Related papers: First detection of ND in the solar-mass protostar …
The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…
Studies of deuterated isotopologues of complex organic molecules can provide important constraints on their origin in regions of star formation. In particular, the abundances of deuterated species are very sensitive to the physical…
Aims. We measure the deuterium fraction, RD, and the CO-depletion factor, fd, toward a number of starless and protostellar cores in the L1688 region of the Ophiuchus molecular cloud complex and search for variations based upon environmental…
Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods.…
UltraCompact HII regions are signposts of high mass star formation. Since high-mass star formation occurs in clusters, one expects to find even earlier phases of massive star formation in the vicinity of UltraCompact HII regions. Here, we…
Molecular deuteration is commonly seen in starless cores and is expected to occur on a timescale comparable to that of the core contraction. Thus, the deuteration serves as a chemical clock, allowing us to investigate dynamical theories of…
We present the detection of deuterated molecular hydrogen (HD) in the remote Universe in a damped Lyman-alpha cloud at zabs=2.418 toward the quasar SDSS J143912.04+111740.5. This is a unique system in which H2 and CO molecules are also…
The chemical structure of high-mass star nurseries is important for a general understanding of star formation. Deuteration is a key chemical process in the earliest stages of star formation because its efficiency is sensitive to the…
Observations of deuterium fractionation in the solar system, and in interstellar and circumstellar material, are commonly used to constrain the formation environment of volatiles. Toward protoplanetary disks, this approach has been limited…
The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In…
The Lyman and Werner band systems of deuterated molecular hydrogen (HD) occur in the far UV range below 1200 A. The high sensitivity of the FUSE mission can give access, at moderate resolution, to hot stars shining through translucent…
We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…
The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…
We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…
Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…
We study deuterium fractionation in two massive starless/early-stage cores C1-N and C1-S in Infrared Dark Cloud (IRDC) G028.37+00.07, first identified by Tan et al. (2013) with ALMA. Line emission from multiple transitions of $\rm N_2H^+$…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Deuterated molecules are good tracers of the evolutionary stage of star-forming cores. During the star formation process, deuterated molecules are expected to be enhanced in cold, dense pre-stellar cores and to deplete after protostellar…
Prestellar cores represent early sites of low-mass ($M$ $\leq$ few M$_\odot$) star and planet formation and provide insight into initial chemical conditions of complex organic molecules (COMs). Deuterated COMs trace the degree of molecular…
We have detected new HD absorption systems at high redshifts, z_abs=2.626 and z_abs=1.777, identified in the spectra of the quasars J0812+3208 and Q1331+170, respectively. Each of these systems consists of two subsystems. The HD column…