Related papers: Electrostatic interactions in critical solvents
Charge-stabilized colloidal spheres dispersed in deionized water are supposed to repel each other. Instead, artifact-corrected video microscopy measurements reveal an anomalous long-ranged like-charge attraction in the interparticle pair…
We experimentally demonstrate that critical Casimir forces in colloidal systems can be continuously tuned by the choice of boundary conditions. The interaction potential of a colloidal particle in a mixture of water and 2,6-lutidine has…
The static interaction of a point charge and a polarisable particle and between two polarisable particles is discussed in vacuo, and force and energy considerations are made. In particular a critical distance is shown (in principle) to…
The effect of imperfections on surface critical properties is studied for Ising models with nearest-neighbour ferromagnetic couplings on simple cubic lattices. In particular, results of Monte Carlo simulations for flat, perfect surfaces are…
We argue that in a fluid, or magnet, confined by adsorbing walls which favour liquid, or (+) phase, the solvation (Casimir) force in the vicinity of the critical point is strongly influenced by capillary condensation which occurs below the…
The present review summarizes and assesses recent theoretical and experimental advances, with special emphasis on the effective interaction between charge-stabilized colloids, in the bulk or in confined geometries, and on the ambiguities of…
Theoretical aspects of polymers in mixed solvents are considered using the Edwards Hamiltonian formalism. Thermodynamic and structural properties are investigated and some predictions are made when the mixed solvent approaches criticality.…
In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…
The electrostatic correlations between ions profoundly influence the structure and forces within electrical double layers. Here, we apply the modified Gaussian Renormalized Fluctuation theory to investigate the counter-intuitive phenomenon…
We calculate the effective force mediated by thermally excited capillary waves between spherical or disklike colloids trapped at a fluid interface. This Casimir type interaction is shown to depend sensitively on the boundary conditions…
In this thesis we study the lateral electrostatic interaction between a pair of non-identical, moderately charged colloidal particles trapped at an electrolyte interface in the limit of short inter-particle separations. Using a simplified…
The Casimir force between macroscopic bodies is well understood, but not the Casimir stress inside bodies. Suppose empty space or a uniform medium meets a soft wall where the refractive index is continuous but its derivative jumps. For this…
In a recent paper (Phys.Rev.A78, 020101(R) (2008)), Kim at al. have reported a large anomaly in the scaling law of the electrostatic interaction between a sphere and a plate, which was observed during the calibration of their Casimir force…
Using Poisson-Boltzmann equation and linear response theory, we derive an effective interaction potential due to a fixed charge distribution in a solution containing polyelectrolytes and point salt. We obtain an expression for the effective…
We demonstrate that in the presence of Coulomb interactions, electrons in graphene behave like a critical system, supporting power law correlations with interaction-dependent exponents. An asymptotic analysis shows that the origin of this…
Antagonistic salts are composed of hydrophilic and hydrophobic ions. In a mixture solvent (water-oil) such ion pairs are preferentially attracted to water or oil, giving rise to a coupling between the charge density and the composition.…
In this paper, we theoretically study the electrostatic interaction between a pair of identical colloids with constant surface potentials sitting in close vicinity of each other at a fluid interface. By employing a simplified yet reasonable…
Some time ago, Fisher and de Gennes pointed out that long-ranged correlations in a fluid close to its critical point Tc cause distinct forces between immersed colloidal particles which can even lead to flocculation [C. R. Acad. Sc. Paris B…
Within a general framework we study the effective, deformation-induced interaction between two colloids trapped at a fluid interface. As an application, we consider the interface deformation owing to the electrostatic field of charged…
We study fluctuation-induced interaction in confined fluids above the isotropic-lamellar transition. At an ideal continuous transition, the disjoining pressure has the asymptotic form $\Pi(d\to\infty)\approx -C k_BT q_0^2/d$, where $d$ is…