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We study the thermodynamic behavior of nonpolar liquid mixtures in the vicinity of curved charged objects, such as electrodes or charged colloids. For small enough charge on the object, or equivalently, small potential, the…

Statistical Mechanics · Physics 2009-11-13 Gilad Marcus , Sela Samin , Yoav Tsori

Stabilization and dispersion of electrical charge by colloids in non-polar media, such as nano-particles or inverse micelles, is significant for a variety of chemical and technological applications, ranging from drug delivery to e-ink. Many…

Chemical Physics · Physics 2019-04-16 Sariel Bier , Arik Yochelis

The effects of the discharge voltage on the formation and nature of electric field transients in a symmetric, collisionless, very high frequency, capacitively coupled plasma are studied using a self-consistent particle-in-cell (PIC)…

Plasma Physics · Physics 2019-07-24 Sarveshwar Sharma , N. Sirse , A. Sen , J. S. Wu , M. M. Turner

Molecular conduction operating in dielectric solvent environments are often described using kinetic rates based on Marcus theory of electron transfer at a molecule-metal electrode interface. However, the successive nature of charge transfer…

Chemical Physics · Physics 2020-02-18 Henning Kirchberg , Michael Thorwart , Abraham Nitzan

We study the response of a model micro-electrochemical cell to a large ac voltage of frequency comparable to the inverse cell relaxation time. To bring out the basic physics, we consider the simplest possible model of a symmetric binary…

Fluid Dynamics · Physics 2013-12-12 Laurits H. Olesen , Martin Z. Bazant , Henrik Bruus

Time-dependent current of the electrons excited in the conduction band after ultrafast interband photogeneration is studied theoretically. The transient photocurrent is calculated for the nonlinear regime of response to a stationary…

Materials Science · Physics 2009-11-11 O. E. Raichev , F. T. Vasko

Nonequilibrium processes in semiconductors are considered with highly nonuniform initial densities of charge carriers. It is shown that there exist such distributions of charge densities under which the electric current through a sample…

Condensed Matter · Physics 2009-10-31 V. I. Yukalov , E. P. Yukalova , M. R. Singh

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…

Soft Condensed Matter · Physics 2009-11-10 Martin Z. Bazant , Katsuyo Thornton , Armand Ajdari

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

Soft Condensed Matter · Physics 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

We theoretically investigate homogeneous crystal nucleation in a solution containing a solute and a volatile solvent. The solvent evaporates from the solution, thereby continuously increasing the concentration of the solute. We view it as…

Soft Condensed Matter · Physics 2023-11-16 R. de Bruijn , J. J. Michels , P. van der Schoot

We study the charge and spin transport under high electric field (up to several kV/cm) on the surface of topological insulator Bi$_2$Se$_3$, where the electron-surface optical phonon scattering dominates except at very low temperature. Due…

Mesoscale and Nanoscale Physics · Physics 2013-02-28 P. Zhang , M. W. Wu

We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem…

Fluid Dynamics · Physics 2016-02-02 Christoffer P. Nielsen , Henrik Bruus

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

We report the polarization, displacement current and leakage current behavior of a trivalent nonpolar cation Al cation substituted lead free ferroelectric NBT-BT electroceramics with tetragonal phase and P4mm space group symmetry. Nearly…

Materials Science · Physics 2015-10-28 Hitesh Borkar , M. Tomar , Vinay Gupta , J. F. Scott , Ashok Kumar

We demonstrate sequential lasing at two well-separated energies in a highly photoexcited planar microcavity at room temperature. Two spatially overlapped lasing states with distinct polarization properties appear at energies more than 5 meV…

Optics · Physics 2015-12-22 Feng-Kuo Hsu , Wei Xie , Yi-Shan Lee , Sheng-Di Lin , Chih-Wei Lai

Colloids dispersed in a non-polar solvent become charged when reverse micelles are added. We study the charge of individual sterically-stabilized poly(methyl methacrylate) spheres dispersed in micellar solutions of the surfactants sodium…

Soft Condensed Matter · Physics 2007-12-18 G. Seth Roberts , Rodrigo Sanchez , Roger Kemp , Tiffany Wood , Paul Bartlett

We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic fluxes, and Faradaic…

Chemical Physics · Physics 2012-08-24 Todd R. Ferguson , Martin Z. Bazant

From thermodynamic analysis we demonstrate that during metal-insulator transitions in pure matters, a nonequilibrium homogeneous state may be unstable against charge density modulations with certain wavelengths, and thus evolves to the…

Strongly Correlated Electrons · Physics 2020-11-06 Yin Shi , Long-Qing Chen

Electrical transients enabled by optical excitation and electric detection provide a distinctive opportunity to study the charge transport, recombination and even the hysteresis of a solar cell in a much wider time window ranging from…

We theoretically study the reentrant condensation of a polyelectrolyte in the presence of an oppositely-charged surfactant,a phenomenon whose phase-transition mechanism remains under discussion. We focus on the adsorption and attraction…

Soft Condensed Matter · Physics 2024-11-12 Huaisong Yong
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