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We present a formalism for rigorous calculations of cross sections for inelastic and reactive collisions of ultracold atoms and molecules confined by laser fields in quasi-2D geometry. Our results show that the elastic-to-inelastic ratios…

Atomic Physics · Physics 2015-05-13 Zhiying Li , Roman V. Krems

The rate coefficient formulae of unimolecular reactions are generalized to the systems with the power-law distributions based on nonextensive statistics, and the power-law rate coefficients are derived in the high and low pressure limits,…

Chemical Physics · Physics 2014-05-06 Cangtao Yin , Ran Guo , Jiulin Du

Quantum effects in chemical reactions are most pronounced at ultracold temperatures, where only a few partial waves contribute. While interference among many partial waves is theoretically expected to persist at higher temperatures, direct…

Quantum Physics · Physics 2026-02-02 Or Katz , Meirav Pinkas , Nitzan Akerman , Ming Li , Roee Ozeri

We consider low energy threshold reactive collisions of particles interacting via a van der Waals potential at long range in the presence of external confinement and give analytic formulas for the confinement modified scattering in such…

Quantum Gases · Physics 2015-06-23 Zbigniew Idziaszek , Krzysztof Jachymski , Paul S. Julienne

We describe a new implementation of magnetic collider for investigating cold collisions between ultracold atomic clouds in different spin states, and we use this to investigate scattering involving both even and odd order partial waves. Our…

Other Condensed Matter · Physics 2007-05-23 Angela S. Mellish , Niels Kjaergaard , Paul S. Julienne , Andrew C. Wilson

Studying chemical reactions at very low temperatures is of importance for the understanding of fundamental physical and chemical processes. At very low energies, collisions are dominated by only a few partial waves. Thus, studies in this…

Chemical Physics · Physics 2017-03-30 Dongdong Zhang , Stefan Willitsch

Reactive and elastic cross-sections, and rate coefficients, have been calculated for the S(1D)+ D2 (v=0, j=0) reaction using a modified hyperspherical quantum reactive scattering method. The considered collision energy ranges from the…

Chemical Physics · Physics 2023-05-24 Manuel Lara , P. G. Jambrina , F. J. Aoiz

We investigate the properties of two interacting ultracold polar molecules described as distinguishable quantum rigid rotors, trapped in a one-dimensional harmonic potential. The molecules interact via a multichannel two-body contact…

Atomic Physics · Physics 2018-07-03 Anna Dawid , Maciej Lewenstein , Michał Tomza

Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…

Chemical Physics · Physics 2023-11-02 Shixin Xu , Robert Eisenberg , Zilong Song , Huaxiong Huang

At ultralow energies, atoms and molecules undergo collisions and reactions that are best described in terms of quantum mechanical wave functions. In contrast, at higher energies these processes can be understood quasiclassically. Here, we…

Atomic Physics · Physics 2018-10-10 I. Majewska , S. S. Kondov , C. -H. Lee , M. McDonald , B. H. McGuyer , R. Moszynski , T. Zelevinsky

The long-range electrostatic interactions between molecules depend strongly on their relative orientation, which manifests as a rotational state dependence. Interactions between molecules in the same rotational quantum state are well-known…

Atomic Physics · Physics 2024-05-16 Etienne F. Walraven , Tijs Karman

Traditional chemical kinetics may be inappropriate to describe chemical reactions in micro-domains involving only a small number of substrate and reactant molecules. Starting with the stochastic dynamics of the molecules, we derive a…

Mathematical Physics · Physics 2009-11-10 D. Holcman , Z. Schuss

We theoretically investigate the collisions between ultracold polar molecules in the presence of two lasers ensuring a Raman resonant transition on individual molecules to suppress photon scattering, taking the example of bosonic…

Rydberg atoms and beams of ultracold polar molecules have become highly useful experimental tools in recent years. There is therefore a need for accessible calculations of interaction potentials between such particles and nearby surfaces…

Quantum Physics · Physics 2012-03-05 Simen Å. Ellingsen , Stefan Yoshi Buhmann , Stefan Scheel

We predict that pairs of polar molecules can be weakly bound together in an ultracold environment, provided that a dc electric field is present. The field that links the molecules together also strongly influences the basic properties of…

Atomic Physics · Physics 2009-11-07 A. V. Avdeenkov , J. L. Bohn

We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focusses on the analysis of elastic scattering and spin relaxation in collisions of O2(3Sigma_g) molecules at cold…

Atomic Physics · Physics 2012-02-06 T. V. Tscherbul , Yu. V. Suleimanov , V. Aquilanti , R. V. Krems

This chapter summarizes the properties of near-threshold molecular states that can be formed from ultracold atoms. The properties of the states for a single potential are characterized for different partial waves using the concepts of…

Atomic Physics · Physics 2009-02-11 Paul S. Julienne

We theoretically investigate the interaction between a single molecule and a metallic nanoparticle. We develop a general quantum mechanical description for the calculation of the enhancement of radiative and non-radiative decay channels for…

Mesoscale and Nanoscale Physics · Physics 2008-01-28 Ulrich Hohenester , Andreas Truegler

We discuss diphoton semi(exclusive) production in ultraperipheral lead-lead collisions at energy of $\sqrt{s_{NN}}$ = 5.5 TeV (LHC) and in proton-proton collisions at $\sqrt{s_{pp}}$ = 7 TeV (LHC) and $\sqrt{s_{pp}}$ = 100 TeV (FCC). The…

High Energy Physics - Phenomenology · Physics 2017-11-16 Antoni Szczurek , Mariola Klusek-Gawenda

We compute the damping rates of one-particle excitations in a cold ultrarelativistic plasma to leading order in the coupling constant e for three types of interaction: Yukawa coupling to a massless scalar boson, QED and QCD. Damping rates…

High Energy Physics - Phenomenology · Physics 2009-10-30 Benoit Vanderheyden , Jean-Yves Ollitrault