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Spin-crossover complexes exhibit two stable configurations with distinct spin states. The investigation of these molecules using low-temperature scanning tunneling microscopy has opened new perspectives for understanding the associated…

Mesoscale and Nanoscale Physics · Physics 2026-01-05 Jonas Fußangel , Björn Sothmann , Sven Johannsen , Sascha Ossinger , Felix Tuczek , Richard Berndt , Jürgen König , Manuel Gruber

Spin crossover molecules have recently emerged as a family of compounds potentially useful for implementing molecular spintronics devices. The calculations of the electronic properties of such molecules is a formidable theoretical challenge…

Materials Science · Physics 2015-06-04 Andrea Droghetti , Dario Alfe' , Stefano Sanvito

Spin crossover (SCO) complexes are highly flexible bistable molecular switches with two distinct spin states that can be switched into each other by external stimuli such as temperature, pressure, or light. In the condensed phase, this spin…

Combining the synthetic tunability of molecular compounds with the optical selection rules of transition metal dichalcogenides (TMDC) that derive from spin-valley coupling could provide interesting opportunities for the readout of quantum…

Mesoscale and Nanoscale Physics · Physics 2025-01-07 Daphné Lubert-Perquel , Byeong Wook Cho , Alan J. Philips , Young Hee Lee , Jeffrey L. Blackburn , Justin C. Johnson

The spin-reversal in dilute Li$_2$(Li$_{1-x}$Fe$_{x}$)N with $x < 1$ % is dominated by resonant quantum tunneling of spatially well-separated states. We report on the effect of finite couplings between those states that give rise to…

Strongly Correlated Electrons · Physics 2024-11-04 M. Fix , J. H. Atkinson , F. Müller , E. del Barco , A. Jesche

Spin-orbit coupling (SOC) lifts molecular orbital degeneracy, enabling bi-level electronic platforms suitable for next-generation digital devices. However, common light-atom molecular feedstocks exhibit weak SOC due to the absence of heavy…

Materials Science · Physics 2025-05-07 Zihao Wang , Wan-Lu Li , Shaowei Li

The role of the many-body (spin-polaronic) effects in the scanning tunneling spectroscopy of half-metallic ferromagnets (HMF) is considered. It is shown that the non-quasiparticle (NQP) states exist in the majority or minority spin gap in…

Strongly Correlated Electrons · Physics 2009-11-11 V. Yu. Irkhin , M. I. Katsnelson

We derive a kinetic equation for the electrons moving on the surface of a three-dimensional topological insulator. Due to the helical nature of the excitations backward scattering is suppressed in the collision integral, and the spin…

Mesoscale and Nanoscale Physics · Physics 2011-04-11 P. Schwab , R. Raimondi , C. Gorini

Motivated by the recent experiments of Amasha {\it et al.} [Phys. Rev. B {\bf 78}, 041306(R) (2008)], we investigate single electron tunneling into an empty quantum dot in presence of a magnetic field. We numerically calculate the tunneling…

Mesoscale and Nanoscale Physics · Physics 2010-09-28 Peter Stano , Philippe Jacquod

Inelastic tunneling through magnetically anisotropic molecules is studied theoretically in the presence of a strong magnetic field. Since the molecular orientation is not well controlled in tunneling experiments, we consider arbitrary…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Carsten Timm

In high spin molecules metal ions are coupled by ferro or antiferromagnetic short range interactions so that their magnetic moments are parallel or antiparallel to each other at temperatures (T) much smaller than the coupling constant J.…

Condensed Matter · Physics 2009-09-25 A. Keren , P. Mendels , A. Kratzer , A. Scuiller , M. Verdaguer , Z. Slaman , C. Baines

We report on a theoretical study of magnetic transitions induced by tunnelling electrons in individual adsorbed M-Phthalocyanine (M-Pc) molecules where M is a metal atom: Fe-Pc on a Cu(110)(2$\times$1)-O surface and Co-Pc layers on Pb(111)…

Mesoscale and Nanoscale Physics · Physics 2010-07-02 Jean-Pierre Gauyacq , Frederico D. Novaes , Nicolás Lorente

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

We study the Josephson effect through a magnetic molecule with anisotropic properties. Performing calculations in the tunneling regime, we show that the exchange coupling between the electron spin on the molecule and the molecular spin can…

Mesoscale and Nanoscale Physics · Physics 2011-11-16 I. A. Sadovskyy , D. Chevallier , T. Jonckheere , M. Lee , S. Kawabata , T. Martin

We employ spin-polarized (SP) STM to study the spin-dependent tunneling between a magnetite (111) sample and an antiferromagnetic tip through a vacuum barrier at room temperature. Atomic scale STM images show significant magnetic contrast…

Materials Science · Physics 2007-05-23 N. Berdunov , S. Murphy , G. Mariotto , I. V. Shvets

The phenomenon of Quantum Tunneling of Mesoscopic Spins is reviewed in the light of the behavior of the archetype of these systems: the molecular complex Mn12-ac. Most observations can be understood in the framework of the reduced Hilbert…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 B. Barbara , I. Chiorescu , R. Giraud , A. G. M. Jansen , A. Caneschi

A mesoscopic spin valve is used to determine the effective spin polarization of electrons tunneling from and into ferromagnetic transition metals at finite voltages. The tunneling spin polarization from the ferromagnet (FM) slowly decreases…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 S. O. Valenzuela , D. J. Monsma , C. M. Marcus , V. Narayanamurti , M. Tinkham

We optically probe and electrically control a single artificial molecule containing a well defined number of electrons. Charge and spin dependent inter-dot quantum couplings are probed optically by adding a single electron-hole pair and…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 H. J. Krenner , E. C. Clark , T. Nakaoka , M. Bichler , C. Scheurer , G. Abstreiter , J. J. Finley

Polyalanine molecules (PA) with an {\alpha}-helix conformation gathered recently a lot of interest as the propagation of electrons through the chiral backbone structure comes along with spin polarization of the transmitted electrons. By…

Mesoscale and Nanoscale Physics · Physics 2022-02-16 Nguyen T. N. Ha , L. Rasabathina , O. Hellwig , A. Sharma , G. Salvan , S. Yochelis , Y. Paltiel , L. T. Baczewski , C. Tegenkamp

By measuring electron tunneling between a ferromagnet and individual energy levels in an aluminum quantum dot, we show how spin-resolved quantum states can be used as filters to determine spin-dependent tunneling rates. We also observe…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Mandar M. Deshmukh , D. C. Ralph