Related papers: A Simple Quantum Model of Ultracold Polar Molecule…
Coherent control of ultrafast molecule making from colliding reactants is crucial for realizing coherent control of binary photoreactions (CCBP). To handle diverse excitation scenarios, feasibility with both weak and strong fields is…
Pairs of free particles cannot form bound states in elastic collision due to momentum and energy conservation. In many ultracold experiments, however, the particles collide in the presence of an external trapping potential which can couple…
We show that ultracold chemical reactions can be manipulated and controlled by using Rydberg-dressed interactions. Scattering in the ultracold regime is sensitive to long-range interactions, especially when weakly bound (or quasi-bound)…
We present a fully quantum mechanical description of a free $^6$Li atom scattering from a trapped $^{171}$Yb$^+$ ion in one dimension. By reformulating the system in polar coordinates and employing the adiabatic representation, we extract a…
In the past two decades, the revolutionary technologies of creating cold and ultracold molecules have provided cutting-edge experiments for studying the fundamental phenomena of collision physics. To a large degree, the recent explosion of…
From a rigorous multichannel quantum-defect formulation of bimolecular processes, we derive a fully quantal and analytic model for the total rate of exoergic bimolecular reactions and/or inelastic processes that is applicable over a wide…
Experiments are starting to probe collisions and chemical reactions between atoms and molecules at ultra-low temperatures. We have developed a new theoretical procedure for studying these collisions using the R-matrix method. Here this…
We introduce a model to study the collisions of two ultracold diatomic molecules in one dimension interacting via pairwise potentials. We present results for this system, and argue that it offers lessons for real molecular collisions in…
We investigate the collisional stability of magnetically trapped ultracold molecules, taking into account the influence of magnetic fields. We compute elastic and spin-state-changing inelastic rate constants for collisions of the prototype…
We investigate the ultracold collisions of rotationally excited dipolar molecules in free-space, taking the hetero-nuclear bi-alkali molecule of KRb as an example. We show that we can sharply tune the elastic, inelastic and reactive rate…
Ultracold collisions between Cs atoms and Cs2 dimers in the electronic ground state are observed in an optically trapped gas of atoms and molecules. The Cs2 molecules are formed in the triplet ground state by cw-photoassociation through the…
The main limitation of most ultracold chemistry studies to date is the lack of an analysis of reaction products. Here, we discuss the first generally tractable, rigorous theoretical framework for computing statistical product-state…
Ultracold collisions between spin-polarized Na atoms and vibrationally excited Na_2 molecules are investigated theoretically, using both an inelastic formalism (neglecting atom exchange channels) and a reactive formalism (including atom…
We calculate the interaction potential between N atoms and NH molecules and use it to investigate cold and ultracold collisions important for sympathetic cooling. The ratio of elastic to inelastic cross sections is large over a wide range…
The Ultra-relativistic Quantum-Molecular-Dynamics model (UrQMD) is used to study central Pb+Pb reactions at RHIC ($\sqrt{s}=200$ AGeV). The computed collision spectrum reveals that the major part (approx. 80%) of the dynamics is governed by…
Ultracold molecules undergo "sticky collisions" that result in loss even for chemically nonreactive molecules. Sticking times can be enhanced by orders of magnitude by interactions that lead to non-conservation of nuclear spin or total…
Inspired by Wannier's threshold law, we recognize that collision complex decay meets the requirements of quantum-classical correspondence in sufficiently exothermic ultracold reactions. We make use of this correspondence to elucidate the…
We introduce a novel approach based on elastic and inelastic scattering rates to extract the hyper-surface of the chemical freeze-out from a hadronic transport model in the energy range from E$_\mathrm{lab}=1.23$ AGeV to…
We study an excited atom-polar molecular ion chemical reaction (Ca$^*$ + BaCl$^+$) at low temperature by utilizing a hybrid atom-ion trapping system. The reaction rate and product branching fractions are measured and compared to model…
Ultracold collisions of the polyatomic species CaOH are considered, in internal states where the collisions should be dominated by long-range dipole-dipole interactions. The computed rate constants suggest that evaporative cooling can be…