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We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…

Soft Condensed Matter · Physics 2015-06-03 T. F. Mohry , A. Maciołek , S. Dietrich

Colloids immersed in a critical binary liquid mixture are subject to critical Casimir forces (CCFs) because they confine its concentration fluctuations and influence the latter via effective surface fields. To date, CCFs have only been…

Soft Condensed Matter · Physics 2013-09-04 Akira Furukawa , Andrea Gambassi , Siegfried Dietrich , Hajime Tanaka

We study the behavior of fluids, confined by geometrically structured substrates, upon approaching a critical point at T = Tc in their bulk phase diagram. As generic substrate structures periodic arrays of wedges and ridges are considered.…

Soft Condensed Matter · Physics 2008-10-31 M. Tröndle , L. Harnau , S. Dietrich

The critical Casimir effect provides a thermodynamic analogue of the well-known quantum mechanical Casimir effect. It acts between two surfaces immersed in a critical binary liquid mixture, and results from the confinement of concentration…

Soft Condensed Matter · Physics 2015-06-15 Van Duc Nguyen , Suzanne Faber , Zhibing Hu , Gerard H. Wegdam , Peter Schall

The Casimir effect in quantum electrodynamics (QED) is perhaps the best-known example of fluctuation-induced long-ranged force acting on objects (conducting plates) immersed in a fluctuating medium (quantum electromagnetic field in vacuum).…

Statistical Mechanics · Physics 2009-07-13 Andrea Gambassi

Based on renormalization group concepts and explicit mean field calculations we study the universal contribution to the effective force and torque acting on an ellipsoidal colloidal particle which is dissolved in a critical fluid and is…

Soft Condensed Matter · Physics 2015-05-13 S. Kondrat , L. Harnau , S. Dietrich

We consider a nematic liquid crystal confined by two parallel planar interfaces, one being laterally homogeneous and the other provided by a substrate endowed with a periodic chemical stripe pattern. Based on continuum theory we analyze the…

Soft Condensed Matter · Physics 2009-11-10 F. Karimi Pour Haddadan , F. Schlesener , S. Dietrich

We present an experimental and theoretical study of the phase behavior of a binary mixture of colloids with opposite adsorption preferences in a critical solvent. As a result of the attractive and repulsive critical Casimir forces, the…

Soft Condensed Matter · Physics 2011-10-03 O. Zvyagolskaya , A. J. Archer , C. Bechinger

Critical Casimir forces can play an important role for applications in nano-science and nanotechnology, owing to their piconewton strength, nanometric action range, fine tunability as a function of temperature, and exquisite dependence on…

If colloidal solute particles are suspended in a solvent close to its critical point, they act as cavities in a fluctuating medium and thereby restrict and modify the fluctuation spectrum in a way which depends on their relative…

Soft Condensed Matter · Physics 2018-11-14 Anna Maciolek , Siegfried Dietrich

Within mean-field theory we determine the universal scaling function for the effective force acting on a single colloid located near the interface between two coexisting liquid phases of a binary liquid mixture close to its critical…

Soft Condensed Matter · Physics 2015-06-22 Adam D. Law , Ludger Harnau , Matthias Troendle , Siegfried Dietrich

Using quasi-exact numerical density-matrix renormalization-group techniques we calculate the critical Casimir force for a two-dimensional (2D) Ising strip with equal strong surface fields, along the thermodynamic paths corresponding to the…

Statistical Mechanics · Physics 2015-06-17 M. Zubaszewska , A. Maciołek , A. Drzewiński

The spatial suppression of order parameter fluctuations in a critical media produces Critical Casimir forces acting on confining surfaces. This scenario is realized in a critical binary mixture near the demixing transition point that…

Statistical Mechanics · Physics 2014-10-03 Oleg A. Vasilyev

We review recent advances in the theoretical, numerical, and experimental studies of critical Casimir forces in soft matter, with particular emphasis on their relevance for the structures of colloidal suspensions and on their dynamics.…

Soft Condensed Matter · Physics 2023-12-27 Andrea Gambassi , S. Dietrich

We present a numerical study of the effective potential $V_\mathrm{eff}$ between two hard-sphere colloids dispersed in a solvent of interacting particles, for several values of temperature and solvent density, approaching the solvent…

Soft Condensed Matter · Physics 2013-04-08 Nicoletta Gnan , Emanuela Zaccarelli , Piero Tartaglia , Francesco Sciortino

We experimentally demonstrate that critical Casimir forces in colloidal systems can be continuously tuned by the choice of boundary conditions. The interaction potential of a colloidal particle in a mixture of water and 2,6-lutidine has…

Soft Condensed Matter · Physics 2009-10-23 Ursula Nellen , Laurent Helden , Clemens Bechinger

By using the critical Casimir force, we study the attractive strength dependent aggregation of colloids with and without gravity by means of Near Field scattering. Significant differences were seen between microgravity and ground…

Soft Condensed Matter · Physics 2015-06-05 Sandra J. Veen , Oleg Antoniuk , Bart Weber , Marco Potenza , Stefano Mazzoni , Peter Schall , Gerard H. Wegdam

We study the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance $L$ from each other confining a non-polar simple fluid or a binary liquid mixture.…

Statistical Mechanics · Physics 2015-07-20 Galin Valchev , Daniel Dantchev

We report a numerical investigation of two colloids immersed in a critical solvent, with the aim of quantifying the effective colloid-colloid interaction potential. By turning on an attraction between the colloid and the solvent particles…

Soft Condensed Matter · Physics 2012-09-12 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

Critical Casimir forces emerge between objects, such as colloidal particles, whenever their surfaces spatially confine the fluctuations of the order parameter of a critical liquid used as a solvent. These forces act at short but…

Soft Condensed Matter · Physics 2020-08-05 Agnese Callegari , Alessandro Magazzù , Andrea Gambassi , Giovanni Volpe