English

Anomalous phase behavior in a model fluid with only one type of local structure

Soft Condensed Matter 2015-05-20 v1 Materials Science

Abstract

We present evidence that the concurrent existence of two populations of particles with different effective diameters is not a prerequisite for the occurrence of anomalous phase behaviors in systems of particles interacting through spherically-symmetric unbounded potentials. Our results show that an extremely weak softening of the interparticle repulsion, yielding a single nearest-neighbor separation, is able to originate a wide spectrum of unconventional features including reentrant melting, solid polymorphism, as well as thermodynamic, dynamic, and structural anomalies. These findings extend the possibility of anomalous phase behavior to a class of systems much broader than currently assumed.

Keywords

Cite

@article{arxiv.1009.4331,
  title  = {Anomalous phase behavior in a model fluid with only one type of local structure},
  author = {Santi Prestipino and Franz Saija and Gianpietro Malescio},
  journal= {arXiv preprint arXiv:1009.4331},
  year   = {2015}
}

Comments

13 pages, 6 figures, in press on J. Chem. Phys

R2 v1 2026-06-21T16:17:31.287Z