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Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally…

We consider ultracold collisions of ground-state, heteronuclear alkali dimers that are susceptible to four-center chemical reactions 2 AB -> A2 + B2 even at sub-microKelvin temperature. These reactions depend strongly on species,…

Atomic Physics · Physics 2011-12-05 Goulven Quéméner , John L. Bohn , Alexander Petrov , Svetlana Kotochigova

We consider collisions of electric and magnetic polar molecules, taking the OH radical as an example, subject to combined electric and magnetic static fields. We show that the relative orientation of the fields has an important effect on…

Atomic Physics · Physics 2013-07-16 Goulven Quéméner , John L. Bohn

We present an analytic model of thermal state-to-state rotationally inelastic collisions of polar molecules in electric fields. The model is based on the Fraunhofer scattering of matter waves and requires Legendre moments characterizing the…

Chemical Physics · Physics 2008-07-09 Mikhail Lemeshko , Bretislav Friedrich

Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

Collision cross sections and rate constants between two ground- state oxygen molecules are investigated theoretically at translational energies below $\sim 1$K and in zero magnetic field. We present calculations for elastic and spin-…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

The collision of molecules at ultracold temperatures is of great importance for understanding the chemical interactions at the quantum regime. While much theoretical work has been devoted to this, experimental data are only available…

Quantum Gases · Physics 2018-01-30 Xin Ye , Mingyang Guo , Maykel L. González-Martínez , Goulven Quéméner , Dajun Wang

We study polar alkali dimer scattering in a quasi-1D geometry for both reactive and non-reactive species. Elastic and reactive rates are computed as a function of the amplitude of a static electric field within a purely long-range model…

Atomic Physics · Physics 2019-09-19 Romain Vexiau , Jean-Michel Launay , Andrea Simoni

Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both…

Atomic Physics · Physics 2020-03-25 N. J. Fitch , L. P. Parazzoli , H. J. Lewandowski

Entanglement, a defining feature of quantum mechanics, arises naturally from interactions between molecular systems. Yet the precise nature and quantification of entanglement in the products of molecular collisions and reactions remain…

Atomic Physics · Physics 2026-01-27 Adrien Devolder , Paul Brumer , Timur Tscherbul

We consider ultracold, chemically reactive scattering collisions of the diatomic molecules KRb. When two such molecules collide in an ultracold gas, we find that they are energetically forbidden from reacting to form the trimer species…

Atomic Physics · Physics 2015-05-18 Edmund R. Meyer , John L. Bohn

This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…

Atomic Physics · Physics 2015-06-26 R. V. Krems

We propose a one-channel, simple model to describe the dynamics of ultracold dipolar molecules around a F\"orster resonance. Slightly above a specific electric field, a collisional shielding can take place, suppressing the molecular losses…

Quantum Gases · Physics 2024-06-21 Lucas Lassablière , Goulven Quéméner

Motivated by the recent experimental developments on ultracold molecules and atoms, we propose a simplest theoretical model to address the disassociation, reflection and transmission probability of a 1-dimensional cold molecule via quantum…

Quantum Gases · Physics 2023-07-13 Wen-Liang Li , Hai-Jing Song , Tie-Ling Song , D. L. Zhou

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…

Atomic Physics · Physics 2015-05-18 K. -K. Ni , S. Ospelkaus , D. Wang , G. Quemener , B. Neyenhuis , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

We discuss the status of thermal model descriptions of particle ratios in central nucleus-nucleus collisions at ultra-relativistic energy. An alternative to the ``Cleymans-Redlich'' interpretation of the freeze-out trajectory is given in…

Nuclear Theory · Physics 2016-09-08 P. Braun-Munzinger , J. Stachel

Scattering and ionizing cross sections and rates are calculated for ultracold collisions between metastable helium atoms using a fully quantum-mechanical close-coupled formalism. Homonuclear collisions of the bosonic ${}^{4}$He$^{*}…

Atomic Physics · Physics 2019-07-03 D. G. Cocks , I. B. Whittingham , G. Peach

Entanglement is a crucial resource for achieving quantum advantages in quantum computation, quantum sensing, and quantum communication. As shown in this Letter, entanglement is also a valuable resource for the coherent control of the large…

Atomic Physics · Physics 2025-05-19 Adrien Devolder , Timur Tscherbul , Paul Brumer

We model sympathetic cooling of ground-state CaF molecules by ultracold Li and Rb atoms. The molecules are moving in a microwave trap, while the atoms are trapped magnetically. We calculate the differential elastic cross sections for CaF-Li…

Atomic Physics · Physics 2015-11-18 Jongseok Lim , Matthew D. Frye , Jeremy M. Hutson , M. R. Tarbutt

Coherent superpositions and entanglement are hallmarks of quantum mechanics, but they are fragile and can easily be perturbed by their environment. Selected isolated physical systems can maintain coherence and generate entanglement using…