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High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{\rm frac}^{{\rm N}_2{\rm H}^+} \equiv {\rm N}_2{\rm D}^+/{\rm…

Solar and Stellar Astrophysics · Physics 2016-12-28 Matthew D. Goodson , Shuo Kong , Jonathan C. Tan , Fabian Heitsch , Paola Caselli

Deuteration has been used as a tracer of the evolutionary phases of low- and high-mass star formation. The APEX Telescope Large Area Survey (ATLASGAL) provides an important repository for a detailed statistical study of massive star-forming…

Astrophysics of Galaxies · Physics 2021-05-05 M. Wienen , F. Wyrowski , C. M. Walmsley , T. Csengeri , T. Pillai , A. Giannetti , K. M. Menten

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars…

Herschel/HIFI observations toward the compact HII region W51 has revealed the presence of a cold dense core along its line of sight in a high-velocity stream located just in front of W51. This detection has been made possible through…

Astrophysics of Galaxies · Physics 2016-12-21 C. Vastel , B. Mookerjea , J. Pety , M. Gérin

Theory predicts, and observations confirm, that the column density ratio of a molecule containing D to its counterpart containing H can be used as an evolutionary tracer in the low-mass star formation process. Since it remains unclear if…

Solar and Stellar Astrophysics · Physics 2015-05-27 F. Fontani , Aina Palau , P. Caselli , A. Sanchez-Monge , M. J. Butler , J. C. Tan , I. Jimenez-Serra , G. Busquet , S. Leurini , M. Audard

Deuterated molecules are a useful diagnostic tool to probe the evolution and the kinematics in the earliest stages of star formation. Due to the low temperatures and high densities in the centre of pre-stellar cores, the deuterium fraction…

Astrophysics of Galaxies · Physics 2026-01-23 K. Giers , S. Spezzano , Y. Lin , P. Caselli , O. Sipilä

Water is a very abundant molecule in star-forming regions. Its deuterium fractionation is an important tool for understanding its formation and evolution during the star and planet formation processes. While the HDO/H$_2$O ratio has been…

High-mass stars are expected to form from dense prestellar cores. Their precise formation conditions are widely discussed, including their virial condition, which results in slow collapse for super-virial cores with strong support by…

Astrophysics of Galaxies · Physics 2017-06-21 Bastian Körtgen , Stefano Bovino , Dominik R. G. Schleicher , Andrea Giannetti , Robi Banerjee

Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…

Astrophysics of Galaxies · Physics 2015-06-04 Vianney Taquet , Cecilia Ceccarelli , Claudine Kahane

Extremely large deuteration of several molecules has been observed towards prestellar cores and low-mass protostars for a decade. New observations performed towards low-mass protostars suggest that water presents a lower deuteration in the…

Astrophysics of Galaxies · Physics 2015-06-19 Vianney Taquet , Steven B. Charnley , Olli Sipilä

Deuteration is a crucial tool to understand the complexity of interstellar chemical processes, especially when they involve the interplay of gas-phase and grain-surface chemistry. In the case of multiple deuteration, comparing observation…

Astrophysics of Galaxies · Physics 2022-05-25 S. Spezzano , O. Sipilä , P. Caselli , S. S. Jensen , S. Czakli , L. Bizzocchi , J. Chantzos , G. Esplugues , A. Fuente , F. Eisenhauer

Searches for the prebiotically-relevant cyanamide (NH$_2$CN) towards solar-type protostars have not been reported in the literature. We here present the first detection of this species in the warm gas surrounding two solar-type protostars,…

Observations of deuterated species are useful in probing the temperature, ionization level, evolutionary stage, chemistry, and thermal history of astrophysical environments. The analysis of data from ALMA and other new telescopes requires…

Solar and Stellar Astrophysics · Physics 2013-10-21 T. Albertsson , D. A. Semenov , A. I. Vasyunin , Th. Henning , E. Herbst

Nitrogen (N) fractionation is used as a tool to search for a link between the chemical history of the Solar System and star-forming regions. A large variation of $^{14}$N/$^{15}$N is observed towards different astrophysical sources, and…

Solar and Stellar Astrophysics · Physics 2019-03-27 L. Colzi , F. Fontani , P. Caselli , S. Leurini , L. Bizzocchi , G. Quaia

The formation of deuterated molecules is favoured at low temperatures and high densities. Therefore, the deuteration fraction D$_{frac}$ is expected to be enhanced in cold, dense prestellar cores and to decrease after protostellar birth.…

Astrophysics of Galaxies · Physics 2017-06-14 S. Zahorecz , I. Jimenez-Serra , L. Testi , K. Immer , F. Fontani , P. Caselli , K. Wang , L. V. Toth

The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…

Solar and Stellar Astrophysics · Physics 2015-12-02 A. Faure , M. Faure , P. Theulé , E. Quirico , B. Schmitt

The abundances of deuterated molecules with respect to their main isotopologue counterparts have been determined to be orders of magnitude higher than expected from the cosmic abundance of deuterium relative to hydrogen. The increasing…

Astrophysics of Galaxies · Physics 2023-03-01 J. Ferrer Asensio , S. Spezzano , L. H. Coudert , V. Lattanzi , C. P. Endres , J. K. Jørgensen , P. Caselli

We have observed the J=3-2 transition of N2H+ and N2D+ to investigate the trend of deuterium fractionation with evolutionary stage in three selected regions in the Infrared Dark Cloud (IRDC) G28.34+0.06 with the Submillimeter Telescope…

Solar and Stellar Astrophysics · Physics 2015-05-18 Huei-Ru Chen , Sheng-Yuan Liu , Yu-Nung Su , Qizhou Zhang

At the low temperatures ($\sim$10 K) and high densities ($\sim$100,000 H$_2$ molecules per cc) of molecular cloud cores and protostellar envelopes, a large amount of molecular species (in particular those containing C and O) freeze-out onto…

Astrophysics of Galaxies · Physics 2019-05-22 Paola Caselli , Olli Sipilä , Jorma Harju

In this work, we study deuterium fractionation in four starless cores in the low-mass star-forming region L1688 in the Ophiuchus molecular cloud. We study how the deuterium fraction ($R_D$) changes with environment, compare deuteration of…