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We report an approach to synthesize high quality graphene by surface segregation and substrate transfer. Graphene was segregated from Ni surface under the ambient pressure by dissolving carbon in Ni at high temperatures followed by cooling…

Materials Science · Physics 2008-12-09 Qingkai Yu , Jie Lian , Sujitra Siriponglert , Hao Li , Yong Chen , Shin-Shem Pei

We have measured optical absorption in mid-infrared spectral range on hydrogen intercalated epitaxial graphene grown on silicon face of SiC. We have used attenuated total reflection geometry to enhance absorption related to the surface and…

Materials Science · Physics 2018-01-08 Jan Kunc , Martin Rejhon , Pavel Hlídek

The wetting properties of graphene have proven controversial and difficult to assess. The presence of a graphene layer on top of a substrate does not significantly change the wetting properties of the solid substrate, suggesting that a…

Soft Condensed Matter · Physics 2017-02-10 Bijoyendra Bera , Noushine Shahidzadeh , Himanshu Mishra , Daniel Bonn

Graphene/hBN heterostructures can be considered as one of the basic building blocks for the next-generation optoelectronics mostly owing to the record-high electron mobilities. However, currently, the studies of the intrinsic optical…

Application of graphene-type materials in electrocatalysis is a topic of growing scientific and technological interest. A tremendous amount of research has been carried out in the field of oxygen electroreduction, particularly with respect…

Materials Science · Physics 2018-05-23 Jerzy K. Zak , Enrico Negro , Iwona A. Rutkowska , Beata Dembinska , Vito Di Noto , Pawel J. Kulesza

The materials science of graphene grown epitaxially on the hexagonal basal planes of SiC crystals is reviewed. We show that the growth of epitaxial graphene on Si-terminated SiC(0001) is much different than growth on the C-terminated…

Si deposition on H terminated Si(100)-2x1 and 3x1 surfaces at temperatures 300-530 K is studied by scanning tunneling microscopy. Hydrogen apparently hinders Si adatom diffusion and enhances surface roughening. The post-growth annealing…

Materials Science · Physics 2009-11-10 Jeong-Young Ji , T. -C. Shen

A friction based method is proposed for obtaining graphite layers. Freestanding thin structures of graphite containing several layers of graphene are obtained by rubbing a graphite rod on the surfaces of NaCl substrate and then dissolving…

Materials Science · Physics 2014-11-26 Manuel Mailian , Kamran ul Hasan , Aram Mailian

The intrinsic doping level of graphene prepared by mechanical exfoliation and standard lithography procedures on thermally oxidized silicon varies significantly and seems to depend strongly on processing details and the substrate…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Myrsini Lafkioti , Benjamin Krauss , Timm Lohmann , Ute Zschieschang , Hagen Klauk , Klaus v. Klitzing , Jurgen H. Smet

A simple optical method is presented for identifying and measuring the effective optical properties of nanometer-thick, graphene-based materials, based on the use of substrates consisting of a thin dielectric layer on silicon. High contrast…

The spatial distributions of the valence-electron density and the total energy reliefs for water (or methanol) migration on the free surface of graphene are obtained, by using the electron density functional and ab initio pseudopotential…

Mesoscale and Nanoscale Physics · Physics 2015-11-30 A. G. Barylka , R. M. Balabai

In hydrogenated amorphous silicon oxide (a-SiO:H) films, incorporation of oxygen enhances optical gap due to a large number of St-O-Si bond formation, which lies deep into valence band states. An induction effect of this Si-O on other bonds…

Condensed Matter · Physics 2007-11-17 S. M. Iftiquar

We provide a theoretical model that describes the dielectric coupling of a 2D layer of graphene, represented by a polarization function in the Random Phase Approximation, and a semi-infinite 3D substrate, represented by a surface response…

Mesoscale and Nanoscale Physics · Physics 2010-06-10 K. F. Allison , Z. L. Miskovic

We report semiconducting behavior of monolayer graphene enabled through plasma activation of substrate surfaces. The graphene devices are fabricated by mechanical exfoliation onto pre-processed SiO2/Si substrates. Contrary to pristine…

Hydrogenated nanographite can display spontaneous magnetism. Recently we proposed that hydrogenation of nanographite is able to induce finite magnetization. We have performed theoretical investigation of a graphene ribbon in which each…

Materials Science · Physics 2009-11-07 Koichi Kusakabe , Masanori Maruyama

Two-dimensional (2D) materials, such as graphene, are seen as potential candidates for fabricating electronic devices and circuits on flexible substrates. Inks or dispersions of 2D materials can be deposited on flexible substrates by…

Epitaxial graphene layers were grown on the C-face of 4H- and 6H-SiC using an argon-mediated growth process. Variations in growth temperature and pressure were found to dramatically affect the morphological properties of the layers. The…

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

Materials Science · Physics 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen

Compressed hydrogen passes through a series of layered structures in which the layers can be viewed as distorted graphene sheets. The electronic structures of these layered structures can be understood by studying simple model systems- an…

Materials Science · Physics 2013-05-22 Ivan I. Naumov , R. E. Cohen , Russell J. Hemley

First principles density functional calculations are used to study the early oxidation stages of the Mg(0001) surface for oxygen coverages 1/16 <= Theta <= 3 monolayers. It is found that at very low coverages O is incorporated below the…

Materials Science · Physics 2015-06-24 Elsebeth Schroder , Roman Fasel , Adam Kiejna