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The competition among reaction processes of a weakly-bound projectile at intermediate times of a slow collision has been unraveled. This has been done using a two-center molecular continuum within a semiclassical, time-dependent…

Nuclear Theory · Physics 2021-07-14 Laura Moschini , Alexis Diaz-Torres

We explore the suitability of ultracold collisions between spin-polarized SrF($^2\Sigma^+$) molecules and Rb($^2$S) atoms as elementary steps for the sympathetic cooling of SrF($^2\Sigma^+$) molecules in a magnetic trap. To this end, we…

Atomic Physics · Physics 2018-10-17 Masato Morita , Maciej B. Kosicki , Piotr S. Żuchowski , Timur V. Tscherbul

We study the evolution of a single BaRb$^+$ molecule while it continuously collides with ultracold Rb atoms. The initially weakly-bound molecule can undergo a sequence of elastic, inelastic, reactive, and radiative processes. We investigate…

We present expressions demonstrating that collisional decoherence of ultracold atoms or molecules in a coherent superposition of non-degenerate quantum states is suppressed when both the real and imaginary parts of the scattering lengths…

Quantum Physics · Physics 2012-07-26 Jie Cui , Roman V. Krems

Microscopic control over polar molecules with tunable interactions would enable realization of novel quantum phenomena. Using an applied electric field gradient, we demonstrate layer-resolved state preparation and imaging of ultracold…

We carry out calculations on $M$-changing collisions of NH ($^3\Sigma^-$) molecules in magnetically trappable states using a recently calculated potential energy surface. We show that elastic collision rates are much faster than inelastic…

Chemical Physics · Physics 2015-05-13 Alisdair O. G. Wallis , Jeremy M. Hutson

The creation of ultracold molecules is currently limited to diatomic species. In this letter we present a theoretical description of the photoassociation of ultracold atoms and molecules to create ultracold excited triatomic molecules, thus…

Atomic Physics · Physics 2015-09-02 Jesús Pérez-Ríos , Maxence Lepers , Olivier Dulieu

The rigorous quantum mechanical description of the collective interaction of many molecules with the radiation field is usually considered numerically intractable, and approximation schemes must be employed. Standard spectroscopy usually…

Chemical Physics · Physics 2023-05-10 Bingyu Cui , Maxim Sukharev , Abraham Nitzan

We theoretically explore photoassociation by Adiabatic Passage of two colliding cold ^{85}Rb atoms in an atomic trap to form an ultracold Rb_2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Moshe Shapiro , Avi Pe'er , Jun Ye

Utilizing single-photon photoassociation, we have achieved ultracold rubidium molecules with a high number density that provides a new efficient approach toward molecular quantum degeneracy. A new detection mechanism for ultracold molecule…

Atomic Physics · Physics 2015-06-12 Jun-Ren Chen , Cheng-Yang Kao , Hung-Bin Chen , Yi-Wei Liu

We present an effective two-channel model for reactive collisions of cold atoms. It augments elastic molecular channels with an irreversible, inelastic loss channel. Scattering is studied with the distorted-wave Born approximation and…

Atomic and Molecular Clusters · Physics 2018-02-14 Christian Cop , Reinhold Walser

We investigate the presence of Feshbach resonances in ultracold alkali-dialkali reactive collisions. Quantum scattering calculations are performed on a new Na_3 quartet potential energy surface. An analysis of scattering features is…

Quantum Physics · Physics 2009-11-13 A. Simoni , J-M. Launay , P. Soldan

We determine trapping conditions for ultracold polar molecules, where pairs of internal states experience identical trapping potentials. Such conditions could ensure that detrimental effects of inevitable inhomogeneities across an ultracold…

Atomic Physics · Physics 2015-06-12 Alexander Petrov , Constantinos Makrides , Svetlana Kotochigova

Collisional complexes, which are formed as intermediate states in molecular collisions, are typically short-lived and decay within picoseconds. However, in ultracold collisions involving bialkali molecules, complexes can live for…

Chemical Physics · Physics 2023-01-13 Roman Bause , Arthur Christianen , Andreas Schindewolf , Immanuel Bloch , Xin-Yu Luo

Quantum scattering calculations are reported for the H+HCl(v,j=0) and H+DCl(v,j=0) collisions for vibrational levels v=0-2 of the diatoms. Calculations were performed for incident kinetic energies in the range 10-7 to 10-1 eV, for total…

Chemical Physics · Physics 2009-11-10 P. F. Weck , N. Balakrishnan

We demonstrate the production of ultracold polar RbCs molecules in their vibronic ground state, via photoassociation of laser-cooled atoms followed by a laser-stimulated state transfer process. The resulting sample of $X ^1\Sigma^+ (v=0)$…

Atomic Physics · Physics 2009-11-11 J. M. Sage , S. Sainis , T. Bergeman , D. DeMille

We present a simple technique for studying collisions of ultracold atoms in the presence of a magnetic field and radio-frequency radiation (rf). Resonant control of scattering properties can be achieved by using rf to couple a colliding…

Quantum Gases · Physics 2010-09-28 Thomas M. Hanna , Eite Tiesinga , Paul S. Julienne

Final-state interactions in the response of a many-body system to an external probe delivering large momentum are normally described using the eikonal approximation, for the trajectory of the struck particle, and the frozen approximation,…

Nuclear Theory · Physics 2008-11-26 M. Petraki , E. Mavrommatis , O. Benhar , J. W. Clark , A. Fabrocini , S. Fantoni

We consider cooperative reactions and we study the effects of the interaction strength among the system components on the reaction rate, hence realizing a connection between microscopic and macroscopic observables. Our approach is based on…

Quantitative Methods · Quantitative Biology 2012-06-07 Aldo Di Biasio , Elena Agliari , Adriano Barra , Raffaella Burioni

We present a thermodynamic description of ultracold gases with dipolar interactions which properly accounts for the long-range nature and broken rotation invariance of the interactions. It involves an additional thermodynamic field…

Quantum Gases · Physics 2025-07-16 Wilhelm Zwerger