Anomalous phase behavior in a model fluid with only one type of local structure
Soft Condensed Matter
2015-05-20 v1 Materials Science
Abstract
We present evidence that the concurrent existence of two populations of particles with different effective diameters is not a prerequisite for the occurrence of anomalous phase behaviors in systems of particles interacting through spherically-symmetric unbounded potentials. Our results show that an extremely weak softening of the interparticle repulsion, yielding a single nearest-neighbor separation, is able to originate a wide spectrum of unconventional features including reentrant melting, solid polymorphism, as well as thermodynamic, dynamic, and structural anomalies. These findings extend the possibility of anomalous phase behavior to a class of systems much broader than currently assumed.
Keywords
Cite
@article{arxiv.1009.4331,
title = {Anomalous phase behavior in a model fluid with only one type of local structure},
author = {Santi Prestipino and Franz Saija and Gianpietro Malescio},
journal= {arXiv preprint arXiv:1009.4331},
year = {2015}
}
Comments
13 pages, 6 figures, in press on J. Chem. Phys