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Deeply supercooled water exhibits complex dynamics with large density fluctuations, ice coarsening and characteristic time scales extending from picoseconds to milliseconds. Here, we discuss implications of these time scales as they pertain…

Statistical Mechanics · Physics 2015-10-28 David T. Limmer , David Chandler

We study the phase behavior of a classical system of particles interacting through a strictly convex soft-repulsive potential which, at variance with the pairwise softened repulsions considered so far in the literature, lacks a region of…

Soft Condensed Matter · Physics 2009-09-17 Franz Saija , Santi Prestipino , Gianpietro Malescio

It has been hypothesized that liquid polyamorphism, the existence of multiple amorphous states in a single component substance, may be caused by molecular or supramolecular interconversion. A simple microscopic model [Caupin and Anisimov,…

Soft Condensed Matter · Physics 2023-09-19 Thomas J. Longo , Sergey V. Buldyrev , Mikhail A. Anisimov , Frédéric Caupin

We present evidence that the concurrent existence of two populations of particles with different effective diameters is not a prerequisite for the occurrence of anomalous phase behaviors in systems of particles interacting through…

Soft Condensed Matter · Physics 2015-05-20 Santi Prestipino , Franz Saija , Gianpietro Malescio

It is well known that some liquids can demonstrate anomalous behavior. Interestingly, this be- havior can be qualitatively reproduced with simple core-softened isotropic pair-potential systems. Although anomalous properties of liquids…

Statistical Mechanics · Physics 2015-07-15 Eu. A. Gaiduk , Yu. D. Fomin , V. N. Ryzhov , E. N. Tsiok , V. V. Brazhkin

We consider the novel properties of the Stell-Hemmer core-softened potentials. First we explore how the theoretically predicted second critical point for these potentials is related to the occurrence of the experimentally observed…

Soft Condensed Matter · Physics 2012-11-26 A. Scala , M. R. Sadr-Lahijany , N. Giovambattista , S. V. Buldyrev , H. E. Stanley

A liquid is termed strongly correlating if its virial and potential energy thermal equilibrium fluctuations in the NVT ensemble are more than 90% correlated [Phys. Rev. Lett. 100, 015701 (2008)]. The fluctuations of a strongly correlating…

Soft Condensed Matter · Physics 2013-01-29 Nicoletta Gnan , Thomas B. Schrøder , Ulf R. Pedersen , Nicholas P. Bailey , Jeppe C. Dyre

Using molecular dynamics simulations we investigate the structure of a system of particles interacting through a continuous core-softened interparticle potential. We found for the translational order parameter, t, a local maximum at a…

Soft Condensed Matter · Physics 2007-11-28 Alan B. de Oliveira , Paulo A. Netz , Thiago Colla , Marcia C. Barbosa

In the present paper we consider dispersion curves of longitudinal excitations of a model core-softened liquid and SPC/E model of water. We show that both systems demonstrate anomalous behavior of the excitation frequencies: the frequencies…

Soft Condensed Matter · Physics 2018-12-27 Yu. D. Fomin , E. N. Tsiok , V. N. Ryzhov , V. V. Brazhkin

Systems of soft-core particles interacting via a two-scale potential are studied. The potential is responsible for peaks in the structure factor of the liquid state at two different but comparable length scales, and a similar bimodal…

Soft Condensed Matter · Physics 2015-12-03 A. J. Archer , A. M. Rucklidge , E. Knobloch

Molecular dynamics simulations are used to examine the relationship between water-like anomalies and the liquid-liquid critical point in a family of model fluids with multi-Gaussian, core-softened pair interactions. The core-softened pair…

Soft Condensed Matter · Physics 2015-05-27 Evy Salcedo , Alan B. de Oliveira , Ney M. Barraz , Charusita Chakravarty , Marcia C. Barbosa

Using molecular dynamic simulations we study a system of particles interacting through a continuous core-softened potentials consisting of a hard core, a shoulder at closest distances and an attractive well at further distance. We obtain…

Statistical Mechanics · Physics 2010-06-02 Jonathas Nunes da Silva , Evy Salcedo , Alan Barros de Oliveira , Marcia C. Barbosa

Analysis of power spectrum profiles for various tagged particle quantities in bulk SPC/E water is used to demonstrate that variations in mobility associated with the diffusional anomaly are mirrored in the exponent of the \onebyf\ region.…

Soft Condensed Matter · Physics 2009-11-10 Anirban Mudi , Charusita Chakravarty , Ramakrishna Ramaswamy

This study examines the transverse and longitudinal properties of hard disks confined in narrow channels. Employing an exact mapping of the system onto a one-dimensional polydisperse, nonadditive mixture of hard rods with equal chemical…

Soft Condensed Matter · Physics 2024-08-13 Ana M. Montero , Andrés Santos

Isomorphs are curves in the thermodynamic phase diagram of invariant excess entropy, structure, and dynamics, while pseudoisomorphs are curves of invariant structure and dynamics, but not of the excess entropy. The latter curves have been…

Soft Condensed Matter · Physics 2024-10-30 Zahraa Sheydaafar , Jeppe C. Dyre , Thomas B. Schrøder

"Fluid polyamorphism" is the existence of different condensed amorphous states in a single-component fluid. It is either found or predicted, usually at extreme conditions, for a broad group of very different substances, including helium,…

The structures of proteins exhibit secondary elements composed of helices and loops. Comparison of several water-only hydrophobicity scales with the functionalities of two repeat proteins shows that these secondary elements possess…

Soft Condensed Matter · Physics 2008-03-04 J. C. Phillips

Near-interface colloidal monolayers have often been used as model systems for research on hydrodynamics in biophysics and microfluidic systems. Using optical microscopy and multiparticle tracking techniques, the correlated diffusion of…

Soft Condensed Matter · Physics 2018-09-03 Na Li , Wei Zhang , Zehui Jiang , Wei Chen

The relation between liquid-liquid phase transitions and waterlike density anomalies in core-softened potentials of fluids was investigated in an exactly solvable one dimensional lattice model and a in a three dimensional fluid with…

Soft Condensed Matter · Physics 2015-03-11 Marco Aurélio A. Barbosa , Evy Salcedo , Marcia Barbosa

The design of complex materials and the formation of specific patterns often arise from the properties of the individual building blocks. In this respect, colloidal systems offer a unique opportunity because nowadays they can be synthesized…

Soft Condensed Matter · Physics 2022-03-01 Fabrizio Camerin , Emanuela Zaccarelli