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We propose and analyze a scheme for sympathetic cooling of the translational motion of polar molecules in an optical lattice, interacting one by one with laser-cooled ions in a radio-frequency trap. The energy gap between the excitation…

Atomic Physics · Physics 2015-05-19 Zbigniew Idziaszek , Tommaso Calarco , Peter Zoller

We propose an alternative method to laser cooling. Our approach utilizes the extreme brightness of a supersonic atomic beam, and the adiabatic atomic coilgun to slow atoms in the beam or to bring them to rest. We show how internal-state…

Sympathetic cooling of molecular ions through the Coulomb interaction with laser-cooled atomic ions is an efficient tool to prepare translationally cold molecules without, ideally, affecting the internal state of the molecular ions.…

Quantum Physics · Physics 2026-04-20 J. Martin Berglund , Michael Drewsen , Christiane P. Koch

Ultracold molecular gases are promising as an avenue to rich many-body physics, quantum chemistry, quantum information, and precision measurements. This richness, which flows from the complex internal structure of molecules, makes the…

Atomic Physics · Physics 2015-06-18 A. M. Jayich , A. C. Vutha , M. T. Hummon , J. V. Porto , W. C. Campbell

Molecular laser cooling and trapping requires addressing all spontaneous decays to excited vibrational states that occur at the $\gtrsim 10^{-4} - 10^{-5}$ level, which is accomplished by driving repumping transitions out of these states.…

Atomic Physics · Physics 2023-06-06 Nickolas H. Pilgram , Arian Jadbabaie , Chandler J. Conn , Nicholas R. Hutzler

For experiments that require a quantum system to be in the ultra-cold regime, laser cooling is an essential tool. While techniques for laser cooling ions and neutral atoms have been refined and temperatures below the Doppler limit have been…

Atomic Physics · Physics 2024-10-31 Caleb Heuvel-Horwitz , S. F. Yelin

We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…

Quantum Physics · Physics 2022-11-21 Emil J. Zak

We present a method to design a finite decay rate for excited rotational states in polar molecules. The setup is based on a hybrid system of polar molecules with atoms driven into a Rydberg state. The atoms and molecules are coupled via the…

Quantum Gases · Physics 2012-05-15 Sebastian D. Huber , Hans Peter Büchler

We demonstrate rotational excitation of molecular ions that are sympathetically cooled by laser-cooled atomic ions to a temperature as low as ca. 10 mK. The molecular hydrogen ions HD+ and the fundamental rotational transition $(v=0,\,…

Quantum Physics · Physics 2013-11-05 J. Shen , A. Borodin , M. Hansen , S. Schiller

We demonstrate broadband laser cooling of atomic ions in an rf trap using ultrafast pulses from a modelocked laser. The temperature of a single ion is measured by observing the size of a time-averaged image of the ion in the known harmonic…

Quantum Physics · Physics 2009-11-11 B. B. Blinov , R. N. Kohn , M. J. Madsen , P. Maunz , D. L. Moehring , C. Monroe

Analogous to the extension of laser cooling techniques from two-level to three-level atoms, Doppler cooling of molecules with an intermediate electronic state is considered. In particular, we use a rate-equation approach to simulate cooling…

Atomic Physics · Physics 2015-03-17 J. H. V. Nguyen , B. Odom

We present a new method for the generation of rotationally and vibrationally state-selected, translationally cold molecular ions in ion traps. Our technique is based on the state-selective threshold photoionization of neutral molecules…

Chemical Physics · Physics 2010-06-30 Xin Tong , Alexander H. Winney , Stefan Willitsch

Recent theoretical investigations have indicated that rapid optical cycling should be feasible in complex polyatomic molecules with diverse constituents, geometries and symmetries. However, as a composite molecular mass grows, so does the…

Atomic Physics · Physics 2020-12-18 Konrad Wenz , Ivan Kozyryev , Rees L. McNally , Leland Aldridge , Tanya Zelevinsky

We demonstrate the production of ultracold polar RbCs molecules in their vibronic ground state, via photoassociation of laser-cooled atoms followed by a laser-stimulated state transfer process. The resulting sample of $X ^1\Sigma^+ (v=0)$…

Atomic Physics · Physics 2009-11-11 J. M. Sage , S. Sainis , T. Bergeman , D. DeMille

We show that circularly polarized femtosecond laser pulses produce field-free alignment in linear and planar molecules. We study the rotational wavepacket evolution of O$_2$ and benzene created by circularly polarized light. For benzene, we…

Chemical Physics · Physics 2014-06-06 C T L Smeenk , P B Corkum

In this work we investigate the theory for three different uni-directional population transfer schemes in trapped multilevel systems which can be utilized to cool molecular ions. The approach we use exploits the laser-induced coupling…

Quantum Physics · Physics 2010-01-27 C. Lazarou , M. Keller , B. M. Garraway

Advances of quantum control technology have led to nearly perfect single-qubit control of nuclear spins and atomic hyperfine ground states. In contrast, quantum control of strong optical transitions, even for free atoms, are far from being…

Atomic Physics · Physics 2020-06-24 Yudi Ma , Xing Huang , Xiaoqing Wang , Lingjing Ji , Yizun He , Liyang Qiu , Jian Zhao , Yuzhuo Wang , Saijun Wu

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

We theoretically and computationally investigate the cooling of antihydrogen, $\bar{H}$, using optical molasses cooling. This updates the results in Ref. [1] to the current capabilities of the ALPHA experiment. Through Monte Carlo…

Atomic Physics · Physics 2025-02-11 Spencer J. Walsh , C. Ø. Rasmussen , F. Robicheaux

Cavity cooling of an atom works best on a cyclic optical transition in the strong coupling regime near resonance, where small cavity photon numbers suffice for trapping and cooling. Due to the absence of closed transitions a straightforward…

Quantum Physics · Physics 2012-11-13 R. J. Schulze , C. Genes , H. Ritsch