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Using helium-3 atom scattering, we have studied the adsorption kinetics, the structure and the diffusional dynamics of atomic hydrogen on the surface of a graphene monolayer on Ni(111). Diffraction measurements reveal a 4$^\circ$ rotated…

Mesoscale and Nanoscale Physics · Physics 2022-12-15 Emanuel Bahn , Anton Tamtögl , John Ellis , William Allison , Peter Fouquet

Using scanning tunneling microscopy (STM) in ultra high vacuum and atomic force microscopy, we investigate the corrugation of graphene flakes deposited by exfoliation on a Si/SiO2 (300 nm) surface. While the corrugation on SiO2 is…

Materials Science · Physics 2009-11-13 V. Geringer , M. Liebmann , T. Echtermeyer , S. Runte , M. Schmidt , R. Rückamp , M. Lemme , M. Morgenstern

Both experimental and theoretical studies of the magnetic properties of micrographite and nanographite indicate a crucial role of the partial oxidation of graphitic zigzag edges in ferromagnetism. In contrast to total and partial…

Mesoscale and Nanoscale Physics · Physics 2011-06-29 D. W. Boukhvalov , S. Moehlecke , R. R. da Silva , Y. Kopelevich

In this paper we show how single layer graphene can be utilized to study swift heavy ion (SHI) modifications on various substrates. The samples were prepared by mechanical exfoliation of bulk graphite onto SrTiO$_3$, NaCl and Si(111),…

Materials Science · Physics 2015-06-12 O. Ochedowski , S. Akcöltekin , B. Ban d`Etat , H. Lebius , M. Schleberger

Graphene Oxide and reduced Graphene Oxide are intriguing materials for photonics and electronic devices both for intrinsic characteristics and as precursors for the synthesis of graphene. Whatever the application and the engineering…

We study the effects of insulating oxides in their crystalline forms on the energy band structure of monolayer and bilayer graphene using a \textit{first principles} density functional theory based electronic structure method and a local…

Materials Science · Physics 2011-12-09 Priyamvada Jadaun , Sanjay K. Banerjee , Leonard F. Register , Bhagawan Sahu

We demonstrate hydrogen assisted growth of high quality epitaxial graphene on the C-face of 4H-SiC. Compared with the conventional thermal decomposition technique, the size of the growth domain by this method is substantially increased and…

Materials Science · Physics 2015-06-23 Tuocheng Cai , Zhenzhao Jia , Baoming Yan , Dapeng Yu , Xiaosong Wu

Surface resistivity of hydrogenated amorphous carbon films was measured as a function of the applied electrical field. The measured dependence shows a sharp ambipolar peak near zero gate voltage. Furthermore, we found that in some samples…

Materials Science · Physics 2014-09-11 Savcho Tinchev

In the case of graphene, hydrogenation removes the conductivity due to the bands forming the Dirac cone by opening up a band gap. This type of chemical functionalization is of utmost importance for electronic applications. As predicted by…

Materials Science · Physics 2017-12-07 W. Wang , W. Olovsson , R. I. G. Uhrberg

Here we develop a class off face centred cubic structure of metallic silver nanocrystals, to enable high ORR activity process. Silver nanoparticles deposited within different carbon supports: carboxylated-graphene, SiO2-doted reduced-…

Precise characterization of the graphene/water interface has been hindered by experimental inconsistencies and limited molecular-level access to interfacial structures. In this work, we present a novel integrated computational approach that…

Chemical Physics · Physics 2026-02-10 Xianglong Du , Jun Cheng , Fujie Tang

Hydrogenated graphene edges are assumed to be either armchair, zigzag or a combination of the two. We show that the zigzag is not the most stable fully hydrogenated structure along the <2-1-10> direction. Instead hydrogenated Klein and…

Pristine graphene is not suitable for hydrogen storage at ambient conditions since it binds the hydrogen molecules only by van der Waals interactions. However, the adsorption energy of the hydrogen molecules can be improved by doping or…

Materials Science · Physics 2022-10-24 Vikram Mahamiya , Alok Shukla , Nandini Garg , Brahmananda Chakraborty

Monolayer graphene was deposited on a Si wafer substrate decorated with SiO2 nanoparticles (NPs) and then exposed to aryl radicals that were generated in situ from their diazonium precursors. Using micro-Raman mapping, the aryl radicals…

Materials Science · Physics 2012-11-28 Q. Wu , Y. Wu , Y. Hao , J. Geng , M. Charlton , S. Chen , Y. Ren , H. Ji , H. Li , D. W. Boukhvalov , R. D. Piner , C. W. Bielawski , R. S. Ruoff

Aiming to improve fabrication protocols for boron nitride and graphene (h-BNG) lateral heterostructures, we studied the growth of h-BNG thin films on platinum and their behavior in an oxygen environment. We employed a surface science…

We study the low temperature properties of a single layer of parahydrogen adsorbed on graphene, by means of Quantum Monte Carlo simulations. The computed phase diagram is very similar to that of helium on the same substrate, featuring…

Mesoscale and Nanoscale Physics · Physics 2018-05-02 Marisa Dusseault , Massimo Boninsegni

We have studied two interchange layer systems, (i) free standing partly hydrogenated graphene (graphone), and (ii) graphone on the Nickel (111) surface, to assess various density functional theory based computational schemes incorporating…

Materials Science · Physics 2022-04-26 Magdalena Birowska , Maciej Marchwiany , Claudia Draxl , Jacek. A. Majewski

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Yong Han , James W. Evans , Michael C. Tringides

We have theoretically investigated the electronic and magnetic properties of graphene whose zigzag edges are oxidized. The alteration of these properties by adsorption of $\mathrm{H_{2}O}$ and $\mathrm{NH_3}$ molecules have been considered.…

Chemical Physics · Physics 2015-05-14 Julia Berashevich , Tapash Chakraborty

It has been shown that the first C layer on the SiC(0001)(2{\times}2)C surface already exhibits graphene-like electronic structure, with linear pi bands near the Dirac point. Indeed, the (2{\times}2)C reconstruction, with a Si adatom and C…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 F. Hiebel , P. Mallet , J. -Y. Veuillen , L. Magaud