Related papers: Electrostatic interactions in critical solvents
Casimir and electrostatic non-contact friction between two gold plates, and a gold tip and a gold plate, are calculated taking into account the contribution of the electrical double layer. It is shown that in an extreme-near field…
We consider the Casimir interaction between a cylinder and a hollow cylinder, both conducting, with parallel axis and slightly different radii. The Casimir force, which vanishes in the coaxial situation, is evaluated for both small and…
It has been established for a long time that the long range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance $H$ is screened by an intervening electrolyte. Here we show how this…
We investigate the effect of quenched surface charge disorder on electrostatic interactions between two charged surfaces in the presence of dielectric inhomogeneities and added salt. We show that in the linear weak-coupling regime (i.e., by…
We establish strict upper limits for the Casimir interaction between multilayered structures of arbitrary dielectric or diamagnetic materials. We discuss the appearance of different power laws due to frequency-dependent material constants.…
We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar…
Criticality in a fluid of dielectric constant D that exhibits Ising-type behavior is studied as additional electrostatic (i.e., ionic) interactions are turned on. An exploratory perturbative calculation is performed for small ionicity as…
We analyze the Casimir force between two parallel infinite metal cylinders, with nearby metal plates (sidewalls), using complementary methods for mutual confirmation. The attractive force between cylinders is shown to have a nonmonotonic…
Many key industrial processes, from electricity production, conversion and storage to electrocatalysis or electrochemistry in general, rely on physical mechanisms occurring at the interface between a metallic electrode and an electrolyte…
A solid substrate, when exposed to a vapour, can interact with it in such a way that sufficiently close to liquid-vapour coexistence a macroscopically thick liquid wetting layer is formed on the substrate surface. If such a wetting…
Within mean-field theory we determine the universal scaling function for the effective force acting on a single colloid located near the interface between two coexisting liquid phases of a binary liquid mixture close to its critical…
The free energy of ion solvation can be decomposed into enthalpic and entropic contributions. This helps to understand the connection between the dielectric properties and the underlying forces. We present a simple linear-response model of…
Hydrodynamic fluctuations have been studied in a wide variety of physical, chemical, and biological phenomena in the past decade. In high energy heavy ion collisions, there will be intrinsic fluctuations even if the initial conditions are…
A better understanding of interfacial mechanisms is needed to improve the performances of electrochemical devices. Yet, simulating an electrode surface at fixed electrolyte composition remains a challenge. Here we apply a finite electric…
For more than 35 years theorists have studied quantum or Casimir friction, which occurs when two smooth bodies move transversely to each other, experiencing a frictional dissipative force due to quantum electromagnetic fluctuations, which…
We calculate the dependence of the Casimir force on the isotopic composition of the interacting objects. This dependence arises from the subtle influence of the nuclear masses on the electronic properties of the bodies. We discuss the…
The high-temperature aspects of the Casimir force between two neutral conducting walls are studied. The mathematical model of "inert" ideal-conductor walls, considered in the original formulations of the Casimir effect, is based on the…
Electrostatic interactions provide a convenient way to modulate interactions between nanoparticles, colloids, and biomolecules because they can be adjusted by the solution pH or salt concentration. While the presence of salt provides an…
We derive exact expressions for the Casimir scalar interaction energy between media-separated eccentric dielectric cylinders and for the media-separated cylinder-plane geometry using a mode-summation approach. Similarly to the…
Electrical image potentials near a metallic or a dielectric wall of higher dielectric constant than that of the solution are attractive, and therefore, can concentrate salt ions near the wall. It has recently been observed that near a…