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Quantum spin chains with competing interactions offer a platform where low dimensionality and frustration--both acting to suppress magnetic order--intersect. We studied magnetic ordering in the spin-1/2 chain compound AgCuVO$_4$ using muon…

Strongly Correlated Electrons · Physics 2025-10-23 A. Hromov , A. Zorko , M. Gomilšek , I. Puente Orench , L. Keller , T. Shiroka , A. Prokofiev , M. Pregelj

We present the synthesis and a detailed investigation of structural and magnetic properties of polycrystalline NaVOAsO$_4$ by means of x-ray diffraction, magnetization, electron spin resonance (ESR), and $^{75}$As nuclear magnetic resonance…

Strongly Correlated Electrons · Physics 2019-01-30 U. Arjun , K. M. Ranjith , B. Koo , J. Sichelschmidt , Y. Skourski , M. Baenitz , A. A. Tsirlin , R. Nath

$^{75}$As NMR measurements were performed on a polycrystalline sample of spin-1/2 alternating-spin-chain Heisenberg antiferromagnet AgVOAsO$_4$. Temperature-dependent NMR shift $K(T)$, which is a direct measure of the intrinsic spin…

Materials Science · Physics 2017-12-27 N. Ahmed , P. Khuntia , H. Rosner , M. Baenitz , A. A. Tsirlin , R. Nath

Motivated by an early experimental study of VOSeO3, which suggested that it is a quasi-2D system of weakly coupled spin dimers with a small spin gap, we have investigated the electronic structure of this material via density-functional…

Condensed Matter · Physics 2009-11-07 Roser Valenti , T. Saha-Dasgupta , F. Mila

Structural and magnetic properties of a quasi-one-dimensional spin-$1/2$ compound NaVOPO$_4$ are explored by x-ray diffraction, magnetic susceptibility, high-field magnetization, specific heat, electron spin resonance, and $^{31}$P nuclear…

Strongly Correlated Electrons · Physics 2019-10-30 Prashanta K. Mukharjee , K. M. Ranjith , B. Koo , J. Sichelschmidt , M. Baenitz , Y. Skourski , Y. Inagaki , Y. Furukawa , A. A. Tsirlin , R. Nath

We present inelastic neutron scattering data on the quantum paramagnet AgVOAsO4 that establish the system is a S=1/2 alternating spin chain compound and provide a direct measurement of the spin gap. We also present experimental evidence for…

The magnetic susceptibility and magnetization of high quality single crystal beta-TeVO4 are reported. We show that this compound, made of weakly coupled infinite chains of VO5 pyramids sharing corners, behaves as a S = 1/2 one-dimensional…

Strongly Correlated Electrons · Physics 2015-05-30 Yu. Savina , O. Bludov , V. Pashchenko , S. L. Gnatchenko , P. Lemmens , H. Berger

We apply density functional theory band structure calculations, the coupled-cluster method, and exact diagonalization to investigate the microscopic magnetic model of the spin-1/2 compound Cu2GeO4. The model is quasi-two-dimensional, with…

Strongly Correlated Electrons · Physics 2011-03-24 Alexander A. Tsirlin , Ronald Zinke , Johannes Richter , Helge Rosner

We report the crystal structure, magnetization measurements, and band-structure calculations for the spin-1/2 quantum magnet CaCu2(SeO3)2Cl2. The magnetic behavior of this compound is well reproduced by a uniform spin-1/2 chain model with…

We investigate magnetic excitations in the frustrated zigzag spin-1/2 chain compound $\beta$-TeVO$_4$ by inelastic neutron scattering. In the magnetically ordered ground state, the excitation spectrum exhibits coexisting magnon dispersion,…

Strongly Correlated Electrons · Physics 2018-09-10 M. Pregelj , O. Zaharko , U. Stuhr , A. Zorko , H. Berger , A. Prokofiev , D. Arčon

In frustrated spin-1/2 chains the competition between the nearest- and next-nearest-neighbor exchange interactions leads to a rich phase diagram that becomes even richer in the presence of perturbations in their material realizations. These…

Strongly Correlated Electrons · Physics 2022-05-25 M. Pregelj , A. Zorko , D. Arčon , M. Klanjšek , N. Janša , P. Jeglič , O. Zaharko , S. Krämer , M. Horvatić , A. Prokofiev

We present a detailed study in the paramagnetic regime of the frustrated $s$ = 1/2 spin-compound linarite, PbCuSO$_4$(OH)$_2$, with competing ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor exchange interactions.…

Based on density functional theory band structure calculations, quantum Monte-Carlo simulations, and high-field magnetization measurements, we address the microscopic magnetic model of BaAg2Cu[VO4]2 that was recently proposed as a spin-1/2…

Materials Science · Physics 2012-06-19 Alexander A. Tsirlin , Angela Moeller , B. Lorenz , Yu. Skourski , H. Rosner

We present a joint experimental and computational study of the recently synthesized spin 1/2 system silver-copper-orthovanadate AgCuVO4 [A. M\"oller and J. Jainski, Z. Anorg. Allg. Chem. 634, 1669 (2008)] exhibiting chains of trans…

Strongly Correlated Electrons · Physics 2009-10-12 A. Möller , M. Schmitt , W. Schnelle , T. Förster , H. Rosner

A new technique for searching low-dimensional compounds on the basis of structural data is presented. The sign and strength of all magnetic couplings at distances up to 12 A in five predicted new antiferromagnetic zigzag spin-1/2 chain…

Materials Science · Physics 2015-06-25 L. M. Volkova

In this work we study the interplay between the crystal structure and magnetism of the pyroarsenate \alpha-Cu_2As_2O_7 by means of magnetization, heat capacity, electron spin resonance and nuclear magnetic resonance measurements as well as…

We report on high-field magnetic properties of the silver vanadium phosphate Ag(2)VOP(2)O(7). This compound has a layered crystal structure, but the specific topology of the V-P-O framework gives rise to a one-dimensional spin system, a…

Strongly Correlated Electrons · Physics 2009-11-13 Alexander A. Tsirlin , Ramesh Nath , Franziska Weickert , Yurii Skourski , Christoph Geibel , Helge Rosner

Magnetic properties of the natural mineral Cu$_2$(OH)$_2$CO$_3$ (malachite) were investigated through DC and AC susceptibility measurements. The analysis of the low-temperature part reveals a quantum spin-gap behavior with $\Delta \approx…

Strongly Correlated Electrons · Physics 2009-10-31 E. Janod , L. Leonyuk , V. Maltsev

We show that LiVCuO4 should be described by strongly ferromagnetically coupled Heisenberg antiferromagnetic chains (HAC) in sharp contrast with the effective exchange integrals Ji given in Enderle et al., Phys. Rev. Lett. vol. 104, 237207…

Strongly Correlated Electrons · Physics 2015-11-25 S. -L. Drechsler , S. Nishimoto , R. Kuzian , J. Malek , W. E. A. Lorenz , J. Richter , J. van den Brink , M. Schmitt , H. Rosner

We investigated the magnetoelastic properties of the quasi-one-dimensional spin-1/2 frustrated magnet LiCuVO$_4$. Longitudinal-magnetostriction experiments were performed at 1.5 K in high magnetic fields of up to 60 T applied along the $b$…

Strongly Correlated Electrons · Physics 2021-01-13 A. Miyata , T. Hikihara , S. Furukawa , R. K. Kremer , S. Zherlitsyn , J. Wosnitza
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