milky Way where stars form. They are enriched by rather complex molecules. Many of these molecules are believed to be synthesized on the icy surfaces of the interstellar submicron-sized dust…
Molecular abundances in protoplanetary disks are highly sensitive to the local physical conditions, including gas temperature, gas density, radiation field, and dust properties. Often multiple factors are intertwined, impacting the…
The gas-phase CO abundance (relative to hydrogen) in protoplanetary disks decreases by up to 2 orders of magnitude from its ISM value ${\sim}10^{-4}$, even after accounting for freeze-out and photo-dissociation. Previous studies have shown…
We present Spitzer IRS spectroscopy of CO2 ice bending mode spectra at 15.2 micrometer toward 19 young stellar objects with luminosity lower than 1 Lsun (3 with luminosity lower than 0.1 Lsun). Ice on dust grain surfaces can encode the…
Experiments on the hydrogenation of CO on crystalline and amorphous ice at 15 K were carried out to investigate the structural effects of the ice surface. The effective rate of H atom addition to CO on the amorphous ice was found to be…
The chemistry of the diffuse interstellar medium is driven by the combined influences of cosmic rays, ultraviolet (UV) radiation, and turbulence. Previously detected at the outer edges of photodissociation regions (PDRs) and formed from the…
Isolated dense molecular cores are investigated to study the onset of complex organic molecule formation in interstellar ice. Sampling three cores with ongoing formation of low-mass stars (B59, B335, and L483) and one starless core (L694-2)…